首页|Structure Elucidation of Two Triterpenoid Saponins from Leaves of Schima superba Gardn. et Champ

Structure Elucidation of Two Triterpenoid Saponins from Leaves of Schima superba Gardn. et Champ

扫码查看
Two new oleanane-type triterpenoid saponins with two angeloyls at C-21, C-22, and a branch of tetrasaccharide moiety (Rha, Cal, Glc, GlcA, or Rha, Xyl, Glc, GlcA) at C-3 were isolated from leaves of Schima superba Gardn。 et Champ。 Their structures were established using one- and two-dimensional NMR and high resolution electrospray ionization mass spectrometry as 21,22-di-O-angeloyl-R_1-bamgenol-3-O-{β-d-glucopyranosyl-(1→2)-β-d-galactopyranosyl-(1 → 2)-[α-l-rhamnopyranosyl-(1 → 4)] }-β-d-glucuronopyranoside, named schi-masuoside A(1), 21,22-di-O-angeloyl-R_1-barrigenol-3-O-{β-d-glucopyranosyl-(1 →2)-β-d-xylopyranosyl-(1 → 2)-[α-l-rhamnopyranosyl-(1 → 4)] }-β-d-glucurono-pyranoside, named schimasuoside B (2)。 There are strong antifungal effect of their mixture on Magnaporthe oryzae。

Schima superbaSchimasuoside ASchimasuoside BStructure elucidation

Guanghua Huo、Changling Zhang、Yingjun Zhang

展开 >

College of Bioscience and Engineering, Jiangxi Agricultural University, 330045 Nanchang, People's Republic of China

Kunming Institute of Botany, Chinese Academy of Sciences, 650204 Kunming, People's Republic of China

International conference on applied biotechnology

Tianjin(CN)

Proceedings of the 2012 international conference on applied biotechnology

915-922

2012