查看更多>>摘要:The seemingly counter-intuitive transition metal-catalyzed deconjugative isomerizations of alpha,beta-unsaturated carbonyls offer novel perspectives within the context of remote functionalization strategies. This Digest provides an overview of the handful of examples that have been reported over the last two decades in this area. (C) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).