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Chemical geology
Elsevier
Chemical geology

Elsevier

0009-2541

Chemical geology/Journal Chemical geologySCIISTPAHCIEI
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    The komatiite testimony to ancient mantle heterogeneity

    Puchtel, Igor S.Blichert-Toft, JanneHoran, Mary F.Touboul, Mathieu...
    21页
    查看更多>>摘要:Komatiites are crystallized samples of high-temperature, high-MgO lavas that were common during the Archean, but became increasingly rarer in the Proterozoic and Phanerozoic. Although the origin of komatiites remains a subject of debate, all komatiites included in this review, ranging in age from 3.6 to 2.0 Ga, are interpreted to have most likely been derived from anhydrous melting in mantle plumes. These plumes are estimated to have been initiated at different depths in the mantle, thus, providing important information about the chemical evolution of the early Earth. The Nd-142,Nd-143, Hf-176, W-182, Os-187, and Os-186 systematics and trace- and highly siderophile element (HSE) abundances of these komatiites provide strong evidence for the presence of isotopic and chemical heterogeneities in the mantle during the first half of Earth history. These heterogeneities likely reflect the combined effects of (1) the co-existence of diverse post-magma ocean silicate domains that were characterized by variably-fractionated lithophile and sidemphile element abundances; (2) the presence of distinct reservoirs that included mantles and cores of late accreted, differentiated planetesimals; and (3) isotopic exchange across the core-mantle boundary. These data highlight the complexity of komatiite mantle sources, none of which were similar in composition to estimates for the modern bulk silicate Earth (BSE). Moreover, no single petrogenetic model can account for the remarkably diverse chemical and isotopic compositions of komatiites. The disappearance of resolvable positive and negative Nd-142 anomalies, as well as decoupled Nd-143-Hf-176 isotopic signatures, in the mafic-ultramafic rock record by similar to 2.5 Ga indicate that, by the end of the Archean, the earliest silicate reservoirs, formed through primordial magma ocean crystallization, had been largely destroyed as a result of vigorous convective mantle mixing. This implies that, during the Hadean and Archean, it took the mantle similar to 1.5 Ga to mix away the early formed Nd-142 heterogeneities via wholesale mantle convection. Similar to Nd-142 systematics, there appears to have been a shift from mostly positive W-182 anomalies in pre-2.5 Ga komatiite mantle sources to no W-182 offsets in post-2.5 Ga komatiite mantle sources. Coupled with the dis-apperance of projected HSE depletions in komatiite mantle sources at similar to 2.5 Ga, relative to the modern BSE, this shift may indicate that, by the end of the Archean, late accreted planetesimals had become largely homogenized within the mantle, and core-mantle interaction took over as the main driving force of creating W-182 isotope anomalies, possibly coincident with the timing of the onset of modern-style plate tectonics on Earth.

    Elucidating the temperature and density dependence of silver chloride hydration numbers in high-temperature water vapor: A first-principles molecular simulation study

    Messerly, Richard A.Yoon, Tae JunJadrich, Ryan B.Currier, Robert P....
    11页
    查看更多>>摘要:Hydration numbers of metal complexes in low-density aqueous solutions are required for developing geochemical models for ore-forming metals and for designing supercritical desalination processes. In this study, we investigate the temperature and density dependence of the hydration numbers of silver chloride at 623 K, 673 K, and 713 K and densities of 10-100 kg/m(3). Experimental estimates of the hydration number in the literature for AgCl at these conditions are inconclusive and possibly contradictory as to the temperature and density dependence. First-principles molecular simulation presents an attractive alternative to experimental measurements. Specifically, recent work shows that machine-learning-accelerated nested Monte Carlo simulations provide reliable estimates for the hydration numbers of CuCl at 623 K from 10 to 100 kg/m(3). Using the same technique, we find a monotonic temperature dependence, with the hydration number decreasing slightly with increasing temperature. In addition, the simulation-predicted hydration numbers steadily increase with increasing density. These temperature and density trends are in agreement with certain experimental data sets. Therefore, this work demonstrates how first-principles Monte Carlo simulations assist in resolving discrepancies between experimental data sets. Our simulation results also correctly predict that the hydration number, and thus also the solubility, of AgCl is lower than that of CuCl under the same conditions. Furthermore, the bond length and angle formed between the water complex and AgCl differ from those for CuCl, consistent with the lower solubility of AgCl.

    Barium isotope fractionation during dehydration melting of the subducting oceanic crust: Geochemical evidence from OIB-like continental basalts

    Xu, ZhengYong-Fei ZhengZi-Fu Zhao
    13页
    查看更多>>摘要:Continental basalts commonly show ocean island basalts (OIB)-like geochemical compositions, and their origin is geochemically linked to metasomatism of the big mantle wedge by the deeply subducting oceanic slab at postarc depths of >200 km. This linkage is tested by a combined study of Ba isotopes with major-trace elements and Sr-Nd isotopes in Cenozoic continental basalts from eastern China. These basalts show OIB-like trace element distribution patterns and depleted to weakly enriched Sr-Nd isotope compositions, suggesting incorporation of the dehydrated slab component into their mantle sources. Their delta Ba-138 values vary from -0.05 parts per thousand to +0.06 parts per thousand, which are lower than the depleted mid-ocean ridge basalts (MORB) mantle but similar to island arc basalts, OIB and OIB-like continental flood basalts. The variation of delta Ba-138 values cannot be ascribed to fractional crystallization and crustal contamination of mantle-derived magmas, but it results from mixing of the depleted mantle with the recycled crustal material of low delta Ba-138 values. In other words, the geochemical deviations from the depleted MORB mantle are attributable to the source mixing at mantle depths rather than the crustal contamination at crustal depths. Although the delta Ba-138 values of the dehydrated oceanic crust would be lower than the initially subducting crust based on the lower coordination number of Ba in liquid phases relative to solid phases in the crust, the low delta Ba-138 recycled crustal material including igneous oceanic crust (IOC) and seafloor sediment is still required to produce the low delta Ba-138 values for the studied basalts. The similarity in delta Ba-138 to island arc basalts not only indicates the similarly low delta Ba-138 values for the recycled crustal components in these basalts, but also suggests the limited Ba isotope fractionation during dehydration melting of the subducting oceanic crust at postarc depths.

    Testing the advantages of simultaneous in-situ Sm-Nd, U-Pb and elemental analysis of igneous monazite for petrochronological studies. An example from the late Archean, Penzance granite, Western Australia

    Cawood, Peter A.Hollis, Steven P.Raveggi, MassimoBarrote, Vitor R....
    12页
    查看更多>>摘要:Monazite has the ability to incorporate a broad range of trace elements (TE), including Sm-Nd, in addition to being a reliable U-Pb geochronometer. Nonetheless, many current isotopic tracer studies mostly focus on laser ablation-multicollector-inductively coupled plasma mass spectrometry (LA-MC-ICPMS) Hf-in-zircon or whole rock isotope dilution Sm-Nd. The conditions necessary to produce reliable Nd-isotopic data from whole rock analyses (i.e. absence of weathering and alteration) restricts the number of samples suitable for this type of study. Conversely, accessory phases such as monazite, apatite, allanite, epidote and titanite are more resistant to weathering and alteration and have a greater chance of preserving their original Nd-isotopic signature. The Archean Penzance granite, in the Yilgarn Craton, Western Australia, is a relatively unweathered high field strength elements (HFSE)-enriched granite that is associated with the Teutonic Bore volcanic-hosted massive sulfide (VHMS) Camp. Here we compare newly acquired LA split-stream (SS)-MC-ICPMS analyses in monazite from the Penzance granite to previously collected whole rock Nd-isotopes, SHRIMP ages in zircon and monazite and Hf-in-zircon of a specific outcrop. The epsilon Nd-0 of monazite from the Penzance granite have a weighted mean value of +1.6 +/- 0.2 both for the values calculated from the SHRIMP single population age and from individual LASS dates. This value is the same within uncertainty to the whole-rock epsilon Nd-0 value of +1.99 +/- 0.39, whereas epsilon Nd-0 show similar juvenile values with mean value of +2.2 +/- 0.5 (2 SE). These findings complement previous studies that argue that monazite has the potential to provide reliable time constrained isotopic and chemical data, which are comparable to, and at times superior than, Hf-in-zircon and whole-rock Nd-isotopes. Additionally, because monazite can record TE signatures that can be used to retrieve petrological information, this study proposes a LASS-MC-ICPMS routine that achieves simultaneous Sm-Nd isotopes, U/Th-Pb dating and TE analyses in monazite, allowing for further petrological information to be obtained from a single analytical routine. This study also assesses the precision and accuracy in U-Pb ages in monazite reference materials, when additional masses are measured in the same routine. The application of the routine presented here facilitates the use of monazite as isotopic tracer in petrological and sedimentary studies.

    Geochemistry of serpentinized and multiphase altered Atlantis Massif peridotites (IODP Expedition 357): Petrogenesis and discrimination of melt-rock vs. fluid-rock processes

    De Hoog, Jan C. M.Schwarzenbach, Esther M.Escartin, JavierJohn, Barbara E....
    19页
    查看更多>>摘要:International Ocean Discovery Program (IODP) Expedition 357 drilled 17 shallow sites distributed similar to 10 km in the spreading direction (from west to east) across the Atlantis Massif oceanic core complex (Mid-Atlantic Ridge, 30 degrees N). Mantle exposed in the footwall of the Atlantis Massif oceanic core complex is predominantly nearly wholly serpentinized harzburgite with subordinate dunite. Altered peridotites are subdivided into three types: (I) serpentinites, (II) melt-impregnated serpentinites, and (III) metasomatic serpentinites. Type I serpentinites show no evidence of melt-impregnation or metasomatism apart from serpentinization and local oxidation. Type II serpentinites have been intruded by gabbroic melts and are distinguishable in some cases on the basis of macroscopic and microscopic observations, e.g., mm-cm scale mafic-melt veinlets, rare plagioclase (<0.5 modal % in one sample) or by the local presence of secondary (replacive) olivine after orthopyroxene; in other cases, 'cryptic' melt-impregnation is inferred on the basis of incompatible element enrichments. Type III serpentinites are characterized by silica metasomatism manifest by alteration of orthopyroxene to talc and amphibole, and by anomalously high anhydrous SiO2 concentrations (59-61 wt%) and low MgO/SiO2 values (0.48-0.52). Although many chondrite-normalized rare earth element (REE) and primitive mantle-normalized incompatible trace element anomalies, e.g., negative Ce-anomalies, are attributable to serpentinization, other compositional heterogeneities are due to melt-impregnation. On the basis of whole rock incompatible trace elements, a dominant mechanism of melt-impregnation is distinguished in the central and eastern serpentinites from fluid-rock alteration (mostly serpentinization) in the western serpentinites, with increasing melt-impregnation manifest as a west to east increase in enrichment in high-field strength elements and light REE. High degrees of melt extraction are evident in low whole-rock Al2O3/SiO2 values and low concentrations of Al2O3, CaO and incompatible elements. Estimates of the degree of melt extraction based on whole rock REE patterns suggest a maximum of similar to 20% non-modal fractional melting, with little variation between sites. As some serpentinite samples are ex situ rubble, the magmatic histories observed at each site are consistent with a local source (from the fault zone) rather than rafted rubble that would be expected to show more heterogeneity and no spatial pattern. In this case, the studied sites may provide a record of enhanced melt-rock interactions with time, consistent with proposed geological models. Alternatively, sites may signify heterogeneities in these processes at spatial scales of a few km.

    Controls on the distributions of GDGTs and n-alkane isotopic compositions in sediments of the Amazon River Basin

    Bertassoli, D. J., Jr.Haeggi, C.Chiessi, C. M.Schefuss, E....
    12页
    查看更多>>摘要:Lipid biomarker proxies from terrigenous sediments have been extensively used to understand variations in paleoenvironmental conditions, but many of the mechanisms affecting these proxies during riverine transport are still poorly understood. Here, we analyze glycerol dialkyl glycerol tetraether (GDGT) distributions and n-alkane isotopic compositions of soils and sediments from the Amazon River Basin. Our dataset includes suspended sediments of the Amazon River and its main tributaries, as well as soils and sediments of the Xingu River, a large clearwater tributary draining the easternmost part of the Amazon River Basin. Our sampling design aimed at understanding the processes behind spatially distinct GDGT distributions and n-alkane isotopic signatures across lowland Amazonia. Gradual changes in the fractional abundances of isoprenoid GDGTs and in 5- and 6- methyl branched GDGT ratios in suspended sediments of the Amazon River towards its mouth suggest that riverine production is an increasingly important control on the distribution of GDGTs in the lower parts of the system, while values from the western parts are more in line with a dominant soil sourcing. In the Xingu River, indices based on the fractional abundances of branched GDGTs and long-chain n-alkanes demonstrate a strong contribution of terrestrial organic material during the high-water season and an important aquatic component during low-water season. Meanwhile, average stable carbon (delta C-13) and hydrogen (delta D) isotopic signatures of long-chain n-alkanes in soils, riverbed and suspended sediments of the Xingu River are similar and reinforce the relatively conservative behaviour of these proxies within large river systems. The average compound-specific delta C-13 signatures of sediments in the Xingu River are within the expected range for C-3 vegetation and do not seem to capture the signals from the nearby deforested areas. n-Alkanes delta D signals in the Xingu Basin are similar to values obtained in the Amazon River mouth and indicate that n-alkanes sourced from easternmost Amazonian lowlands may predominate over signals from western areas.