首页期刊导航|Chemical geology
期刊信息/Journal information
Chemical geology
Elsevier
Chemical geology

Elsevier

0009-2541

Chemical geology/Journal Chemical geologySCIISTPAHCIEI
正式出版
收录年代

    Comparing isotopic estimates of paleoelevation from carbonates and volcanic glass from the Miocene-age Chucal Formation in northern Chile

    Jimenez-Rodriguez, SebastianQuade, JayDettinger, MatthewHuntington, Katharine W....
    13页
    查看更多>>摘要:Paleoaltimetry reconstructions of the Central Andes based on stable isotope data indicate variable timing and rates of uplift, reflecting the operation of multiple geodynamic mechanisms. There are a range of isotopic methods and proxies involved in these reconstructions, and it may be that biases inherent in some of these methods has led to misinterpretations. Here we explored the limitations of carbonate archives in reconstructing past elevations, including underestimation of paleoelevations by oxygen-isotope evaporative enrichment and carbonate formation in the subsurface. To conduct our test, we obtained stable isotope values of carbonates from the Western Cordillera in northern Chile at similar to 18.5-19.5 degrees S, where previously published paleoaltimetry results from the same sections, based on the hydrogen stable isotope composition of volcanic glass, indicate that this region of the Andes has remained at high elevations (>4.4 km) since at least similar to 23 Ma. We present new oxygen and carbon isotopic, and clumped isotopic results, petrographic and sedimentologic observations, as well as major element abundance (ICP-MS and microprobe analyses) from lacustrine carbonates (marlstones) and cements in sandstones of the early Miocene Chucal Formation in the central Andes of northern Chile. The clumped isotope paleotemperature estimates range from 26 to 45 degrees C in lacustrine carbonates and 27 to 54 degrees C in cements. These results indicate that carbonates from this section do not reflect surface temperatures, suggesting clumped isotope resetting in a rock-buffered setting for marlstones and carbonate formation at depth in the presence of groundwater for cements in sandstones. In contrast, the oxygen and carbon isotopic values from carbonates appear to be primary and combined with Mg/Ca ratios and Na concentrations document the transition from lake deposition into a dominantly fluvial environment within the Chucal Formation, also indicating variable evaporative conditions during deposition. The paleoaltimetry estimates in carbonates significantly underestimate the results determined in volcanic glass, with paleoelevation results ranging between 1.4 km and 2.6 km in marlstones and from 2.6 and 3.6 km in cements.. The results presented in this study highlight the importance of using multiple proxies for paleoaltimetry reconstructions, especially in arid land settings where meteoric waters have been modified by evaporation.

    Chemical variability in volcanic gas plumes and fumaroles along the East African Rift System: New insights from the Western Branch

    Boudoire, G.Giuffrida, G.Liuzzo, M.Bobrowski, N....
    9页
    查看更多>>摘要:The origin of magmatic fluids along the East African Rift System (EARS) is a long-lived field of debate in the scientific community. Here, we investigate the chemical composition of the volcanic gas plume and fumaroles at Nyiragongo and Nyamulagira (Democratic Republic of Congo), the only two currently erupting volcanoes set on the Western Branch of the rift. Our results are in line with earlier conceptual models proposing that volcanic gas emissions along the EARS mainly reflect variable contributions of either a Sub-Continental Lithospheric Mantle (SCLM) component or a Depleted Morb Mantle (DMM) component, and deeper fluid. At Nyiragongo and Nyamulagira, our study discards a major contribution of a high He-3/He-4 mantle plume component in the genesis of volcanic fluids beneath the area. High CO2/He-3 in fumaroles of both volcanoes is thought to reflect carbonate metasomatism in the lithospheric mantle source. As inferred by previous results obtained on the lava chemistry, this carbonate metasomatism would be more pronounced beneath Nyiragongo. This supports the idea of the presence of distinct metasomes within the lithospheric mantle beneath the Western Branch of the rift.

    Redox conditions in Late Permian seawater based on trace metal ratios in fluid inclusions in halite from the Polish Zechstein Basin

    Sendula, EszterGill, Benjamin C.Rimstidt, J. DonaldLowenstein, Tim K....
    16页
    查看更多>>摘要:Previous studies have confirmed that primary fluid inclusions in halite record and preserve information concerning the major ion chemistry of seawater. Here, we determine ratios of redox sensitive trace metals (Fe, Mn, V, Mo, U) in paleo-seawater trapped as primary fluid inclusions in halite from two boreholes (Przybor ' ow IG3, Gorz ' ow Wielkopolski IG1) from the Polish sector of the European Southern Permian Basin and estimate the original seawater concentrations of the redox sensitive trace metals. Our results show generally higher ratios of Fe/U, Fe/Mo, and Fe/V in fluid inclusions in halites associated with sulfate-depleted (calcium-rich) brines, compared to inclusions in halites formed in association with sulfate-rich brines in the Przybor ' ow IG3 borehole. This behavior is consistent with the interpretation of Garcia-Veigas et al. (2011) to reflect changes in redox conditions from oxidizing (represented by sulfate-rich brines) to reducing (represented by sulfate-depleted and calcium-rich brines) in the Zechstein epicontinental sea during the Late Permian. The correlation is more complex in halites from the Gorz ' ow Wielkopolski IG1 borehole, likely reflecting local controls on redox state. Results suggest that ratios of Mn/U, Mn/V, and Mn/Mo in fluid inclusions may be used to refine redox conditions in the water column when these data are evaluated in combination with Fe/U, Fe/Mo, Fe/V, and Mn/Fe ratios because reduction of Mn(III, IV) to Mn(II) occurs at a higher redox potential compared to that required to reduce Fe(III) to Fe(II). The estimated original Mn and Mo concentrations in the seawater in the Late Permian Zechstein Basin are generally within the concentration range observed in modern anoxic basins while concentrations of V and Fe are generally higher and U is generally lower. Our results suggest that trace metal abundances in fluid inclusions in halite vary in response to redox changes in seawater and provide a potential redox proxy. To better understand and apply results obtained from fluid inclusions in halite as a paleoredox proxy, however, further work is required. These include the study of fluid inclusions in halite from more locations worldwide and the more detailed characterization of redox sensitive trace metal behavior during seawater evaporation.

    Boron isotopes of tourmalines from the central Himalaya: Implications for fluid activity and anatexis in the Himalayan orogen

    Liu, ShuaiqiZhang, GuibinZhang, LifeiLiu, Zeyu...
    20页
    查看更多>>摘要:The relationship between fluid activity and anatexis in the Himalaya is ambiguous in regard to whether it is dominated by fluid-saturated melting triggered by Lesser Himalayan Sequence (LHS) fluids or dehydration melting of Greater Himalayan Sequence (GHS) metasedimentary rocks. Boron isotopes are a sensitive probe for tracing the source of fluids and their role during partial melting. However, a lack of constraints on LHS fluid activity has limited our understanding of anatectic processes in the Himalayan orogen. Here we report the results of in situ tourmaline and muscovite B isotope analyses of a suite of samples from the LHS and GHS, including chlorite schist from the LHS, quartz-tourmaline rock from the Main Central Thrust Zone, and leucogranites, leucosomes, mica schist, and garnet amphibolite from the GHS. Tourmaline B isotopic compositions fall in the range of delta B-11 = -18.3 parts per thousand to -8.2 parts per thousand, with tourmalines from leucogranites showing delta B-11 values of -17.2 parts per thousand to -8.2 parts per thousand, from leucosomes of -11.8 parts per thousand to -10.7 parts per thousand, from schists of -17.8 parts per thousand to -13.9 parts per thousand, from quartz-tourmaline rock of -18.3 parts per thousand to -12.8 parts per thousand, and from garnet amphibolite of -16.9 parts per thousand to -13.6 parts per thousand. Muscovites from leucogranite and mica schist yield relatively low B isotopes of -23.3 parts per thousand to -17.2 parts per thousand and -22.4 parts per thousand to -15.4 parts per thousand, respectively. Different source compositions, prograde devolatilization, tourmaline fractionation, fluid exsolution, and external fluid metasomatism are inferred to be the main mechanisms responsible for the varied B isotopes in this study. Our data suggest that the LHS is characterized by depleted B-11, with LHS-derived dehydration fluids calculated to have delta B-11 values of -15.2 parts per thousand to -12.0 parts per thousand at 600 degrees C, whereas metamorphic fluids in the GHS have delta B-11 values of -11.8 parts per thousand to -4.8 parts per thousand. Thus, we propose that dehydration of LHS hydrous minerals produced relatively light-B fluids. Consequently, leucogranites derived from hydration melting triggered by LHS fluids exhibit light B isotopic compositions compared with those derived from dehydration melting in the GHS. To investigate the source of heavy B in GHS leucogranites, we modeled B isotopic fractionation during muscovite pmgrade devolatilization, with results showing that substantial fractionation (0 11 13 > 7 parts per thousand) would occur during muscovite dehydration. Hence, B lost from micas could be a source of heavy B in the leucogranites. On the basis of these results, we propose a model whereby LHS hydrous metasediments underwent intense dehydration, with the resultant fluids migrating upward and triggering hydration melting on the edge of melt channel in the GHS. Hence, tourmalines that crystallized from the hydrated magmas inherited the low delta B-11 characteristic of the LHS fluids, whereas those derived from dehydration melting of micas in the interior of melt channel acquired higher delta B-11 values.

    Isotopic constraints on selenium degassing from basaltic magma and near-surface capture by fumarolic deposits: Implications for Se redistribution onto the Earth's surface

    Rosca, CarolinaVlastelic, IvanVaras-Reus, Maria IsabelKoenig, Stephan...
    12页
    查看更多>>摘要:Volcanic emanations from cooling basaltic lava represent a diffuse and relatively poorly constrained source of metallic and non-metallic compounds to the Earth's surface. These compounds become incorporated in fumarolic minerals and redeposit at the surface of lava flows before entering the environmental cycle. The semi-volatile and chalcophile element selenium (Se) can be either vital or toxic to animals and humans. Thus, understanding the pathways of Se capture and relative concentrations in fumaroles is imperative for estimating their contributions to soils and aquifers in volcanically active regions, with implications for animal and human health. In this study, we report Se concentrations and Se stable isotope composition in a sample suite comprising degassed and undegassed basaltic rocks and various fumarolic deposits (thenardite, Na-K sulfate, gypsum, fluoride, and native sulfur) fed from degassing lava flows at Piton de la Fournaise volcano, Reunion Island. Erupted basaltic lavas (136-58 ng.g(-1) Se) lost up to more than half of their pre-eruptive Se due to subaerial degassing and retained a heavier isotope composition (delta Se-82/76 = 0.11 +/- 0.17 parts per thousand, 2 s.d.) compared to less undegassed volcanic glass (138 ng.g(-1) Se and delta Se-82/76 = -0.19 +/- 0.04 parts per thousand, 2 s.e.). Fumarolic deposits that formed over a temperature range of similar to 800-100 degrees C and captured Se from the degassing lava show higher to very high Se concentrations ranging from 0.54 mu g.g(-1) to 1578 mu g.g(-1) and significant Se isotope fractionation (delta(82/76) Se = +0.6 to -2.08 parts per thousand). We propose two separate models that can explain the relative concentration and Se isotope composition of the deposits: 1) A compound oxidation state-dependent Se incorporation into the various fumarolic minerals, or 2) Temperature-dependent Rayleigh condensation from a cooling gas triggered by compound saturation. The Rayleigh condensation model can entirely explain the Se concentration and isotope composition of the fumaroles and predicts that up to 80% of the Se released from the lava is likely to be captured by precipitation to form solid phases within the lava pile, most dramatically in the coldest deposits below the sublimation temperature of SeO2 (< 315 degrees C). In contrast, mineral-dependent isotope pathways cannot fully explain our data, including the lighter Se isotope compositions in the more oxidized compounds compared to more reduced ones. Such a mineralogical effect cannot be excluded but further investigations and experimental studies are required in order to scrutinize and invoke its role. Finally, the environmental impact of these degassing-induced secondary products will be dependent on the relative compound water solubilities resulting in either Se mobilization towards aquifers or accumulation onto developing soils and plants. Such studies could prove useful for developing risk assessments in volcanically active regions on our planet, and for reaching a better understanding of the global continent-ocean Se isotope budget and signature.

    High helium reservoirs in the Four Corners area of the Colorado Plateau, USA

    Halford, D. T.Karolyte, R.Barry, P. H.Whyte, C. J....
    16页
    查看更多>>摘要:Radiogenic He-4 is naturally produced in Earth's crust due to alpha decay of Uranium (U) and Thorium (Th). Helium has unique thermodynamic properties required for the medical imaging industry, aerospace and other fields of high-tech manufacturing, and currently is in increasingly high demand. Despite its economic value, the mechanisms of helium migration and retention in sedimentary basins remain poorly understood. Oil and gas fields with economic helium (>0.3%) concentrations have been discovered in Paleozoic intervals in the Colorado Plateau, southwestern USA. Here we report new noble gas isotope and abundance data for gas samples (n = 31), from actively producing Paleozoic formations within five fields: Ratherford, Tocito Dome, Navajo Springs, Pinta Dome, and Dineh-Bi-Keyah. Helium concentrations range from 0.01% to 7.9% with varying amounts of liquid and gaseous hydrocarbons, N-2, and CO2. We present multi-stage gas, water, and oil equilibration models to account for the observed noble gas elemental and isotopic signatures. Oil-dominated systems are explained by a closed system oil/water equilibration and subsequent admixture of air. He-rich dry gas samples exhibit uniform He-4/N-2 ratios consistent with the regional mean values, suggesting a common crustal source and no subsequent fractionation. In contrast, air-derived Ne-20/Ar-36 ratios are highly fractionated. These observations are consistent with a tectonically controlled crustal gas release from the basement, groundwater saturation with He-4 and N-2, and subsequent degassing. Extensive gas-water interaction (i.e., migration) leads to extreme fractionation of Ne-20/Ar-36, but does not affect He-4/N-2 due to water saturation with crustal gases released from the basement. We show the volume of rock required to have produced helium in the reservoir to be significantly larger than the current reservoir volume immediately beneath the field. Therefore, the reservoir helium concentration cannot be sourced by in-reservoir decay of U and Th and instead requires a process to incorporate exogenous sources of helium in the reservoir without significant dilution from hydrocarbons. For helium-rich fields, excess helium is sourced from the Precambrian granitic basement likely utilizing a large area beneath the field area (i.e., crustal gas mobilization and transport via fracture zones), consistent with the degree of water contact. Deep crustal faults in the Precambrian basement are in close proximity to the high helium fields, indicating that these structures are potentially serving as primary migration conduits via advective fluid flow.

    Permafrost, geomorphic, and hydroclimatic controls on mercury, methylmercury, and lead concentrations and exports in Old Crow River, arctic western Canada

    Staniszewska, Kasia J.Reyes, Alberto, VCooke, Colin A.Miller, Brooklyn S....
    12页
    查看更多>>摘要:Permafrost degradation has been implicated as a dominant control on riverine mercury fluxes in arctic watersheds. However, the importance of permafrost thaw on fluxes of mercury, methylmercury, and trace metals such as lead-relative to other geomorphic and hydroclimatic controls-remains unclear. To investigate these controls, we conducted -weekly water chemistry sampling at the mouth of the Old Crow River, a pristine, 13,900 km(2) watershed in arctic Canada underlain entirely by continuous permafrost. Mercury, methylmercury, and lead concentrations were low on average (similar to 2 ng/L, 0.04 ng/L, 0.8 mu g/L, respectively), and peaked during the freshet (< 7 ng/L, 0.11 ng/L, 11 mu g/L, respectively). The trace elements had strong positive association with suspended sediment, and were mobilized during periods of high discharge (freshet and rainfall). Summer time sampling of major tributaries and at thaw slumps revealed that trace element concentrations were not elevated downstream of thaw slumps or thermokarst lakes across the watershed. Ubiquitous thermokarst in the Old Crow basin did not result in anomalously high catchment-scale concentrations, fluxes, and yields of mercury, methylmercury, nor lead. Rather, warming-driven increases in precipitation and elevated discharge during freshet and rainfall promoted permafrost and talik river bank erosion. This erosion, which was controlled by landscape and geomorphic factors, supplied short-lived increases in particle-bound trace element flux.

    The distribution of intact polar lipid-derived branched tetraethers along a freshwater-seawater pH gradient in coastal East China Sea

    Cao, JiantaoLian, ErgangYang, ShouyeGe, Huangmin...
    13页
    查看更多>>摘要:In view of the application of microbial branched tetraether lipids (i.e., brGDGTs) in terrestrial pH reconstructions, their potential as seawater pH proxy is investigated from the Yangtze River Estuary (YRE) to the shelf region in the East China Sea (ECS). BrGDGTs occurring as 'fossil' core and in 'living' intact polar lipids (CL-brGDGTs and IPL-brGDGTs, respectively) in surface sediments are separately analyzed. The results show that riverine IPL-brGDGTs are rapidly lost at the transition from the YRE to the marine settings and sedimentary IPL-brGDGTs are predominantly produced in situ in brackish water environments. Among environmental parameters, surface water pH is a determinant factor controlling the cyclization of IPL-brGDGTs, with higher cyclization at higher pH. Hereby, two IPL-brGDGTs-based seawater pH calibrations are established in the brackish seawater environment in this study: surface pH = 7.28 + 1.08 x #Rings(tetra) (n = 18, r(2) = 0.87, RMSE = 0.05, p < 0.01) and surface pH = 7.13 + 3.82 x f(Ic) + 4.29 x f(IIb') + 4.21 x f(IIIa) (n = 18, r(2) = 0.90, RMSE = 0.04, p < 0.01), which are different from those established in terrestrial environments. This is the first work demonstrating that in situ produced microbial brGDGTs can trace seawater pH change in marine environment, which makes it promising to apply brGDGTs for seawater pH reconstructions in marine settings where the terrestrial inputs are negligible.

    Detrital orthopyroxene as a tracer of geodynamic setting: A Raman and SEM-EDS provenance study

    Borromeo, LauraAndo, SergioBersani, DaniloGarzanti, Eduardo...
    16页
    查看更多>>摘要:Raman spectroscopy is a powerful and efficient tool that is being used more and more frequently in high-resolution provenance analysis. This study is dedicated to Ca-poor orthorhombic pyroxene, which for its low durability during diagenesis can be considered as a diagnostic first-cycle phase. We focused on 15 samples of modern sands representing a full range of rock units exposed at different structural levels of continental, arc, or oceanic lithosphere and generated in diverse geodynamic settings. By coupling optical observations, SEM-EDS mineral-chemistry and Raman spectroscopy analyses on the same grains we show how orthopyroxene from mantle, deep crustal, and volcanic rocks ranging in composition from andesite to dacite and felsic differentiates can be robustly distinguished. The Mg# [Mg/(Mg + Fe)] content of orthopyroxene grains can be accurately estimated by recording the characteristic position of their six main characteristic peaks (nu(1) to nu(6), vibrational modes) even during routine point-counting under the Raman spectroscope. In particular, the position of the strong and narrow nu(3) peak (similar to 655 cm(-1)) also allows estimation of the Ca content when compared to the position of other peaks (especially nu(1) , similar to 330 cm(-1)). High-Mg orthopyroxene is exclusively derived from mantle rocks, whereas metagabbms of the lower continental crust and gabbroic rocks of arc crust are distinguished by their lower Ca. The lowest Mg# was recorded in detrital orthopyroxene derived from the silicic Amiata Volcano in central Italy, whereas trachytes in rift-related settings did not show unique characteristics apart from their slightly higher Ca content.