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Journal of Petroleum Science & Engineering
Elsevier Science B.V.
Journal of Petroleum Science & Engineering

Elsevier Science B.V.

0920-4105

Journal of Petroleum Science & Engineering/Journal Journal of Petroleum Science & Engineering
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    Pour point depressant efficacy as a function of paraffin chain-length

    Kurniawan, MuhNorrman, JensPaso, Kristofer
    14页
    查看更多>>摘要:Pour point depressant (PPD) activity mechanisms include solubilization, morphology alteration, and steric/entropic repulsion. A wealth of complex intermolecular interactions governs PPD efficacies in real crude com-positions. The current study utilizes single-component model waxes (n-C24H50, n-C28H58, n-C32H66 or n-C36H74) dissolved in dodecane to reveal chain-length dependent PPD efficacies. Wax appearance temperature depression, effected by PPD, diminishes as paraffin chain-length increases. Stronger London van der Waals attractions be-tween longer wax components effectively diminish PPD solubilization activity. Controlled-temperature centri-fugation reveals partitioning of PPD polymers and paraffin waxes between solid and liquid phases. PPD polymers typically contain a polydisperse molecular weight distribution. The highest molecular weight PPD polymers partition preferentially to solid phases, including PPD aggregates and PPD-modified wax crystals. The lowest molecular weight PPD polymers remain preferentially soluble in the liquid phase, binding only weakly to precipitated wax. The presence of precipitated wax counteracts the solubilization activity of PPD polymer. At high precipitated wax fractions, PPD shows no wax solubilization activity. As the precipitated wax fraction decreases, the wax solubilization activity of the PPD progressively increases. The wax solubilization activity of the PPD attains a maximum at the WAT. Finally, the results are consistent with a single optimal polymer mo-lecular weight for PPD activity occurring at a single temperature. PPD polymers larger than the optimal MW undergo a coil-to-globule transition prior to wax crystallization, deactivating the polymer. Polymers smaller than the optimal molecular weight show weaker binding to wax crystals, consistent with a smaller Gibbs free energy of binding, and partition preferentially to the liquid phase. Modern PPD formulations should utilize polymers that are tailored according to molecular weight. Optimally tailored PPD polymers should be less polydisperse in nature than current PPD formulations.

    Highly viscous liquid foam for oil-displacement: Surface & phase behavior enhancement

    Wei, PengZhai, KunyuGuo, KaidiXie, Yahong...
    12页
    查看更多>>摘要:To ensure a sustainable and efficient future, the foam flooding project has been paid more and more attentions to eco-friendly and high stability. Toward this effort, polysaccharides (XG) was applied together with alkyl polyglucoside (APG) to produce a highly stable foam. The properties in both surface and liquid phase were first studied in XG/APG solutions, and the specific characteristics created by XG/APG were then investigated from the aspects of bulk foam stability, coarsening behavior and foam viscoelasticity, after which the microstructure of foam films and the possible intermolecular interactions were inquired. The results indicated that the addition of XG in APG foam can enhance the performance includes both surface elasticity and liquid viscosity aspects, thus producing the high water-carried foam films and the super-low bubble coarsening as a result of the formation of complex aggregations by the hydrogen bonding. It was found that the foam half-life increases dramatically to 60min and the liquid drainage rate is reduced by 90% by adding only 0.1 wt% of XG. Furthermore, XG could successfully stabilize the foam front and substantially promote oil-displacement efficiency by producing a considerable capillary number and viscosity ratio in oil-bearing porous media during the foam flooding, which shows a great potential application in the oil recovery project.

    Estimating shear wave velocity in carbonate reservoirs from petrophysical logs using intelligent algorithms

    Mehrad, MohammadRamezanzadeh, AhmadBajolvand, MahdiHajsaeedi, Mohammad Reza...
    25页
    查看更多>>摘要:Shear-wave velocity (Vs) is a key petrophysical data for a wide spectrum of applications in the upstream oil industry. In many wells, however, the corresponding log cannot be acquired due to technical and/or cost-related issues. Appreciating the importance of this parameter, its relationship to other petrophysical logs has been extensively studied. For the most part, such studies focus on modes based on either rock physics, analytic equations, or artificial intelligence (AI). Inherent complexity of hydrocarbon reservoirs, especially carbonate ones, has made it difficult to build a comprehensive model of adequately high accuracy for various fields, keeping the research on novel models for such a purpose a still hot topic. This paper presents a high-accuracy high-generalizability model for predicting Vs from logging data. The required logs were acquired along three wells penetrating three carbonate reservoirs in SW Iran. In a preprocessing step, a robust regression technique was applied to identify and omit outliers. Subsequently, the data at two wells were used for training the model, with the data at the third well used for validating the trained model. Feature selection was performed by NSGA-II and five parameters were selected (Vp, Depth, RHOB, NPHI, and RT) as inputs to the model. For the first time, we employed the convolutional neural network (CNN) and multilayer extreme learning machine (MELM) in simple and hybrid forms with a few optimization algorithms, including particle swarm optimization (PSO), cuckoo optimization algorithm (COA), and genetic algorithm (GA) to build different models for predicting Vs from logging data. For the sake of comparison, we further applied the least-squares support-vector machine (LSSVM) in simple and hybrid forms with COA, PSO, and GA as well as a couple of popular analytic methods. Results of the training showed the superiority of the CNN, as measured by RMSE. Nevertheless, the MELM-COA model provided for much shorter learning time although its RMSE was only marginally higher than the CNN. Results of the testing phase showed better generalizability and accuracy of the MELM-COA. The same outcome was confirmed in the validation phase. A comparison between the developed IAs and well-known empirical equations showed the higher performance of the IAs. Accordingly, the methodology proposed in this study is highly recommended for estimating the shear-wave velocity at other wells across similar fields provided the model can be trained on a larger set of training data.

    The effect of the structure of functional monomers on the resistance of copolymers to Fe2+ and S2-

    Wu, ChunyuanDong, HaikuanSu, GaoshenYang, Huan...
    11页
    查看更多>>摘要:Free radical solution polymerization method was used to preparing copolymers (FAPAM, IAPAM, and MAPAM) by copolymerizing acrylamide (AM) with functional monomers fumaric acid (FA), itaconic acid (IA) and maleic anhydride (MAH) respectively. The basic parameters of the polymer were characterized by fourier transform infrared spectrometer (FTIR), proton nuclear magnetic resonance spectroscopy (1HNMR), elemental analyzer and ubbelohde viscometer. In polymer flooding, the viscosity reduction effect of Fe2+ and S(2-)in formation water is more serious than that of inert cations, and they have greater impact on oil recovery. Therefore, this paper studied the influence of functional monomers on the structure of polymers and the influence on the resistance to Fe2+ and S(2-)properties of polymers through rheometer, gel permeation chromatography (GPC) and scanning electron microscope (SEM). The results revealed that the intra-chain or interchain forces can be increased to varying degrees by introducing different functional groups into the polymer molecular chains, as a result, the copolymer had different resistance to Fe2+ and S2-. In addition, the carboxyl groups on MAPAM chain were the most evenly distributed, its configuration was the most regular, and its resistance to Fe2+ was the strongest. Relatively, the carboxyl groups on IAPAM macromolecular chain were evenly distributed on both sides of the main chain, and it had the strongest ability to resist S2-. The results of GPC and SEM further proved that the copolymers had the ability to resist Fe2+ and S2-.

    Prediction of split-phase flow of low-velocity oil-water two-phase flow based on PLS-SVR algorithm

    Song, HongweiWang, MingxingLi, MingWu, Chaoquan...
    11页
    查看更多>>摘要:In the middle and late stages of water flooding development in oil fields, oil wells will have the characteristics of low production fluid and high water cut content, making traditional production profile combination instruments unable to meet field needs. In order to accurately obtain the flow rate of each phase of the oil-water two-phase flow under the condition of low velocity, this paper proposes a new production profile logging method that combines an ultrasonic Doppler logging tool and a combined annulus logging tool. The measurement characteristics are verified by simulation experiments. Through frequency spectrum transformation of the original ultrasonic logging data, the power spectrum curve of the oil-water two-phase flow is obtained, the oil frequency, oil amplitude and other parameters are obtained by Gaussian fitting, and the distance analysis of the obtained experimental data is performed to obtain the correlation between the variables. Finally, the PLS-SVR algorithm is used to predict the oil and water flow. The mean absolute percentage error of oil flow is 7.96%, and the mean absolute percentage error of water flow is 9.4%. The prediction results show that the proposed low-velocity oil water two-phase split-phase flow prediction model can meet actual needs, and has higher accuracy than support vector regression (SVR) and back propagation (BP) neural network prediction models, which can provide a new theoretical support for logging interpretation of production profiles.

    Tar mitigation using insitu heat generation chemicals (part I): A comparative study

    Alade, Olalekan S.Mahmoud, M.Al Shehri, D. A.Patil, S....
    9页
    查看更多>>摘要:Tar is an extra-heavy oil with ultra-high viscosity. Accumulation of tar in a reservoir ultimately results in production decline. This study represents the first part of the series of investigation, which aim at developing an insitu heat generation scheme (through thermochemical reaction) for tar mitigation to improve oil production from tarmat-impacted reservoir. Comparative studies have been conducted through both coreflooding experiments and field scale numerical simulation for tar removal using injection of thermochemical fluids (TCF) at 90 degrees C and other fluids, including water (23 degrees C), hot water (90 degrees C), oil soluble organic solvent sludge (90 degrees C) and steam (210 degrees C). The results from coreflooding experiments revealed that TCF injection has comparable removal efficiency in terms of recovery factor (RF = 93%), with that of steam injection (RF = 94%). In comparison, the RF from water, hot water, and injection of an oil-soluble solvent sludge are 21, 53, and 85%, respectively. From the field scale simulation, the results affirmed greater efficiency of TCF injection over steam injection with higher tar recovery rate, recovery factor (RF), and Oil: Steam ratio (OSR). In addition, the simulation results revealed that cyclic injection of TCF outperformed continuous injection operation.

    A fluid dynamic model for Single Well Chemical Tracer tests with variable petrophysical and pre-flushing parameters

    Pedersen, T.
    15页
    查看更多>>摘要:Porosity and permeability are two fundamental reservoir parameters. We study how important large variations in their values are for residual oil saturation estimates from Single Well Chemical Tracer tests. Although porosity and permeability do not enter the classical chromatography formulae, or variations thereof, that does not necessarily imply that they are irrelevant in all real scenarios. This is because porosity and permeability govern how fluids are distributed within the oil-bearing formation, and thus influence dispersion, temperature, rate of hydrolysis of the primary tracer, pH, partitioning etc., all of which may affect the residual oil saturation estimates. We focus on coarsening and fining upwards sedimentary sequences, but we also consider constant porosity scenarios. In addition, we examine how spatial variations in residual oil saturation influence the single value 'average' obtained by the tracer test. The impact of pre-flushing on the estimated residual oil saturation estimate is investigated as well. An axially symmetric finite element model was developed that calculates fluid flow in the wellbore as well as in the oil-bearing target formation; reservoir cooling caused by the injection of cold brine; transport of solutes in the brine; and pH driven changes in the rate of hydrolysis of ethyl acetate. A Reynolds Averaged Navier-Stokes equation with an algebraic turbulence model was applied in the wellbore to calculate fluid flow there, whereas the Brinkman equation was used in the porous target formation. The temperature of the brine pumped into the target as a function of time was calculated analytically for a down casing model. pH changes induced by the acetic acid produced by the hydrolysis of ethyl acetate are buffered by solutes in the injected brine as well as by calcite in the oil-bearing formation were accounted for. The transport of solutes calculations account for fluid advection, diffusion, dispersion as well as temperature dependent partitioning of ethyl acetate between the residual oil and the injected brine. We use test data based on published values and a brine composition that is realistic for a sandstone reservoir. The synthetic tracer production curves generated by the model vary only modestly between the various porosity, permeability, residual oil saturation and pre-flushing models. A simple and widely used chromatography formula was applied to estimate the residual oil saturation from the synthetic tracer curves. This yields 18-19% for all porosity-permeability scenarios when the true constant value is 22%. We also studied six cases with variable Sor. In these cases, the chromatographic formula underestimates the average residual oil saturation by 1-3% except in two models where residual oil saturation increases with increasing porosity; then, the estimate is 8% too low. More work is needed to understand why. In summary, we find that variable porosity and permeability do not significantly increase the estimation error relative to constant models, except when the residual oil saturation varies spatially - then, the error may be much larger. Finally, four pre-flushing models all yield 18% residual oil saturation for a true constant value of 22%, i.e., the error is like the tests without pre-flushing.

    Shale well factory model reviewed: Eagle Ford case study

    Nandlal, KiranWeijermars, Ruud
    11页
    查看更多>>摘要:This case study highlights that shale wells drilled with close well spacing in the same landing zone in the same reservoir rock, using the same fracture treatment plan and parameters, commonly show large variances in well productivity. Searching for the root cause(s) of this variance in performance, we conclude that the factory model - which assumes wells can be engineered in reproducible and identical ways using the same treatment plans - is not yet feasible in practice. A thorough analysis of production data from wells completed in the Eagle Ford Formation shows variations in cumulative oil production cannot be attributed to lateral length, the number of hydraulic fracture stages or fluid/proppant load due to the almost constant values used in keeping with the "Factory Model" drilling method. Based on the dataset available, other parameters for the discrepancies in production volumes are proposed. Some parameters such as (1) reservoir quality and (2) well production control have been determined to have very low impact on production rates variability, while others such as (3) production timing, and (4) water cut may have a more moderate effect. The last defined parameters of (5) fracture quality/performance, and (6) well spacing are determined to have the largest impact on the cumulative production and were concluded to have the highest probability of being the main drivers behind the variations in well productivity. Use of production data with the Complex Analysis Method (CAM) to produce spatial drainage plots also provides insight into recovery factors from these wells. CAM results reveal relatively small, drained rock volumes (DRV) around the modeled hydraulic fractures, which is typical for unconventional shale wells.

    Dynamic modeling of a topside process plant with modified black-oil approach

    Trica, Diego Jose
    12页
    查看更多>>摘要:Modeling and simulation of oil and gas facilities has been done by several authors in closed-source commercial applications, with low flexibility for model adaptation. A few authors used free modeling environments, which results in a differential-algebraic equations (DAE) system and lets the model be adaptable for plantwide simulation. Still, it has limitations in obtaining the model's initial conditions and to perform dynamic simulations when the compositional approach is used. The Modified Black-Oil (MBO) approach, which models the thermodynamic equilibria in a simpler way, has been used by several authors for reservoir modeling but not for topside facilities. This work proposes the use of the MBO approach for topside dynamic modeling. This was done in EMSO (c), obtaining a large index-1 DAE system and successful obtention of consistent initial conditions. Disturbances on specific variables were applied and shows the potential use of the MBO approach for new dynamic studies.

    Vertical and lateral equilibrium in a Lower Cretaceous reservoir

    Baghooee, HadiseMontel, FrancoisShapiro, Alexander
    10页
    查看更多>>摘要:The aim of the study is to find representative fluid samples and study depth gradient and lateral variations in the Lower Cretaceous reservoir. Consistency analysis methods for the samples will be carried out to find representative reservoir fluid samples that can be used in a depth gradient study. Based on the representative samples, it will be analyzed and investigated whether observed compositional variations between samples can be explained by compositional gradients originating from gravitational and/or thermal gradient effects. This work illustrates how a depth gradient analysis can help in understanding fluid communication between the representative samples.