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Industrial Crops and Products
Elsevier Science Publishers
Industrial Crops and Products

Elsevier Science Publishers

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Industrial Crops and Products/Journal Industrial Crops and ProductsSCIISTPEI
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    Production, processing, properties and applications of karaya (Sterculia species) gum

    Prasad N.Thombare N.Sharma S.C.Kumar S....
    15页
    查看更多>>摘要:? 2021 Elsevier B.V.This paper presents a comprehensive review of commercially important exudate gum from the karaya tree (Sterculia species). This gum is naturally available, non- hazardous, cost effective and renewable with unique properties, which make it an ideal choice over other natural or synthetic counterparts for a variety of applications in food, pharmaceutical and alike industries. Owing to a huge demand and high value of this commercially important gum, the karaya trees are being over exploited. To curb the threat to karaya trees in natural habitat, some states in India have banned the commercial production and marketing of this gum. Hence, it is required to establish a balance between gum production and species conservation, which can be done through adopting the scientific tapping methods. This review covers practices followed and past as well as recent research works carried out in production, processing, value addition and application development of this gum. It also presents compiled information on the size and importance of this gum in the world market. This review is likely to help research workers, enthusiasts and end users of natural gums.

    High strength and multifunctional polyurethane film incorporated with lignin nanoparticles

    Wu L.Liu S.Wang Q.Wang Y....
    9页
    查看更多>>摘要:? 2022 Elsevier B.V.Polyurethane (PU) has a wide application in the chemical, electronic and textile industries due to its high ductility, toughness, and good thermal stability. However, the generation of strong and multifunctional PU film is challenging. Herein, lignin nanoparticle (LNP), which was produced from black liquor (i.e., a waste stream from the wheat straw pulping process) using biomass based γ- valerolactone via nanoprecipitation, was used as a nano-filler for enhancing the strength of the PU film. The well distributed LNP had nano-sized particles and abundant phenolic hydroxyl groups, which could act as lubricating agents when incorporated into the PU matrix, thus leading to energy dissipation. By developing additional hydrogen bonds, LNP enhanced the tensile strength and elongation of the PU film. The maximum tensile strength and elongation at break of 50.7 MPa and 755.8% were achieved, while pure PU film had 18.4 MPa and 223.2% tensile strength and elongation, respectively. In addition, the natural inherent properties of lignin endowed the PU film with multifunctional properties, such as hydrophobicity, anti-ultraviolet, and better hydrothermal stability. Based on these interesting results, the LNP incorporation into the PU film could further broaden the practical utilization of the PU film.

    Effects of Kraft lignin and corn cob agro-residue on the properties of injected-moulded biocomposites

    de Baynast H.Tribot A.Audonnet F.Michaud P....
    12页
    查看更多>>摘要:? 2021 Elsevier B.V.Lignocellulosic by-products are frequently disposed by means of combustion. This study investigates an alternative route for corn cob and Kraft lignin resources in order to support circular economy. The respective plant-based fibres and filler were compounded for the first time together with a poly(lactic acid) (PLA) matrix. Consecutively, seven different biocomposites were processed by injection-moulding and further characterized. The biocomposite containing a mixture of Kraft lignin and corn cob (12 wt% in total) exhibited the highest flexural strength (84 MPa). A proper wetting of PLA onto the corn cob particles demonstrated a good compatibility at matrix/fibre interface. PLA molecular structure changed in presence of 20 wt% lignin filler, with effect on the glass transition temperature and on the composite mechanical strength. The fibres moderately influenced composites surface tension, while Kraft lignin contributed to a slight increase of surface hydrophobicity. Surface energy (σsTotal) of composites have been estimated at 27.6, 28.7 and 27.8 mN/m for PLA/KL-20, PLA/CC-10 and PLA/KL-15/CC-5 respectively. While the polar component (σsPolar) have been estimated at 17.8, 20.0 and 18.7 mN/m for PLA/KL-20, PLA/CC-10 and PLA/KL-15/CC-5 respectively. Unlike the PLA/corn cob composite, those containing Kraft lignin were entirely biodegraded within 2 months in industrial composting conditions study. The materials could be utilized for end-use products thanks to their good mechanical and thermal properties. By adding wood-lignin and corn by-products, materials cost and carbon footprint shall decrease in comparison to pure PLA, while being a biodegradable and sustainable replacement of polyolefins.

    Structure and functionality of cassava starch in different deep eutectic solvents/water mixtures: A comparative study

    Zeng L.Mao W.Hao J.Ye G....
    11页
    查看更多>>摘要:? 2021 Elsevier B.V.Starch, as one of the most abundant natural polysaccharides, is regarded as a sustainable material due to its renewability, biodegradability, and modifiability, and is widely used as an excellent industrial material. However, as a polyhydroxyl polymer, native starch has low solubility in most situations due to its network structure formed by intramolecular and intermolecular hydrogen bonds, which limits its industrial application. In this study, the solubility of cassava starch (CS) in a series of acidic, neutral, and alkaline deep eutectic solvents (DESs) was investigated. Relatively high solubilities of 52.8 wt%, 11.4 wt%, and 10.2 wt% were obtained in choline chloride/formic acid (CF), ethylammonium chloride/ethylene glycol (EE), and choline chloride/diethanolamine (CD), respectively. The dissolution behavior of CS in pure mixtures of these DESs and in DESs/water mixtures (2:8) was also compared. The results of gel permeation chromatography (GPC) analysis showed that the weight-average molecular weights (Mw) and number-average molecular weights (Mn) were ranked in the order CF > EE > CD. The same pattern was observed for the DESs/water mixtures (2:8), although the reduction in Mw and Mn was less distinct than in the pure DESs. The results of X-ray diffraction, small-angle X-ray scattering, and scanning electron microscope observations were consistent with the GPC data, i.e., the hydrolysis ability of CS was higher in the acidic DESs (CF) compared to the neutral (EE) and alkaline (CD) DESs. The dissolution behaviors of CS in the DESs/water mixtures were affected by the structure of the DESs and their water content. These results demonstrate that aqueous DESs serve as excellent media for starch dissolution. Moreover, this study provides a comprehensive understanding of the solubilization behavior of CS in different aqueous DESs and provides insights into the development of novel starch-based materials using DESs.

    Understanding pyrolysis mechanisms of pinewood sawdust and sugarcane bagasse from kinetics and thermodynamics

    Wang J.Liu S.Lu J.Zhang P....
    14页
    查看更多>>摘要:? 2021 Elsevier B.V.The kinetics and thermodynamics of biomass pyrolysis are crucial to exploring the reaction mechanisms of biomass pyrolysis and the way forward to design, optimize, and commercialize the processes. The FWO and KAS isoconversional methods and the Kissinger method were usually used to determine the activation energy and frequency factor, respectively. However, those methods would lead to some important errors involved in the activation energy and frequency factor. A new method for estimating the conversion-dependency frequency factor was proposed based on the kinetic compensation effect, empirical kinetic mechanism function, results from the Friedman method and pattern search method since existing methods having some limitations. The thermodynamic parameters were determined using the Eyring theory and obtained activation energy and frequency factor values. This research revealed that (1) The activation energies determined by the Friedman isoconversional method ranged from 180 to 282 kJ mol?1 in the conversion range between 0.05 and 0.95 for the pyrolysis of both biomass samples; (2) The frequency factor values varied from 2.0 × 1011 to 3.0 × 1018 s?1 in the conversion range of 0.05 – 0.95 for the pyrolysis of both samples; (3) The average change in Gibbs free energy was 207.5 and 205.8 kJ mol?1 for the pyrolysis of pinewood sawdust and sugarcane bagasse, respectively; (4) The difference between activation energy and enthalpy for the pyrolysis of both biomass samples was approximately 5.5 kJ mol?1, indicating favorable product formation with considerable bioenergy potential.

    Non-food bioactive product (+)-nootkatone: Chemistry and biological activities

    Fan J.Liu Z.Yan X.Cheng W....
    15页
    查看更多>>摘要:? 2021 Elsevier B.V.(+)-Nootkatone, first isolated from the heartwood of Alaska yellow cedar (Chamaecyparis nootkatensis), is a non-food natural sesquiterpene ketone. Due to its strong grapefruit aroma and wide range of biological activities, there is a growing demand for (+)-nootkatone in the food, cosmetic, pharmaceutical, and chemical industries. Therefore, there is a need to combine the latest and previously available information to understand the research status of (+)-nootkatone and to pave a way for the further development of (+)-nootkatone and its analogs. The present work reviews the research progress in the plant sources, chemical synthesis, biosynthesis, and structural modifications of (+)-nootkatone, and the pesticidal and other physiological activities of (+)-nootkatone and its derivatives. We hope this work can provide a reference for the further application of (+)-nootkatone and its analogs in the food, cosmetic, pharmaceutical, and chemical industries.

    Improving biodegradability of corn stover pretreated by different organic acids: Investigation on the hydrolysis/acidification and methanogenic performance

    Li Y.Fang X.Hua D.Xu H....
    10页
    查看更多>>摘要:? 2021 Elsevier B.V.Lignocellulosic materials (LM) are abundant bioenergy resources for renewable energy development. Pretreatment using organic acids including acetic acid (HAc) and butyric acid (HBu) was applied to reduce the recalcitrance of LM in methane production by two-phase anaerobic digestion (AD). The structural and compositional changes of solids and aqueous phase were analyzed. It showed that pretreatment with 2 g/L HAc/HBu at 120 °C was optimum, under which the net volatile fatty acids (VFAs) production could reach the maximum concentration of 11.5 g/L. The yield of VFAs decreased with the concentration increasing to > 2 g/L due to the feedback inhibition on the microbial metabolism. The species of organic acids also influenced the metabolic pathway of VFAs. The acidogenic metabolites can be transformed in up-flow anaerobic sludge bed (UASB) with organic loading rate (OLR) up to 12 g COD/Ld (COD, chemical oxygen demand). The hydrothermal-organic acid pretreatment (HTOAP) could provide important information for subsequent application.

    Ethanol production from Agave tequilana leaves powder by Saccharomyces cerevisiae yeast applying enzymatic saccharification without detoxification

    Avila-Gaxiola J.C.Avila-Gaxiola E.
    7页
    查看更多>>摘要:? 2022The replacement of fossil resources with renewable biomass in a bioeconomy is seen as a major contribution to climate change mitigation. The transformation from a petrochemical-based economy to a bio-based economy necessitates the novel exploitation of cost-effective natural materials for both future biorefinery development and a range of value-added products of interest. The present investigation proposes the use of Agave tequilana Weber leaves, an agro-industrial residue with a huge potential to produce liquid biofuels. The objective of the present work is to evaluate the alcoholic fermentation by S. cerevisiae yeast in powdered A. tequilana leaves (dry-mill,100 °C, diameter ≤ 300 μm) pretreated with two enzymatic saccharification processes without detoxification and determine the highest yield bioconversion of sugars to ethanol. Alcoholic fermentation was evaluated using yeast at different times (0?42) h with an initial concentration of 34.06 ± 0.4 g/L reducing sugars. S. cerevisiae has the highest ethanol production 12.20 ± 0.3 g/L within 18 h obtained an ethanol yield of 0.41 g/g (81% of theoretical value), and volumetric ethanol productivity 0.68 ± 0.02 g/L/h. Yeast was able to consume the 86.4% reducing sugars and increase to 17.2-fold cell concentration in the presence of 80.30 ± 0.70 mg/L phenolic compounds. This biotransformation of waste has great potential and significant prospects for wider industrial and biotechnological applications, the results show the feasibility and efficiency to produce ethanol, is a clean source of energy and offers a solution for countries that produce agave or similar feedstocks. It is firmly believed by the author that, due to the large amounts of waste produced by the tequila industry, the best solution for this problem does not lie in this paper or implementation of a single treatment. On the contrary, a mix of some of the alternative treatments presented in other works would probably represent the most efficient option, from both an economic and environmental point of view.

    Long-term cotton stubble return and subsoiling increases cotton yield through improving root growth and properties of coastal saline soil

    Zhang L.Mao L.Yan X.Liu C....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.Short-term cotton stubble return increased cotton yield in coastal saline soil. Due to high groundwater level, salt return from deep soil would affect the sustainability of long-term cotton stubble return on the improvement of soil properties and yield in coastal saline soil. However, subsoiling can cut off the capillary and inhibit the seasonal salt return. Here we quantified the effects of long-term cotton stubble management (removal or return) and tillage (non-subsoiling or subsoiling) on soil properties, root growth and cotton yield. Cotton yield increased 36.3.% after stubble return than after stubble removal, and enhanced 22.8% after subsoiling compared to non-subsoiling. Structural equation model showed that stubble return increased cotton yield by reducing salt content, pH and bulk density, increasing total porosity, small macro-aggregates, root weight density (RWD) in the topsoil, total organic carbon (TOC), nitrogen (N), and their fractions in both layers, while subsoiling increased yield by reducing salt content, pH and bulk density, and increasing total porosity, small macro-aggregates, RWD in the subsoil. Compared to stubble removal, TOC, dissolved OC (DOC) and microbial biomass C (MBC) increased 54.3%, 33.2% and 24.8% in the topsoil, 37.4%, 18.8% and 39.1% in the subsoil after stubble return. Stubble return increased TN and its fractions in the topsoil, and DON, MBN, ammonium nitrogen in the subsoil compared to stubble removal. Maximum root shoot ratio can be obtained only when two measures are combined. Combination of stubble return and subsoling increased yield by optimizing soil properties and root growth in two layers, which is much better than only stubble return or subsoiling. Our analyses demonstrate combination of cotton stubble return and subsoiling can increase cotton yield and be widely applied as an effective measure in coastal saline fields.

    Integrating mild chemical pretreatments with endogenous protein supplement for complete biomass saccharification to maximize bioethanol production by enhancing cellulases adsorption in novel bioenergy Amaranthus

    Madadi M.Wang Y.Zhang R.Hu Z....
    11页
    查看更多>>摘要:? 2021 Elsevier B.V.Amaranthus is a fast-growing perennial plant containing large amounts of extractable green proteins and lignocellulose residues. However, it remains to explore optimal Amaranthus biomass process technology for biofuel production. In this study, we examined that mild alkali and acid pretreatments (1% NaOH, 2% H2SO4) were sufficient for near-complete biomass enzymatic saccharification, while 8% Amaranthus endogenous proteins were supplemented into the enzymatic hydrolyses. By performing classic yeast fermentation with all carbon sources from directly-extractable sugars and starch and lignocellulose enzymatic hydrolysis, this work achieved the bioethanol yield up to 23.5% (% dry matter). Notably, with respect to extremely high yield of Amaranthus straw, the maximum bioethanol yield was estimated at 14.46 t/ha/year, which was much higher than those of other major bioenergy crops as previously reported. Furthermore, this work proposed a hypothetic model to elucidate how the complete biomass saccharification was achieved to maximize bioethanol production at large scale, based on the effective wall polymer extraction and distinct lignocellulose feature modification for remarkably enhanced biomass porosity and cellulases adsorption. Hence, this work has demonstrated that Amaranthus could be applied as a novel and leading bioenergy crop, providing a powerful strategy for optimal biomass processing towards high bioethanol production.