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Industrial Crops and Products
Elsevier Science Publishers
Industrial Crops and Products

Elsevier Science Publishers

0926-6690

Industrial Crops and Products/Journal Industrial Crops and ProductsSCIISTPEI
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    LAI and biomass of kenaf as affected by sowing time and plant density: A simple model simulates the time course in a Mediterranean environment

    Corinzia S.A.D'Agosta G.Cosentino S.L.Scordia D....
    12页
    查看更多>>摘要:? 2022 Elsevier B.V.Kenaf (Hibiscus cannabinus L.) is a warm-season annual plant grown in the past for the bast fiber. In the last decades, this crop has been re-evaluated for many alternative industrial uses of its biomass (i.e., production of biofuel, biocomposite materials, bioproducts). In this paper, the interaction effects of sowing time (May and June) and plant population (P20 and P40, 20 and 40 plants m-2, respectively) on yield and some biomass parameters were analysed in two cultivars of kenaf (Tainung 2-TAI, and Everglades 41-EVER), in a two-year experiment in semi-arid environment, under irrigation. The aim of this paper was to assess the potential of this crop as an energy or industrial feedstock, in south Mediterranean environment where was never cultivated. Overall, plants from late sowing (June) were smaller and with less node, those at high plant density (P40) were thinner. In both seasons, plants of TAI were taller than those of EVER. Plant weight was greater in P20, and an overall significant negative correlation was found between plant weight and actual plant density (r = ?0.76 **). The shift of sowing time reduced significantly the final dry biomass. Crop productivity did not change with plant density, however a higher percent bark corresponded to P40 in both years, cultivars, and sowing times, A simple model was developed to simulate and predict the course of LAI and dry biomass (AGB) with time, using field dataset of 2004, for calibration, and dataset of 2005, for validation. The minor response of LAI to plant population in 2005 led to a low accuracy of model approximation. This result suggests that other variables that are not considered in the model, may influence LAI. Nevertheless, the overall AGB model approximation of observed value was accurate. Concluding, the results revealed that biomass productivity is more influenced by sowing time than by plant density. However, plant population has been found to regulate the proportion of bark/core layers, with important implications for industrial (energy and pulp production) purposes. Further improvements on the simple model developed, e.g., including soil water nitrogen balances submodels, may be done, in order to explore the possibility of using the model under different conditions of soil water content and nitrogen fertilization.

    Agronomic performance of camelina genotypes selected for seed yield and quality characteristics in eastern China

    Gao Y.Zhang Y.Wang Y.Diao J....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.Camelina [Camelina sativa (L.) Crantz] has gained extensive attention in Europe and North America as a potential dietary oil and biofuel feedstock. It is a relatively new crop in Asia (e.g., China, Korea). There is great potential for the cropping of camelina in eastern China on marginal lands where the climatic conditions (e.g., cooler temperature) may be suitable for cultivating this crop. However, little has been done to evaluate its agronomic performance in eastern China. To address this, a three-year (2019–2021) field study was conducted to evaluate the effect of fall and spring seeding dates on seed yield and quality of sixteen spring camelina genotypes across the three different growing environments in eastern China and to select potentially high-yielding genotypes for fall or spring seeding with the suitable seeding dates for each growing environment. The study showed that fall seeding camelina between late Oct. and the third week of Nov. in eastern China, including Anyang, Qingdao, and Yangzhou, produced a sustainable and satisfactory seed and oil yield (mean across genotypes, locations, and years: 2372 and 921 kg ha?1, respectively). While spring seeding between mid- and the end of April at Qingdao showed a lower productive performance (mean seed and oil yield across genotypes: 1081 and 373 kg ha?1, respectively), it still provides an alternative option for the production of high-quality edible oil compared to other oilseed crops such as soybean [Glycine max (L.) Merr.]. Although the strong genotype × environment interactions showed, among the tested camelina genotypes, fall seeding camelina accessions of CamK9, CamC2, and CamC4 at the suitable seeding dates showed a consistently greater mean seed yield (range: 1648–3170 kg ha?1) and oil yield (747–1368 kg ha?1) in all test locations compared to other genotypes. At the suitable fall seeding dates, mean seed oil content and yield across the tested genotypes and locations were 43.5% (range: 39.0–48.9%) and 856 kg ha?1 (range: 161–1489 ha?1), respectively, with the highest mean oil content of 45.9% determined at Yangzhou (range: 43.6–48.9%) and the highest mean seed yield of 2539 kg ha?1 at Qingdao (range: 1365–3501 kg ha?1). The camelina genotypes indicated would be good candidates for large-scale cropping in eastern China and other parts of the world with similar climatic conditions.

    Switchable photochromic transparent wood as smart packaging materials

    Liu L.Zhu G.Chen Y.Liu Z....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.Transparent wood (TW) has been developed to combine the optical and functional aspects of wood. Many efforts have been dedicated to adding quantum dots, nanoparticles, or dyes to TW to provide additional functionalities, such as luminescent, electrochromic, thermochromic, and photo-switchable TW. However, the UV shielding performance and its new application of transparent wood are needed to explore. Herein, we report a photochromic transparent wood (PTW) by incorporating poly(methyl methacrylate) and UV/visible light switchable molecules into the delignified wood template. The focus is to investigate the relationship of process-structure-property of the PTW. The dispersion of photochromic molecules in PTW is shown by using energy-dispersive X-ray spectroscopy. The transmittance and the color of the PTW are switchable under UV and visible light excitation due to a change from the closed-ring to the open-ring form. Moreover, the PTW was found to possess, UV shielding performance, favorable thermal and mechanical properties, as well as excellent dimensional stability. We also demonstrate the potential smart packaging application of the UV-blocking PTW. We envision this PTW could be utilized for anti-counterfeit materials, intelligent sensors, and smart indicators.

    Integrating metabolomics and transcriptomics to unveil the spatiotemporal distribution of macrocyclic diterpenoids and candidate genes involved in ingenol biosynthesis in the medicinal plant Euphorbia lathyris L.

    Zhao W.Xu Y.Xue J.Peng J....
    14页
    查看更多>>摘要:? 2022 Elsevier B.V.Macrocyclic diterpenoids, such as ingenol, are the main bioactive ingredients in Euphorbia lathyris L. Ingenol is the precursor for industrial production of ingenol-3-angelate, which was approved for the treatment of actinic keratosis in 2012. However, the distribution and biosynthesis of macrocyclic diterpenoids, especially ingenol, during the growth cycle of E. lathyris L. are largely unknown. To investigate the dynamics of the distribution of macrocyclic diterpenoids in different tissues across the entire life cycle of E. lathyris L. and candidate genes involved in their biosynthesis, combined metabolome-transcriptome analysis was performed. A total of 144 samples collected from different tissues covering the whole life cycle of E. lathyris L. were detected by high-performance liquid chromatography quadrupole-time-of-?ight mass spectrometry (HPLC-QTOF-MS/MS). Next, 67 macrocyclic diterpenoids were profiled via MS/MS characteristic ions, and their dynamic distributions were analyzed. The results indicated that macrocyclic diterpenoids mainly accumulated in the roots and seeds of E. lathyris L. To gain insight into ingenol biosynthesis, transcriptome sequencing of different tissues from mature E. lathyris L. was carried out, and a total of 50,177 ? 69,999 unigenes were annotated. Subsequently, weighted gene coexpression network analysis (WGCNA) was performed, candidate genes with high potential of involvement in ingenol biosynthesis were obtained. This study provides a basis for further research and utilization of macrocyclic diterpenoids in E. lathyris L. and benefits the green production of ingenol.

    Eco-friendly and mildly modification of wood cell walls with heat treated wood extracts to improve wood decay resistance

    Bi Z.Lei Y.Yan L.Ji M....
    7页
    查看更多>>摘要:? 2022 Elsevier B.V.Wood protection using plant-derived extracts has shown some promise but the extracts are often easily leached making them less attractive for long-term wood protection. The potential of extracts from heat treated wood sawdust as a natural substitute for wood preservatives was explored, and a mild enzyme-catalyzed method was used to improve its leaching resistance. Laccase was used to catalyze grafting reactions of extracts from heat treated spruce (Picea asperata Mast.) and larch (Larix gmelinii (Rupr.) Kuzen.). The resulting extracts were screened for antifungal activity and then impregnated into poplar blocks (Populus tomentosa Carr.). Fourier Transform Infrared Spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to characterize extracts reactions. Gas chromatography-mass spectrometry (GC-MS) was used to analyze the grafted compounds. Acetone extracts from both heat treated spruce and larch exhibited good activity against the test fungi. Heat treated spruce and larch acetone extracts grafted on modified poplar and subjected to leaching showed better activity against the white-rot fungus, Trametes versicolor (L. ex Fr.) Quél. than the brown-rot fungus, Gloeophyllum trabeum (Pers.: Fr.) Murr. FTIR and XPS results indicated that heat-treated spruce and larch extracts were grafted on poplar by laccase catalysis. Squalene, 3-hydroxy-4-methoxybenzoic acid, and n-hexadecanoic acid were among those compounds suggested to be grafted. The results suggest that laccase-mediated pre-treatment of plant extracts has the potential to increase resistance to leaching. Trials with additional plant-extracts are recommended.

    Molecular genetic diversity analysis using SSR marker amongst high solasodine content lines of Solanum khasianum C.B. Clarke, an industrially important plant

    Munda S.Begum T.Pandey S.K.Bhandari S....
    9页
    查看更多>>摘要:? 2022 Elsevier B.V.Solanum khasianum C. B. Clarke contains a pharmaceutically useful alkaloid, solasodine, which is mainly used for the synthesis of steroid hormones. In this study, a total of 273 accessions were collected from nine states of India and planted at experimental farm of CSIR-NEIST, Jorhat, India. After screening, 180 lines containing > 0.8% solasodine were further used for the assessment of genetic diversity using 59 SSR primers. An average of 78.21% polymorphic alleles was obtained from the studied primers out of which 17 primer pairs can be recommended as most efficient primers. The dendrogram based on UPGMA method grouped the 180 accessions into three clusters. To further confirm the clustering of the accessions, principal component analysis (PCA) plot was constructed. The interesting fact in this study is that the rich solasodine lines > 1% is clustered together based on their geographical locations. The analysis of molecular variance showed the diversity amongst the studied populations to be 20% and within the populations 80%. The analysis of genetic diversity parameters revealed effective number of alleles (Ne) of 1.39, Nei's gene Diversity (He) of 0.23 and Shannon's diversity index (I) of 0.36. Dendrogram constructed to check the relationship among the collection site of the accessions revealed high divergence between the population of Mizoram and Himachal Pradesh. The hybridization of the divergent lines can help identify genes for solasodine content and alleles for high content. Linkage disequilibrium and association analysis further identified two SSR primers associated with solasodine content. To date there are no reports regarding the genetic diversity analysis of S. khasianum; this is the first study on genetic relationships amongst 180 high solasodine lines of this species using SSR marker.

    Long term antibacterial effect cellulose film was modified with polyhexamethylene biguanide (PHMB)

    Song X.Zhang L.Wang Y.Zhao R....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.Cellulose products such as textile, paper, package and so on are apt to breed bacterial. In this study, AA-PHMB antibacterial agent was synthesized innovatively. It was grafted onto cellulose by the addition polymerization of carbon carbon double bonds and hydroxyl groups to prepare cellulose antibacterial film with excellent performance. The structures, elements, mechanical properties and antibacterial activities of films were studied. The results showed that C[dbnd]N absorption at 1631 cm?1 of guanidine and the amide group absorption peak at 1554 cm?1 appeared on cellulose graft copolymers; employing SEM-EDS, a great quantity of deposited materials, with the elements of C, O and N, were observed on the grafted cellulose. The graft percentage of cellulose-AA-PHMB was about 62%. Compared with unmodified cellulose films, the mechanical properties of PHMB-AA-cellulose film were lower, and the crystallinity of the PHMB-AA-cellulose film was lower than that of original cellulose film. The modified film as a raw material had a good inhibitory effect on Escherichia coli and Staphylococcus aureus was proved by bacteriostatic experiments. Under the condition of continuous culture for 15 days, it still had a good bacteriostatic effect on the above strains, and therefore the cellulose-AA-PHMB films were long term antibacterial effect materials.

    Efficient extraction of polysaccharides from Lycium barbarum L. by aqueous two-phase system combined with tissue-smashing extraction

    Hu J.Liu J.Huang X.Di D....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.An effective method based on tissue-smashing extraction assisted aqueous two-phase system (TSE-ATPS) was developed for extracting Lycium barbarum L. fruits polysaccharides (LBPs). The ethanol/salt aqueous two-phase system (ATPS) composed of three different salts was evaluated, from which the system of 17.86% (NH4)2SO4 (w/w) and 28.86% ethanol (w/w) was chosen. The conditions were as follows: solid-to-solvent ratio 1:30 (m/v), tissue-smashing power 8000 rpm (8 krpm), extraction time 4 min and the extraction yield of LBPs was 24.79 mg/g. Compared with hot water extraction (HWE) and ultrasound-assisted extraction (UAE), TSE-ATPS ((NH4)2SO4/ethanol) improved the extraction yield of LBPs. LBPs extracted using various methods have different chemical structures and monosaccharide compositions. Superior antioxidant activity was demonstrated when the ATPS was composed of K2HPO4/ethanol and NaH2PO4/ethanol. Therefore, as an innovative, promising, and rapid crushing extraction technology, TSE-ATPS provides a better choice for extraction and separation of polysaccharides from natural products.

    NIR spectroscopy for rapid measurement of moisture and cannabinoid contents of industrial hemp (Cannabis sativa)

    Su K.Tan J.W.Yoon J.Y.Hildebrand D....
    15页
    查看更多>>摘要:? 2022 Elsevier B.V.With the legalization of industrial hemp in the United States, defined based on tetrahydrocannabinol (THC) dry weight content of ≤ 0.3%, the market for various cannabinoids including cannabidiol (CBD), cannabinol (CBN), cannabigerol (CBG), and cannabichromene (CBC) have flourished. The current measurement methods such as ultra-high performance liquid chromatography and gas chromatography (GC) require sophisticated instruments and trained personnel and are time-consuming. Therefore, there is a critical need for a rapid and reliable method to measure cannabinoids for regulatory compliance, determination of usage, and for quality control. Here, we report the use of near-infrared spectroscopy (NIRS) for rapid measurement of moisture content (MC) and cannabinoid contents of ground and whole hemp and rapid identification of legal from illegal industrial hemp. Good NIRS quantitative predictions were obtained for MC of ground and whole hemp, THC of ground hemp, CBD of ground and whole hemp, and CBC of whole hemp. Binary classification of industrial hemp as legal (≤0.3% THC) or illegal was performed using discriminant analysis and thresholding models. Discriminant calibration models developed showed correct classifications (CC) ranging from 93.0% to 94.0% with CC for independent validation at 83.9–87.5%. The concurrent multi-constituent predictions of MC and THC using NIRS allows for real-time adjustments of cannabinoid contents and rapid identification of legal or illegal hemp. These are important tools that will benefit the hemp industry, regulators, farmers, and consumers.

    Preparation of Al-loaded magnetic Chinese medicine residue-derived biochar and application of it in fluoride removal

    Tie J.Sang S.Li Y.Xu Z....
    12页
    查看更多>>摘要:? 2022 Elsevier B.V.The development and application of new materials for the extreme fluoride pollution problem has drawn increasingly wide attention. Here, Chinese medicine residue, FeSO4.7 H2O, FeCl3.6 H2O and Al(NO3)3 were used as raw materials to create an novel Al-loaded magnetic Chinese medicine residue-derived biochar (Al/Fe3O4/CMRB) adsorbent for effective fluoride adsorption. Al/Fe3O4/CMRB was characterized and used to conduct fluoride adsorption. In the pH range of 4–11, the fluoride adsorption reduced from 37.38 mg/g to 15.84 mg/g. The pseudo-second-order equation and Freundlich equation was the ideal model to describe the adsorption. The thermodynamic study confirmed the spontaneous and exothermic nature of fluoride adsorption by Al/Fe3O4/CMRB. Chloridion, nitrate, and sulfate had no influence on fluoride adsorption when a single anion and all three anions were present. phosphate created a more significant reduction of fluoride adsorption with rising concentrations, whether or not the other three anions were present. Al/Fe3O4/CMRB was an potential composite for aqueous fluoride removal. In addition, Al/Fe3O4/CMRB showed high separation efficiency in a contactless magnetic field, which demonstrated its potential use for large-scale applications in real samples.