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Industrial Crops and Products
Elsevier Science Publishers
Industrial Crops and Products

Elsevier Science Publishers

0926-6690

Industrial Crops and Products/Journal Industrial Crops and ProductsSCIISTPEI
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    A novel bamboo engineering material with uniform density, high strength, and high utilization rate

    Luan Y.Ma Y.-F.Liu L.-T.Fei B.-H....
    9页
    查看更多>>摘要:? 2022 Elsevier B.V.Bamboo has attracted much attention and gained economic and environmental values for its excellent properties such as fast growth, short rotation, sustainability, and high strength. One of the bamboo engineering products most widely used in construction, furniture, etc. is the laminated bamboo board which is made of bamboo strips. However, the arc-shape makes bamboo strips must be planed on four sides to be rectangular before assembling and gluing. After the quadrilateral planning process, a large part (60–70%) is removed. On the other hand, due to the non-uniform distribution of vascular bundles, bamboo is characterized by heterogeneity confined to decreased density and mechanical strength from the outer to the inner part, which causes the difficulty of stable quality control of engineered bamboo products. To increase the rate of bamboo utilization and achieve the goal of homogenization, this study proposed an integrated thermo-hydro-mechanical treatment combining flattening and homogenization on arc-shaped bamboo strips. Fresh bamboo strips with 70% moisture content were compressed at 170 °C with customized vapor releasers for 20 min. After the integrated treatment, arc-shaped bamboo strips were flattened and densified with a compression set of around 44%. The average density reached up to 1.10 g/cm3 from 0.67 g/cm3. And treated bamboo exhibited a relatively uniform density throughout its thickness. The increases of fiber bundle fraction and the density of parenchyma tissues were basic reasons for the density homogenization. The longitudinal tensile tests showed that the treated bamboo had remarkable mechanical performances. After treatment, tensile strength and modulus of elasticity (MOE) of bamboo increased by 52.6% and 35.4%, respectively.

    Green biomass quality of perennial herbaceous crops depending on the species, type and level of fertilization

    Peni D.Stolarski M.J.Debowski M.
    9页
    查看更多>>摘要:? 2022 The AuthorsThe characteristics of biomass as renewable energy or bioindustry feedstock are very important from their final utilization point of view. This study aimed to evaluate the effects of fertilization on biomass characteristics and chemical composition during three-year field and laboratory trials. Two perennial herbaceous crops (Silphium perfoliatum L. and Helianthus salicifolius A. Dietr.) cultivated using different types (organic and mineral) and doses (0, 85, 170 kg ha–1 N) of fertilizers were investigated. The analyzed factors significantly influenced most of the investigated features of collected biomass. The application of fertilizers increased the fixed carbon and volatile matter content, higher heating value, chlorine, hemicellulose and cellulose content. The moisture content of green S. perfoliatum biomass harvested in September (75.8%) was 14.78% higher than in the case of H. salicifolius. The highest higher heating value (18.69 MJ kg–1 DM) and the lowest ash content (mean 4.72% DM) was obtained from H. salicifolius for the biomass fertilized at a dose of 170 kg ha–1 N with mineral fertilizer. Under mineral fertilization, the highest carbon content (47.88% DM) was obtained from H. salicifolius. However, the total nitrogen content in the S. perfoliatum biomass was the highest (1.41% DM) in 2019 for biomass treated with mineral fertilization in the dose of 170 kg ha–1 N. The highest content of hemicellulose (15.36% DM) was noted in H. salicifolius biomass, while cellulose and lignin contents were higher in S. perfoliatum (24.47% and 8.29% DM, respectively).

    One step synthesis of Mo-doped carbon microspheres for valorization corncob to levulinic acid

    Li X.Xu H.Hu W.Zhou H....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.This work presents the catalytic valorization agricultural waste into levulinic acid over Mo-doped carbon microspheres (MoCMP) in γ-valerolactone/water solvents. The MoCMP with Br?nsted and Lewis acid were synthesized by hydrothermal carbonization of uncrystallized cellulose with phosphomolybdic acid in one step, which was in absence of any additional modification. The MoCMP catalyst displayed a peak levulinic acid yield of 33.02% at 195 ℃ for 90 min. The improvement of Lewis acid sites was related by the Mo2C and Mo6+ species to promote the isomerization of glucose to fructose. The enhanced strong Br?nsted acid sites were generated by carboxyl groups to facilitate the glucose dehydration to levulinic acid. MoCMP provided a high catalytic efficiency for production of LA from corncob. A simple and green method was proposed to synthesize Mo-doped carbon microspheres for valorization of agricultural biomass into valuable chemicals.

    Floral volatile chemical diversity in Hedychium F1 hybrid population

    Zhou Y.Abbas F.He J.Yan F....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.Floral scent profiles play crucial role in the ornamental values of cut flowers, and efficient floral scent profiling acquisition is a critical premise for quality assessment and genetic improvement of fragrant cut flowers. Despite the fact that cross breeding is an effective method for improving the fragrance of cut flowers, less focus has been paid on floral scent evaluation in cross populations due to the complexity of fragrance phenotype detection. In the current study, floral scent profile of Hedychium coronarium 'ZS', H. 'Jin' and their 110F1 hybrid cultivars were evaluated. Headspace solid phase microextraction- gas chromatography-mass spectrometry (HS–SPME–GC–MS) identified 33 volatile organic compounds (VOCs), including 15 monoterpenoids, 7 sesquiterpenoids, 9 phenylpropanoids, 1 fatty acid derivative, and 1 other, while proton transfer reaction-time of flight-mass spectrometry (PTR–ToF–MS) detected 68 masses. Correlation analysis indicated that β-myrcene, α-terpinene, eucalyptol, (E)-β-ocimene, cyclopentene, 3-isopropenyl-5, 5-, allo-ocimene, indole, isoamyl benzoate, (E)-β-famesene, m/z 74.069 and m/z 118.069 played an important role in sensory concentration of Hedychium flowers fragrance. Furthermore, partial least squares (PLS) analysis of VOCs and masses revealed that 44 masses were highly sensitive to 21 VOCs (8 monoterpenoids, 6 sesquiterpenoids, 5 benzenoids/phenylpropanoids, 1 fatty acid derivative, and indole). Overall, the data showed that two mass spectrometric methodologies were highly complementary, revealing a novel and dynamic perspective on volatile complex diversity of Hedychium F1 hybrid population cut flowers.

    High-performance polylactic acid compressed strawboard using pre-treated and functionalised wheat straw

    Chougan M.Ghaffar S.H.Mijowska E.Kukulka W....
    12页
    查看更多>>摘要:? 2022An eco-friendly pre-treatment coupled with surface functionalisation were developed to enhance the quality of wheat straw particles to be used for development of high-performance polylactic acid (PLA) compressed strawboard. Eco-friendly hybrid pre-treatment (i.e., hot water followed by steam, H+S) and surface functionalisation processes employing attapulgite nanoclay (AT) and graphene nanoplatelets (G) were used to obtain an appropriate wheat straw surface quality while increasing its compatibility with the PLA matrix. The successful pre-treatment and surface functionalisation of wheat straw particles was verified through characterisation techniques, including SEM, FTIR, XRD, Raman spectroscopy, and TGA. Tensile strength and water absorption properties of compressed strawboards were examined to investigate the influence of pre-treatment and surface functionalisation of wheat straws. The maximum tensile strengths of 28 MPa and 27 MPa were recorded for 10 H+S-AT and 10 H+S-G samples, respectively, which are considerably higher than the value (i.e., 9.7 MPa) registered for the sample without pre-treatment and surface functionalisation (i.e., 10UN). The lowest water absorption after 24 h of immersion was registered for 10UN-G (i.e., 1.6%), which is 11% and 31% lower than the 10UN and 10 H+S samples, respectively. The effect is attributed to an improved interfacial bond between wheat straw and PLA matrix due to the graphene surface functionalisation, as evidenced by the SEM.

    Aqueous two-phase simultaneous extraction and purification of a polysaccharide from Grifola frondosa: Process optimization, structural characteristics and antioxidant activity

    Mao G.Chen Y.Feng W.Wu X....
    8页
    查看更多>>摘要:? 2022 Elsevier B.V.Traditional method for Grifola frondosa polysaccharide (CGFP) separation is water extraction or other method assistance, ethanol precipitation and further purification via column chromatography. Due to the strict control conditions, inefficient and not environmental-friendly, the method is hard to scale up and implement, and even limited the biological activity study and application of Grifola frondosa polysaccharide. Therefore, an ammonium sulfate/ethanol aqueous two phases (ATPS) was developed to extract and preliminary purify the polysaccharide from Grifola frondosa (GFPA). The optimized conditions were concluded as the ATPS composition of ammonium sulfate 17% and ethanol 27.9%, extraction pH 3.22 based on single-factor and response surface methodology experiments. Under this condition, the recovery yield and content of GFPA were 90.21% and 66.7%, respectively. The structural characteristics investigation revealed that GFPA exhibited a slight change in weight average molecular weight (Mw), molar ratio of monosaccharide and microstructure as compared to CGFP. Results indicated that the Mw of GFPA was 2.954 × 106 Da, which was lower than that of CGFP. Both of them are heteropolysaccharides with pyranose ring, and mainly composed of glucose. GFPA exhibited a rod shape and reticular structure with smooth surface, while CGFP showed a rough surface. Also, Congo red test indicating the presence of triple-helix structure in both of them, while AFM observation suggesting a spherical structure tended to aggregate occurred. The chemical antioxidant activities of GFPA were increased in a dose-dependent manner. Moreover, GFPA can effectively prevent RAW264.7 cells from H2O2-induced damage through reducing the release of MDA, LDH and ROS, and enhancing the levels of SOD, CAT and GSH-Px. Furthermore, GFPA showed more significant and effective than CGFP at all the tested dosages. Thus, it can be seen that the ATPS method established in this paper possess the merits of efficient, environmental-friendly and simple operation, which can successfully be applied for Grifola frondosa polysaccharide large scale separation, and make the application of GFPA possible. It has reference value for other large-scale polysaccharide separation. The resulting also revealed that GFPA has the potential value of developing as a natural antioxidant agent.

    Effects of pith ring on the hygroscopicity and dimensional stability of bamboo

    Wang X.Zhang S.Chen L.Huang B....
    17页
    查看更多>>摘要:? 2022 Elsevier B.V.The pith ring is an important component of bamboo, which is located on the inner side of the culm wall. However, the effect of pith ring on bamboo properties is unclear. The study aimed to analyze the influence of pith ring on the hygroscopicity and dimensional stability of bamboo. The study used X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) to measure the crystallinity and chemical composition of bamboo pith ring and middle layer. The scanning electron microscopy and high-resolution computed tomography to observe the morphology of bamboo pith ring and parenchyma. The analysis showed a higher crystallinity and lignin content for the pith ring than the middle layer. In addition, the analysis revealed that the pith ring and the middle layer formed a criss-cross structure. The existence of the pith ring reduced the hygroscopicity and hygroscopicity hysteresis to a certain extent. In fact, the pith ring improved the dimensional stability of bamboo in radial and tangential directions, while it slightly reduced the dimensional stability in the longitudinal direction. These observations indicate that the pith ring was formed in bamboo during evolution to improve dimensional stability and to better adapt to complex environmental conditions. In the manufacture of bamboo products, the retention of pith ring can improve the utilization rate of bamboo and the dimensional stability of bamboo products.

    Facile fabrication of starch-based, synergistic intumescent and halogen-free flame retardant strategy with expandable graphite in enhancing the fire safety of polypropylene

    Xia Y.Chai W.Liu Y.Su X....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.Aimed at improving the efficiency of bio-based flame retardants, a starch-based, chemical-physical synergistic intumescent and halogen-free flame retardant system has been prepared in polypropylene (PP). Besides, the starch-based flame retardants have been modified via surface hydrophobicity to enhance the interfacial compatibility with PP. Surprisingly, limiting oxygen index (LOI) value of PP composites can reach as high as 33.5% with UL-94 V-0 rating when the total flame retardant content is 30 phr. Definitely, the synergistic effect of starch-based flame retardants and expandable graphite (EG) endows the better flame retardancy and anti-dripping ability of PP, which can be attributed to the conjunct chemical-physical intumescence action in improving the quality of charring layer. Finally, systematic analysis on char residue has revealed the synergistic flame retardant mechanism. This work has opened up a new path for exploiting the bio-based flame retardant with high performance in actual applications.

    Safflower (Carthamus tinctorius L.) a winter multipurpose oilseed crop for the Mediterranean region: Lesson learnt from on-farm trials

    Foschi L.Clemente C.Tavarini S.Rossi A....
    16页
    查看更多>>摘要:? 2022 Elsevier B.V.Mediterranean farmers have a really limited choice for winter crops to put in rotation with cereals, thus creating big challenges for weed and disease management. Crop diversification has undisputable environmental benefits and plays a central role in the agroecological transition toward sustainable and resilient farming systems. Among other crop candidates, safflower (Carthamus tinctorius L.) is recently attracting the attention of Mediterranean farmers, due its broad environmental suitability, low input needs, high plant vigor, also in marginal soil conditions, and tolerance to low temperatures. Thus, in the whole Mediterranean basin, safflower could be grown with a winter cycle, differently than sunflower (Helianthus annuus L.). The availability in the market of high-oleic safflower varieties tremendously enlarges the applications of its oils, easily meeting the needs of the domestic bio-based industry. Aiming at evaluating the feasibility of high-oleic safflower as a winter oilseed crop in the Mediterranean region, a multi-year and multi-location study has been carried out, across multiple growing seasons (2019–2021), at eight locations across Emilia-Romagna (ER) and Tuscany (TU) regions (Italy), traditionally devoted to winter cereal cultivation. In each region, the locations were chosen as representative of optimal, mean, and marginal conditions. The trials were managed as on-farm experiments by local farmers, to define safflower suitability to available equipment and practices. All trials were rainfed and carried out under low input agronomic management and using mechanical weed control. The safflower seed yield was not affected by growing region (grand mean: 1775 kg DM ha‐1), while 1000-seed weight and seed oil content were significantly influenced by growing environment. In particular, safflower produced significantly heavier seeds in Emilia Romagna (40.8 vs. 38.2 g, ER vs. TU, respectively, P ≤ 0.05), while seed oil content was higher in Tuscany (TU vs. ER, 40.3 vs. 36.1% DM respectively, P ≤ 0.05). Safflower confirmed its compositional stability with oleic acid representing > 75% of total fatty acids, but, again, some differences were revealed between regions, with ER having significantly higher oleic acid content than TU (78.8 vs. 75.9%, ER vs. TU, respectively). High oleic safflower, grown in winter, confirmed to be an interesting opportunity for Mediterranean farmers who are willing to differentiate their rotations while producing an oilseed crop with several biobased applications and able to increase local production of vegetable oil and protein.

    Effect of selected bioengineering measures on runoff, soil loss, and cotton (Gossypium hirsutum L.) productivity in the semi-arid region of western India

    Rao B.K.Singh G.Pande V.C.Dinesh D....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.Soil erosion and associated loss of soil nutrients and organic carbon are one of the major reasons for low crop productivity in major cotton (Gossypium hirsutum L.) growing areas of India. This calls for designing acceptable and low-cost bioengineering measures to enhance system productivity and soil health. Thus, a field study was conducted at Vasad, Gujarat, India from 2014 to 2017 to evaluate the efficacy of selected bioengineering treatments on cotton crop production and runoff and soil loss. The eight experimental treatments consisted of bio-filters of three grass species, viz.Para (Brachiaria mutica), Guinea (Megathyrsus maximus),and Napier (Pennisetum purpureum) at two strip widths (1 m and 2 m), field bund, and the conventional system as practiced by the farmers of the region. The treatments were tested in 45 × 10 m plots having the gauging facility for recording runoff and soil loss data. Rainfall, runoff, sediment concentration, soil loss, organic carbon, nutrient loss, and growth and yield parameters of grass barrier species and the cotton crop were recorded and analysed. The filter strip of Guinea sp. at 2 m width was most effective, reducing runoff by 30%, soil loss by 66%, nutrients loss by 69%, sediment concentration to 1/3rd, and soil organic carbon loss by 65%. The lowest runoff coefficient value of 0.209 observed among the filter strips in this treatment, indicated about 79% of rainwater was conserved in situ. The available soil nutrients increased by up to 42% and SOC concentration by 61%, and cotton equivalent yield by 25% than that of the conventional system. We concluded that Guinea grass filter strips of 2 m width planted at 45 m spacing in cultivable lands having 2% slope minimized runoff, soil loss, nutrient loss, improved soil fertility and enhanced cotton productivity.