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Industrial Crops and Products
Elsevier Science Publishers
Industrial Crops and Products

Elsevier Science Publishers

0926-6690

Industrial Crops and Products/Journal Industrial Crops and ProductsSCIISTPEI
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    Opportunities and challenges for sustainable production and processing of Rosa damascena in Bulgaria

    Harizanova A.Ivanova B.Beluhova-Uzunova R.Shishkova M....
    11页
    查看更多>>摘要:? 2022 The AuthorsThe production of Rosa damascena and rose products is traditional for Bulgaria and is of key importance for the family farms in the rural areas where it is carried out. At the same time, this production faces some technological, economic and environmental challenges. The latter is a prerequisite for the application of the principles of the bioeconomy and the appropriate use of residues. In this regard, the aim of the study is based on research and analysis of the challenges and opportunities in the production and processing of Rosa damascena, to reveal the potential for sustainable results. This article discusses (1) trends and problems in the production of Rosa damascena; (2) key factors influencing the decision to leave the sub-sector and the possibilities for keeping farmers in it and (3) the potential for increasing the economic efficiency of processing enterprises. The case study and regression analysis are applied. The results of the study show that the main difficulties faced by the producers are determined by the low purchasing price of Rosa damascena, the high cost of labor and the lack of workers. In turn, the factors that have a strong effect on the decision to leave or to stay in this type of production are the age of farmers, their education, experience in growing Rosa damascena and the size of the cultivated area. Based on the results of the study, it can be recommended to the policies in the field to provide additional support for young farmers to continue to develop this business. Investments are also needed to increase the level of human and social capital. On the other hand, new technologies and models enable processors to further process residuals that are currently being discarded. However, representatives of the processing enterprise identified the need for development of innovative and cheaper solutions for drying waste products.

    Lignin-rich cellulose nanocrystals from coir fiber treated with ionic liquids: Preparation and evaluation as pickering emulsifier

    Ferreira P.F.O.de Santiago-Aguiar R.S.Pereira A.L.S.Rosa M.F....
    15页
    查看更多>>摘要:? 2022 Elsevier B.V.Lignocellulosic materials are promising sources of energy and biomaterials. In this context, the biomass from the mesocarp of the green coconut can be used to produce nanocellulose. For this purpose, this work proposed approaches for pretreatment of coconut biomass using protic ionic liquids (PILs), which are solvents that have specific characteristics and less environmental impact, followed by acid hydrolysis to obtain lignin-containing nanocellulose. Thus, three PILs were produced, and two pretreatment methodologies were evaluated. The results showed that, when using the ionic liquid 2-HEAA and Methodology B, there was a delignification of 17.4 %, a reduction of 14 % of hemicelluloses and a gain of 50.8 % of cellulose. Furthermore, acid hydrolysis provided a stable suspension of lignin-containing cellulose nanocrystals (zeta potential of ?34.6 mV) with particles in the nanometer scale and more thermally resistant. When testing these lignin-containing cellulose nanocrystals as a stabilizer for oil-in-water emulsions, satisfactory results were obtained at a concentration of 0.50 %, which generated a stable emulsion for 14 days (?47.5 mV of zeta potential and mean diameter of 6.23 μm).

    Seven underutilized species of the Fabaceae family with high potential for industrial application as alternative sources of oil and lipophilic bioactive compounds

    Grygier A.Rudzinska M.Chakradhari S.Ratusz K....
    12页
    查看更多>>摘要:? 2022 Elsevier B.V.Fabaceae is the third largest family in the plant world, mainly considered a source of relatively valuable plant protein and a rather poor source of oil. The present study shows that several legume species (Bauhinia purpurea, Phanera vahlii, Butea monosperma, Caesalpinia crista, Gliricidia sepium, Mimosa pudica, Millettia pinnata) can be also considered as an alternative source of oil. The oil yield in studied species (19–36%) was similar or even higher than in soybean (Glycine max), the most known representant of the Fabaceae family. Palmitic, stearic, oleic, and linoleic acids constitute 87–99% of detected fatty acids with predomination of unsaturated (62–82%). All obtained oils were rich sources of tocopherols (79–187 mg/100 g oil), mainly α (five species) and γ (two species) homologues. With the exception of M. pinnata, where Δ5-stigmasterol (25%) and α-amyrin (26%) were the main phytosterols, β-sitosterol, Δ5-stigmasterol and campesterol constituted 51–96% of total phytosterols with a predomination of β-sitosterol (36–64%). The total carotenoid and phytosterol contents in studied Fabaceae species were in the range 0.6–8.9 and 175–622 mg/100 g oil, respectively. The present study demonstrated that several legume seeds could be considered a valuable source of oil and lipophilic bioactive compounds.

    Untargeted metabolomics used to describe the chemical composition and antimicrobial effects of the essential oil from the leaves of Guatteria citriodora Ducke

    Santos A.S.Ramos M.V.de Souza D.P.de Carvalho Goncalves J.F....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.Plant oils are sources of metabolites that have enormous potential for industrial applications. Herein, the chemical profile and in vitro antimicrobial activity of the essential oil (EO) from the leaves of Guatteria citriodora Ducke (Annonaceae) have been investigated for the first time. The composition of the hydrodistilled EO was analyzed using gas chromatography-mass spectrometry (GC-MS), which permitted the identification of oxygenated monoterpenes as the most highly representative class, and included citronellal (40.99%) and citronellol (14.6%) as the main compounds. The antimicrobial activity of G. citriodora EO (GcEO) was evaluated against pathogenic bacteria and phytopathogenic fungi. The experimental design was completely randomized (CRD), and used doses for each microorganism. Gram-positive strains were the most sensitive with a minimum inhibitory concentration (MIC) of 5.0 μL mL?1, while Gram-negative strains were 10.0 μL mL?1. The most potent antifungal activity was against Alternaria alternata (MIC of 1.25 μL mL?1). In addition, it fully inhibited A. alternata conidia germination at the minimum inhibitory concentration. The nucleic acid and soluble protein contents were significantly released from the conidia of A. alternata after treatment with GcEO. Using SEM (scanning electron microscopy), morphological alterations were observed in the conidia, which indicates that a lesion in the cytoplasmic membrane is one of its mechanisms of action. Overall, these results indicate that GcEO is an antimicrobial agent with potential applications in the agriculture, food, and pharmaceutical industries.

    Controllable fabrication of nanofibrillated cellulose supported HKUST-1 hierarchically porous membranes for highly efficient removal of formaldehyde in air

    Chen Z.He X.Fan G.Zhang L....
    14页
    查看更多>>摘要:? 2022Nanofibrillated cellulose (NFC) has presented great potential as supports for functional membrane materials owing to its unique advantages. In this work, NFC-supported MOF hierarchically porous membranes were synthesized by anchoring HKUST-1 (copper 1,3,5-benzenetricarboxylate open-framework) on NFC membrane through a green DMF-free (N,N-Dimethylformamide) method at room temperature and afterward, the as-prepared composite membrane was used to remove formaldehyde from the air. The addition of HKUST-1 particles significantly increased the specific surface area of NFC membrane without affecting the NFC properties. Meanwhile, the nucleation and growth process of HKUST-1 on the NFC membrane could be effectively regulated, which further controlled the morphology of HKUST-1 as well as the anchored position of HKUST-1. When HKUST-1 was anchored on the interior and surface of the membrane, HKUST-1 reduced the compactness of the arrangement between fibers, which resulted in a hierarchical porous structure and then exposed more active adsorption sites of HKUST-1 particles. Thus, the flexible composite membranes exhibited effective formaldehyde adsorption from a low formaldehyde concentration environment (3.0 mg/m3). Under the optimum conditions, the maximum adsorption capacity of the HKUST-1@NFC-1 for formaldehyde reached 378.09 mg/g (based on HKUST-1 wt), which was considerably higher than support-free HKUST-1 powders. Consequently, the present work offers a green and controllable route to prepare NFC-supported MOF composite membranes with highly effective formaldehyde adsorption capacity and thus provides a promising option for NFC application as a flexible adsorbent support.

    Micro and nanoencapsulation of bioactive compounds for agri-food applications: A review

    Guia-Garcia J.L.Charles-Rodriguez A.V.Reyes-Valdes M.H.Ramirez-Godina F....
    7页
    查看更多>>摘要:? 2022 Elsevier B.V.Bioactive compounds (BCs) extracted from plants have been under study since ancient times due to their outstanding features such as antioxidant, anticancer, anti-inflammatory, and antimicrobial properties. This has led to the development of various extraction techniques, which are classified as conventional (e.g., Soxhlet extraction, maceration, and hydrodistillation) and non-conventional (e.g., ultrasound-assisted extraction, ohmic extraction, supercritical fluid extraction), both seeking high yields and recovery effectiveness. However, these compounds have an important disadvantage, as they are very susceptible to degradation when exposed to heat, light, and humidity, among other factors. Micro and nanoencapsulation can protect the BCs from these factors allowing their controlled release, favoring their application in this manner. To build these systems several techniques and materials are used, and they must be properly selected as they directly influence their functionality and structural characteristics. Recently, micro and nanostructures have also been explored as carriers for BCs with the aim of combating microbial attacks on crops and extending the food products shelf life. This review covers relevant and updated information on BCs from plants, describing and discussing different extraction techniques and encapsulation processes. It also presents an updated summary about the most frequently used wall materials for encapsulating BCs. There is a review of the advantages that micro and nano encapsulation of BCs from plants can provide, showing that their design can improve their properties, which represents an excellent alternative to potentiate future applications that cover needs in several areas, mainly in the agri-food industry.

    Preparation and characterization of a bio-based rigid plastic based on gelatinized starch cross-linked with furfural and formaldehyde

    Zhang J.Liu B.Zhou Y.Zhou X....
    8页
    查看更多>>摘要:? 2022 Elsevier B.V.The extensive use and rapid consumption of energy especially with the shortage of oil-derived resources pushed researchers to focus on developing more biomass-based plastics. The current article presents the possibility to undergo polycondensation of gelatinized starch and corn-derived furfural in presence of formaldehyde under acidic conditions to produce a thermoplastic material, starch–furanic resin. The structure of resulting product was studied intensively using solid-state 13C nuclear magnetic resonance (NMR) and Raman spectroscopy. The glass transitions, molecular weight, and thermal stability of the developed material were investigated with techniques such as differential scanning calorimetry (DSC), gel permeation chromatograph (GPC) and thermogravimetric analysis (TGA). In addition, the morphological features of the material's surface were studied with scanning electron microscopy (SEM). Moreover, the related properties of the plastic were characterized by the measurements of Brinell hardness and compression resistance. The plastic shows a smooth appearance without crack and bubbles, and exhibited a glass transition temperature as high as 129 °C and a 12% weight loss temperature of 200 ℃ in nitrogen. All these results support that the condensation reactions between the gelatinized starch and aldehydes were more appropriate under acidic conditions to yield more complicated network structure with better homogeneous microstructure, which revealed superior and comparable results to that of phenol-formaldehyde plastics.

    A novel pH-responsive charge reversal nanospheres based on acetylated histidine-modified lignin for drug delivery

    Yi C.Xu Q.Yang D.Wang M....
    10页
    查看更多>>摘要:? 2022 Elsevier B.V.In this work, we developed a novel technique to prepare pH-responsive charge reversal nanospheres based on softwood kraft lignin (SKL) through two steps modification and high efficient self-assembly. SKL was first grafted with imidazole groups by Mannich reaction and further fabricated into acetylated histidine-modified lignin (Ace-SKL-HIS) via acetylation reaction. Ace-SKL-HIS nanospheres (Ace-SKL-HIS NPs) were prepared by fast vacuum evaporation method, their effective diameters (ED) were around 100 nm, exhibited low Polydispersity Index(PDI, <0.2) and good shape. Ace-SKL-HIS NPs demostrated excellent pH response performance with charge reversal under acidic environment. Then, curcumin was applied as a model drug to prepare drug-loaded nanospheres (Ace-SKL-HIS@CUR). The drug loading degree (DL%) and encapsulation efficiency (EE%) were 22.34 % and 70.76 %, respectively. The in vitro release behavior of curcumin exhibited excellent pH dependent release property, 76.82 % release at pH 5.7 while only 12.92 % at pH 7.4 in 120 h. Furthermore, in vitro cytotoxicity studies showed that Ace-SKL-HIS@CUR had potent anti-tumor effect, with IC50 of 28.16 μg/ mL. This study constructed a promising nanocarrier platform for cancer drug delivery, which paved a new way to the high value-added application of lignin.

    Application of poly(lactic acid)-grafted cellulose nanofibers as both inhibitor and reinforcement for 3D-printable tough polydicyclopentadiene composites via frontal ring-opening metathesis polymerization

    Ma R.Wang S.Ma L.Li B....
    12页
    查看更多>>摘要:? 2022 Elsevier B.V.Due to the contradiction between curing rate and degree of polymerization, fabrication of 3D-printable thermosetting polymer resin with strong, and tough properties via frontal ring-opening metathesis polymerization (FROMP) remains challenging. Here, poly(lactic acid)-grafted cellulose nanofibers (CNF-g-PLA) was used as both inhibitor and fortifier to prepare 3D printable, strong, and tough polydicyclopentadiene (PDCPD)-based composites by FROMP. When 5 % CNF-g-PLA was added, the fracture toughness and tensile strength of the PDCPD/CNF-g-PLA composites increased by 277.94 % and 12.6 %, respectively. Meanwhile, the rate of radical-induced polymerization was reduced by 106 %, significantly improved the 3D-printability of PDCPD. The two-dimensional (2D) sheet of PDCPD/CNF-g-PLA composites exhibited good flexibility, which could easily be crimped into a cylinder because of CNF-g-PLA contribution. Moreover, owing to the improved toughness, PDCPD/CNF-g-PLA composites can be used as engineering protect materials such as vehicle bumpers, further broadening the application fields of 3D-printed PDCPD/CNF-g-PLA composites. This study provides a feasible method for the application of CNF in 3D printable thermoset resins.

    The contribution mechanism of furfuryl alcohol treatment on the dimensional stability of plantation wood

    Li G.Chu F.Yang S.Shen X....
    11页
    查看更多>>摘要:? 2022 Elsevier B.V.Furfuryl alcohol polymers (PFA) derived from lignocellulosic biomass have been confirmed as an effective modifier to improve dimensional stability of wood. However, the main reason for the dimensional stability related to this method has remained unclear. In this study, principal consideration of dimensional stabilization was analyzed by a mathematics model regarding anti-swelling efficiency (ASE) and cell wall bulking of furfurylated woods with different weight gain precents (WPGs), and ASE’ obtained by method of Ohmae et al. Simultaneously, confocal laser scanning microscopy and nanoindentation technique were applied to explain the dimensional stability mechanism. Results showed that both ASE and cell wall bulking increased with WPG at 0–69%. A nearly linear (R2 = 0.9690) relationship was observed between ASE and cell wall bulking. ASE’ values at different WPGs were approaching zero. The dimensional stability was dominated by cell wall bulking analyzed through both the mathematical model and small ASE’ values at various WPG. In this study, the mechanistic insights into dimensional stabilization of furfurylated wood could provide highly beneficial for controlling the dimensional stability by cell wall bulking.