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Physica
North-Holland
Physica

North-Holland

0921-4526

Physica/Journal Physica
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    High-temperature lamellar of an extremely anti-symmetrical surfactant, barium ethyl(n-octyl)phosphate, in D2O: A small angle neutron scattering study

    Hirata, Hiro-HitoGhosh, SwapanO'Connor, Charmian J.Furusaka, Michihiro...
    5页
    查看更多>>摘要:The lamellar structure of an extremely anti-symmetric bi-tail-type surfactant "barium ethyl (n-octyl)phosphate Ba (EOP)(2)" in D2O was investigated by the SANS method. The SANS intensity spectra were analyzed, based on a one-dimensional paracrystal model with uniaxial randomly oriented stacks. The results provided the lamellar model in which the ethyl and n-octyl chains are closely packed in a tail-to-tail manner which alternately combines the short and long n-alkyl chains. The closely-packed lamella was ascribed to the coordination effect of Ba2+ to the two PO4- groups of the EOP surfactants, as a result of comparison with the x-ray low angle diffraction consequence of "a loosely packed lamellar model" of Li (EOP) (already reported by Hirata et al. [1]).

    Influence of Ru dopants on the structural, optical, and magnetic properties of nickel oxide nanoparticles

    Abdallah, A. M.Awad, R.
    11页
    查看更多>>摘要:The co-precipitation method was adopted to synthesize Ni1-xRuxO nanoparticles, with x = 0.000, 0.005, and 0.010. The X-Ray Diffraction patterns showed the formation of the NiO phase without any secondary phases or impurities due to the doping. The Ru-dopants are well incorporated into the lattice without changing its structural properties, owing to the comparable ionic radii of Ru3+ and Ni2+ ions. The doped samples have cubic morphology with reduced sizes, as seen in Transmission Electron Microscope images. The Fourier Transform Infra-Red and X-Ray Photo-induced spectra (XPS) assured the purity and the successful doping of trivalent Ru ions into NiO nanoparticles. Moreover, the XPS spectra revealed the generation of more oxygen vacancies with Ru-doping. The optical properties were investigated by Ultra-Violet and Photoluminescence (PL) spectroscopies. The Ru-doped samples have higher transmittance that is beneficial for transparent electrodes and optoelectronic devices. The TAUC and derivative plots were used to estimate the bandgap energies. The Ru-doped samples demonstrated suppressed bandgap energies, mainly due to the formation of additional energy levels near the valence band. The visible region of the PL spectra was investigated to track the deep-level defects. All the samples have traces of nickel vacancies, oxygen vacancies, and oxygen interstitials. The magnetic studies were tested by Vibrating Sample Magnetometer at room temperature. The M - H loops were then fitted by the different models of the law of approach to saturation. The best-fitted model was the one accounting for the exchange and anisotropy fields. The pure and Ru-doped samples showed a weak ferromagnetic behavior with a slight increase in the linear magnetization with Ru dopants, due to the antiferromagnetic Ru-Ru interactions.

    Calculation of the transition amplitude using differential forms for the simplest electron-electron interaction

    Kondo, Shin-ichiro
    15页
    查看更多>>摘要:To examine the transition amplitude, we apply differential forms to the formal expression of the transition amplitude when the Hamiltonian includes the simplest electron-electron interaction. Simultaneous differential equations are obtained after applying the differential forms. In the analysis of the steady state, the transition amplitude tends to become flat with increasing Coulomb potential if electron transfer from the initial configuration is blocked by the Coulomb potential. In contrast, the transition amplitude exhibits oscillation irrespective of the Coulomb potential if electron transfer from the initial configuration is less inhibited by the Coulomb potential. In the non-steady state, the transition amplitude displays oscillation even if electron transfer from the initial configuration is inhibited by the Coulomb potential. Consequently, the electron transfer mechanism in the non-steady state may be distinct from that in the steady state.

    Specifics of electromagnetic wave propagation through a non-ideal 1D photonic crystal

    Rumyantsev, V. V.Paladyan, Yu A.Fedorov, S. A.Gumennyk, K., V...
    5页
    查看更多>>摘要:ABS T R A C T The paper employs mathematical modeling to elucidate the specifics of propagation of electromagnetic excita-tions through a non-ideal one-dimensional photonic crystal. We focus on such key quantities as the refractive index and the width (energy gap) of the lowest forbidden band in the energ y spectrum and study their depen-dence on concentrations of point and layer structural defects (the layers are allowed to va r y in their compositions and thicknesses).

    Structural, electronic, elastic, phonon and thermoelectric properties of Heusler-structured intermetallic HfCu2In: Using density functional theory

    Jain, AditiShrivastava, DeepikaKurchania, Rajnish
    8页
    查看更多>>摘要:Structural, electronic, elastic, vibrational and thermoelectric properties of HfCu2In Heusler-structured intermetallic compound in MnCu2Al-type structure with space group Fm-3m has been studied by using ab-initio density functional theory for the first time. The calculated band structure shows the metallic nature of the compound. HfCu2In is ductile which was affirmed by the computed values of the Poisson's ratio, Cauchy's pressure and Pugh's ratio. Thermoelectric properties such as electrical conductivity, Seebeck-coefficient, electronic thermal conductivity and power factor are measured with the BoltzTrap software. The calculated phonon dispersion curve contains positive frequencies in all symmetric directions in the first Brillouin zone, indicating the dynamical stability of the compound in a cubic MnCu2Al-type structure. Furthermore, near the zone center, Raman and infrared phonon modes for alloy have been explored, indicating that the estimated phonon spectra are accurate. The present calculated results are compared with those of the other Heusler alloys of a similar type.

    Modification in the physical properties of nanocrystalline ZnO thin films by Sn/Ni co-doping for transparent conductive oxide applications

    Tiwari, AradhanaSahay, P. P.
    10页
    查看更多>>摘要:In this paper, the modification in the physical properties of spin-coated ZnO thin films upon Sn/Ni co-doping has been presented. All the films possess the hexagonal wurtzite structure of ZnO with varying surface morphologies. Among all the films, the optical transmittance beyond 550 nm wavelength is maximum for the 1 at% Ni-doped ZnO (1NZO) and (1 at% Sn + 1 at% Ni) co-doped ZnO (1T1NZO) films. The optical band gap for the pristine ZnO film is 3.26 eV, which decreases upon doping and co-doping. The PL spectra of the films exhibit the UV emission corresponding to excitonic transitions and the blue and green emissions related to native defects in the ZnO structure. The room-temperature electrical conductivity is found maximum in the 1T1NZO film. The existence of 1T1NZO film with improved optical transmittance and high electrical conductivity supports its use in transparent conductive oxide applications.

    Effects of impurity factor on the physical and transport properties for Ga1-xAlxAs quantum wire in the presence of Rashba spin-orbit interaction

    PriyankaSharma, RinkuKumar, Manoj
    9页
    查看更多>>摘要:There is a need to get familiarized with a systematic and precise approach to study the energy dispersion and ballistic conductance in a Ga1-xAlxAs quantum wire. We have employed parabolic confinement in this work. The combined impacts of Rashba spin orbit interaction (RSOI), external electric field, magnetic field, and Aluminium concentration on energy dispersion and conductivity in a Ga1-xAlxAs quantum wire have been explored. The Energy eigenvalues and eigenvectors are quantified using the diagonalization method and the transport properties are computed by Landuer-Bttiker formalism. It is noticed that the external electric field, magnetic field, Rashba spin-orbit interaction, and Aluminium concentration (impurity factor x) alter the energy spectra and conductivity. Hence, these parameters significantly affect the physical and transport properties.

    Hyperspectral imaging thermometry assisted by upconverting nanoparticles: Experimental artifacts and accuracy

    Martinez, Eduardo D.Brites, Carlos D. S.Urbano, Ricardo R.Rettori, Carlos...
    10页
    查看更多>>摘要:We combined the sensing capabilities of Er3+-doped upconverting nanoparticles (UCNPs) with hyperspectral microscopy to construct thermal images on thermally active nanostructures. Here, we studied the heat dissipation of a percolating network of silver nanowires under controlled electric current flow. We quantified the electrothermal action by analyzing the hyperspectral data and constructing 2D maps for the emission intensity, the signal-to-noise ratio, and the thermometric parameter. By studying selected clusters in the network, we concluded that the temperature is quite uniform across the film without any significant thermal gradients. Nonetheless, the thermal evolution was clearly sensed by the UCNPs when the heat dissipation due to the Joule effect was turned on and off, validating the use of this method for studying slow-dynamic thermal processes. Finally, we discuss the accuracy of the thermal readings and the systematic limitations of the proposed method.

    InGaAs/InP SAGCM avalanche photodiode with a heterojunction multiplication layer

    Zhao, YangyangChen, Jun
    5页
    查看更多>>摘要:In this paper, the InGaAs/InP separate absorption, grading, charge, and multiplication avalanche photodiode (SAGCM-APD) with a heterojunction multiplication layer and a hybrid absorption layer has been simulated. Due to the effect of the heterojunction multiplication layer on avalanche photodiode collision ionization, compared with the traditional structure, the break-down voltage and the punch-through voltage of the structure with a heterojunction multiplication layer was reduced by 2 V. By optimizing the thickness of the heterojunction multiplication layer, the electrical performance of the device has been enhanced. The avalanche gain was 193.37, which is much higher than the conventional structure (51.65). Besides, the thickness of InP in the heterojunction multiplication layer affects the capacitance characteristics of the device.

    Thermal transport controlled by intra- and inter-dot Coulomb interactions in sequential and cotunneling serially-coupled double quantum dots

    Pirot, Bashdar RahmanAbdullah, Nzar RaufManolescu, AndreiGudmundsson, Vidar...
    8页
    查看更多>>摘要:We study thermoelectric transport through a serial double quantum dot (DQD) coupled to two metallic leads with different thermal energies. We take into account the electron sequential and cotunneling effects via different master equation approaches. In the absence of intra- and inter-dot Coulomb interactions, a small peak in thermoelectric and heat currents is found for E-L= E-R indicating the Coulomb blockade DQD regime, where E-L(E-R) is the energy of the state of the left(right) quantum dot. In the presence of intra- and inter-dot Coulomb interactions with strengths U-intra, and U-inter, respectively, avoided crossings or resonance energies between the intra- and the inter-dot two-electron states, 2ES, are found. These resonances induce extra transport channels through the DQD leading to strong side peaks in the thermoelectric and heat currents at E-L- E-R = +/-(U-intra-U-inter) in addition to the main peak generated at E-L=E-R. The current side peaks are enhanced by increased strength of the Coulomb interactions. Interestingly, the current side peaks are enhanced when cotunneling terms are considered in which the resonances of the 2ESs assist the electron cotunneling process through the system. Furthermore, the issue of coherences is carefully checked in the DQD-leads system via different approaches to the master equation, which are the Pauli, the Redfield, a first order Lindblad, and the first- and second order von-Neumann methods. We realize that the Pauli method gives a wrong results for the thermoelectric transport when the role of the coherences is relevant.