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Resources, Conservation and Recycling
Pergamon
Resources, Conservation and Recycling

Pergamon

0921-3449

Resources, Conservation and Recycling/Journal Resources, Conservation and RecyclingEI
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    Regional allocation of renewable energy quota in China under the policy of renewable portfolio standards

    Zhou, DequnHu, FanshuaiZhu, QingyuanWang, Qunwei...
    14页
    查看更多>>摘要:Renewable energy policy plays an important role in achieving carbon neutrality which is main goal for climate change mitigation. China is striving to promote the implementation of renewable portfolio standards under the goal of carbon neutralization in 2060. Thus, based on the principles of equality and efficiency, we apply zero sum gains data envelopment analysis (ZSG-DEA) model combined with entropy model to allocate China's renewable energy quota from provincial perspectives. Further, we introduce an environmental Gini coefficient to evaluate the rationality of allocation results. The allocation results show that Guangdong, Jiangsu, Sichuan and Shandong are four provinces with the most renewable energy quota, while Hainan, Guizhou, Gansu, and Xinjiang are four provinces with the least quota. In addition, the quota allocation results have achieved the goal of transferring the responsibility of renewable energy quota from western provinces to eastern provinces. Last, managerial suggestions in promoting renewable energy development are discussed.

    Recovery of spent LiCoO2 lithium-ion battery via environmentally friendly pyrolysis and hydrometallurgical leaching

    Tao, RenXing, PengLi, HuiquanSun, Zhenhua...
    10页
    查看更多>>摘要:LiCoO2 (LCO) lithium-ion battery (LIB) is rich in valuable metals (cobalt and lithium), which has high recycling value. The existing process has basically realized the extraction of cobalt, but there are still shortcomings in harmless disposal of fluorine-containing electrolyte, binder and other organic matters, selective extraction of lithium and low-cost extraction of cobalt. In this context, a novel process was developed to realize the full-component recovery of spent LiCoO2 battery via environmentally friendly pyrolysis and hydrometallurgical leaching. The organic matters were recovered in the form of pyrolytic oil and gas, in which the harmful fluorine element was absorbed by Ca(OH)(2) solution. The current collectors (copper and aluminum) were recovered after the easy separation of electrode materials due to the degradation of binders. During pyrolysis the cathode material was deconstructed and reduced under the synergistic effect of pyrolytic gas and anode graphite. Selective recovery of lithium and cobalt was achieved through carbonated water leaching and reductant-free acid leaching. The leaching efficiencies of lithium and cobalt were respectively 87.9% and 99.1% under the optimal conditions. Lithium carbonate and cobalt sulfate were obtained by evaporative crystallization, respectively. The remaining residue was only graphite without impurity entrainment. The results in this research suggest that the process consisting of pyrolysis and hydrometallurgical leaching is inexpensive, efficient, and eco-friendly for full-component recycling of spent LiCoO2 battery.

    A review on characteristics of silico-manganese slag and its utilization into construction materials

    Nath, Susanta KumarRandhawa, Navneet SinghKumar, Sanjay
    11页
    查看更多>>摘要:This paper reviews the potential use of silico-manganese slag (SiMnS) as binder and aggregate in Portland cement and geopolymer concrete. SiMnS is a byproduct of alloy steel production. Depending on the process of solidification, the slag is available in crystalline hard stone type and granulated glassy form. The latter one is more reactive due to the presence of amorphous phases. Therefore, granulated slag has been mostly used as supplementary cementitious material, either blending with clinker or as a precursor for alkali activated binder. Whereas the former is less reactive, and has been mostly used as aggregate, which can enhance the properties of the concrete. The reactive component such as CaO and SiO2 improve the binding capability of the cement gel. The leaching of toxic and heavy metals from the SiMnS reacted binder matrix is not reported. This paper also highlights the future potential of this slag by a process called slag engineering to modify its chemistry similar to granulated blast furnace slag (GBFS), to be utilized more effectively.

    Life cycle inventory and carbon footprint assessment of wireless ICT networks for six demographic areas

    Ruiz, D.San Miguel, G.Rojo, J.Terius-Padron, J. G....
    14页
    查看更多>>摘要:The aim of this work is to quantify, assess, and identify hotspots in the environmental sustainability of newly constructed ICT networks designed to provide internet access (4 G LTE mobile technology) to regions still lacking this service. The analysis has been carried out on six demographic areas, from high-density urban and peri-urban to remote rural, using ISO 14,040. A Dynamic Inventory Model (DIM) relating demographic/connectivity features with foreground material and energy inventories was validated using real data from Peru. The results showed carbon footprints between 81 and 103 kg CO2 eq./subscription/year, equivalent to 1.35 - 1.73 kg CO2 eq./Gb. Most of this (between 68 and 86%) correspond to end user devices, primarily in the form of embodied emissions. Operational emissions account for about one-third of the total and derive primarily from the electricity consumed by end user devices, and to a lower extent by access networks and data centers. Linear correlations were observed between operational - embodied carbon emissions and the number of subscribers. This trend was overturned in very small ICT networks designed to serve sparsely populated rural areas, due to higher energy consumption and carbon emissions per functional unit generated by access and IP network components. The robustness of these results was studied through sensitivity and uncertainty analyses.

    Environmental assessments of scales: The effect of ex-ante and ex-post data on life cycle assessment of wood torrefaction

    Tsalidis, Georgios ArchimidisKorevaar, Gijsbert
    9页
    查看更多>>摘要:Life Cycle Assessment (LCA) is a powerful tool for achieving sustainability. Traditional LCAs analyze well defined and developed industrial systems, but recent developments of LCA focus on analyzing emerging technologies which are not yet optimized with respect to energy and materials. Therefore, LCA results of ex-ante applications can be very different from ex-post applications for the same system. The purpose of this study is to show the different effects of data scales on LCA results regarding global warming, fine particulate matter formation, terrestrial acidification and freshwater eutrophication potentials. For this purpose torrefaction technology was selected as the case study and assessed based on bench scale data, lab scale data, data derived from process simulations, pilot scale data and commercial scale data. Considered environmental impacts were global warming, fine particulate matter formation, terrestrial acidification and freshwater eutrophication. Results showed that process efficiencies improved significantly between the bench scale system and systems with higher technology readiness levels (TRLs), such as pilot, process simulations and commercial scale systems. Furthermore, process simulations result in scores closer to commercial scale regarding all considered environmental impacts. However, if LCA practitioners focus only on global warming impact, then pilot scale is also a good alternative. Finally, due to torrefaction technology being relatively simple in terms of raw materials input, we suggest more complex chemical systems to be assessed with LCA in various TRLs.

    Effect of alum sludge ash on the high-temperature resistance of mortar

    Liu, YueZhuge, YanChow, Christopher W. K.Keegan, Alexandra...
    9页
    查看更多>>摘要:The effect of high temperature on the mechanical, durability, and microstructural properties of mortar containing alum sludge ash (ASA) was investigated in this paper. The ASA was derived from grinding and calcinating alum sludge, a typical by-product of the drinking water treatment processes. Four different mortar mixtures with ASA content at weight percentages of 0%, 10%, 20%, and 30% (as cement replacement) were exposed to high temperatures of 300 degrees C, 550 degrees C, and 800 degrees C, respectively. The experimental results showed that mortar samples containing up to 20% of cement replaced with ASA exhibited superior high-temperature resistance to the reference ones (without ASA), especially after exposure to 800 degrees C. The thermal analysis determined the portlandite consumption because of ASA pozzolanic reaction, and the x-ray diffraction pattern showed that the ASA reaction might contribute to the formation of aluminum-bearing phases with excellent refractoriness in the binder matrix. In addition, crack examination conducted by backscattered electron images evidenced that the ASA addition mitigated the binder paste degradation.

    When to replace products with which (circular) strategy? An optimization approach and lifespan indicator (vol 174, 105704, 2021)

    Hummen, TorstenDesing, Harald
    1页

    What contributes more to life-cycle greenhouse gas emissions of farm produce: Production, transportation, packaging, or food loss?

    Qin, YuweiHorvath, Arpad
    9页
    查看更多>>摘要:The food production and supply systems are some of the biggest contributors to climate change, and food loss from the entire food chain aggravates the problem. We developed a model to estimate the GHG emissions from the entire food cycle (production, packaging, transportation, refrigeration, and waste management), and applied it to cherries, onions, and plums, the first time these produce have been assessed comprehensively in the United States. We pulled into the analysis 6 additional fruits and vegetables for which California accounts for more than 50% of U.S. production and which we have assessed at least partially earlier: strawberries, avocados, lemons, celery, oranges, and tomatoes. We assessed uncertainty for 34 parameters through Monte Carlo simulation. The total life-cycle food losses for one unit of cherries, onions, and plums produced are 66%, 57%, and 44%, respectively. The consumer stage contributes most of the food loss for eight of the nine produce. The results show that food loss contributes 19-61%, transportation 14-46%, packaging 11-31%, and farm production 7.7-30% to the total emissions. Alternative packaging was also explored. Polyethylene produce bags substituted with PLA bags can lower the total food-loss-inclusive emissions by only 7%, 5%, and 4% for tomatoes, oranges and onions, respectively. Forgoing retail-provided PE bags for produce that are not pre-packaged could reduce total GHG emissions by 12%, 10%, 6%, 6%, and 4% for one unit of tomatoes, onions, lemons, plums, and oranges, respectively. The GHG emissions for the 9 produce can be significantly reduced by decreasing consumer-level food loss. For tomatoes and onions, more than half of the emissions due to food loss can be offset by forgoing packaging at the retail stores.

    Early-stage assessment of minor metal recyclability

    van Nielen, Sander S.Kleijn, ReneSprecher, BenjaminXicotencatl, Brenda Miranda...
    11页
    查看更多>>摘要:The growing demand for minor metals creates both pressure on the supply chain of these metals and challenges in waste management. Consequently, there is a wide interest in recycling opportunities. To identify these opportunities, it is key to understand bottlenecks and drivers in recycling value chains. Hence, we analyzed existing recyclability frameworks and related recycling literature, revealing 113 factors that determine the success of recycling minor metals. These factors were linked to the stages of the recycling value chain, i.e. manufacturing, use phase, waste collection, preprocessing, metallurgical recovery and secondary marketing. Based on the insights from the literature analysis, we propose a novel recyclability assessment framework. The framework indicates how properties of products, recycling technologies and society determine recyclability. The framework is suitable for assessing the recyclability of minor metals during the recycling technology development process. Therefore, it includes indicators that can be quantified easily, as demonstrated in three case studies. As such, it can be a useful tool to guide policy makers and technology developers towards closing material loops.

    Large inter-city inequality in consumption-based CO2 emissions for China's pearl river basin cities

    Qian, YukunZheng, HeranMeng, JingShan, Yuli...
    11页
    查看更多>>摘要:Cities are leading carbon mitigation but are heterogeneous in their mitigation policies due to different socioeconomic backgrounds. Given that cities are increasingly inextricably linked, formulating mitigation policies of different cities cannot be easily achieved without comprehensive carbon inventories, who taking the inter-city supply chains into account. The Pearl River Basin is one of the important economic zones in China, with huge disparity in its cities, but very limited information is available on their consumption-based CO2 emissions. To fill this gap, we compiled a consumption-based inventory of 47 cities in the Basin for 2012. We found that the total consumption-based emissions of 47 cities was 933.8 Mt, accounting for 13.1% of China's emissions. There were huge differences in the consumption-based emissions, ranging from 3.6 Mt (Heyuan City) to 153.1 Mt (Shenzhen City). The consumption-based emissions were highly concentrated in the largest seven cities, which accounted for 52.8% of the total emissions of the Basin. The consumption-based emissions per capita also varied greatly, from 1.2 to 14.5 tons per capita. Large scale infrastructure was the biggest driving force for most cities, resulting in 42.1% to 75.6% of the emissions. At sector-level, construction, heavy industry and services were leading in emissions, contributing more than 80% of emissions. The major inter-city carbon transfers occurred within upstream cities in the developing regions and downstream cities in the Pearl River Delta respectively, instead of the transfers between upstream and downstream cities. The findings highlight that the regional mitigation strategies could mainly focus on cities in intra-province boundary, rather than inter-province boundary, and also the city-level mitigation strategies should pay attention to the key emission sectors and drivers in respect of the heterogeneity of cities.