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Journal of the Indian Chemical Society
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Journal of the Indian Chemical Society

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0019-4522

Journal of the Indian Chemical Society/Journal Journal of the Indian Chemical SocietySCICCR
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    Development of PLA based nanocellulose films for packaging applications

    Gupta, M. K.Gond, R. K.
    5页
    查看更多>>摘要:Owing to environmental concern, demand of nanocellulose of natural fibres has been increasingly increased in packaging applications. In this work, nanocellulose of sugarcane bagasse was isolated through a series of chemical treatments followed by the mechanical grinding process. The films of neat PLA and nanocellulose reinforced PLA were prepared by the solvent casting method with changeable weight percentages (i.e. 1, 2, 3, and 4) of nanocellulose of sugarcane bagasse. Tensile properties, optical properties and morphological analysis of the prepared films were studied. The better performance of tensile properties was exhibited by the film with 2 wt.% of nanocellulose. Transparency values of the films were found to decrease with adding of nanocellulose of sugarcane bagasse.

    A 4-pyridyltetrazole-based zinc metal-organic framework for photocatalytic degradation of methylene blue

    Chouhan, ArtiPandey, AshutoshSingh, SadhanaAmbreen, Subia...
    5页
    查看更多>>摘要:Metal organic frameworks (MOFs) have been found to be potentially effective for treatment of industrial wastewater. In the present work, a metal-organic framework [mono(5-(4-pyridyl) tetrazolato)hydroxylzinc(II)]monoaqua (1) has been synthesized and characterized. The average particle size of the product was calculated to be 43 nm by X-ray diffraction. In addition, the efficacy of the synthesized MOF as a photocatalyst was investigated by taking a common wastewater dye methylene blue (MB). The photocatalytic activity MOF (1) has been found to be 86% within one hour for 16 ppm of methylene blue (MB) dye using 0.8 g/L of catalyst.

    Gallic acid extraction with mixed aminic extractants dissolved in 1-decanol

    Pandey, ShitanshuKumar, Sushil
    5页
    查看更多>>摘要:Gallic acid (GA) is a one of those phenolic acids which has a significant role in different industrial applications. In present study, the organic phase volume of TOA-Aliquat 336 extractant mixture dissolved in 1-decanol is optimized for the maximum recovery of GA by synergic extraction. The effects of acid concentration, extractant volume ratio, solvent polarity and pH of initial aqueous solution on GA extraction, are examined. The 1:1 acid-extractant complexation is considered as the acid loading ratio Z and the number of reacting acid molecules per molecule of extractant m, are found < 0.5 and 1.11 respectively. With the effect of synergism, the maximum extraction is found 98.37% with 10% TOA- 20% Aliquat 336 extractant mixture dissolved in 70% 1-decanol for initial gallic acid concentration of 0.02939 kmol m(-3). For the extraction yield >95%, the optimum organic phase volume of 10% TOA-5% Aliquat 336 in 85% of 1-decanol is selected for the synergic extraction of GA.

    Numeric and experimental investigation of Fe2O3 based nanofluids in direct absorption solar collector

    Sonawane, ShriramBhambore, NehalLokhare, PraneetBhad, Rahul...
    6页
    查看更多>>摘要:Increasing the world population requires clean and sustainable energy sources and energy conservation methods. Use of the nanofluids in solar energy devices is one such approach. In this study, we used the Fe2O3 based nanofluids for the absorption of the solar radiation using prototype direct absorption solar collector. The realizable k-epsilon model in the ANSYS FLUENT V16.2 is used to validate the experimental results obtained. The average error of 8.02% is found after the comparison. 50% enhancement in collector efficiency is recorded during these experiments. Exergy efficiency is recorded 72% more at the 0.035 volume fraction of the nanoparticle concentration and 1.25 lpm flow rate than the exergy efficiency of the water as a base fluid. But the power required to pump this nanofluid is more than the power required in the water as a base fluid. Thus, this study is useful for the scale-up study for further findings.

    Ultra-sonication assisted removal of an anionic dye using solvent impregnated resin: Response surface methodology optimization

    Awasthi, AnjaliIqbal, MuzaffarBatra, SakshiArya, Ankit...
    5页
    查看更多>>摘要:Textile industries create a critical marine living situation as most unfixed dyes dumped as an effluent without further dye-fixing treatment. In this work, methyl orange dye was removed from the aqueous solution by ultrasonication process using Amberlite XAD-7HP resin impregnated with Aliquat-336. The experiments were designed by central composite design of response surface methodology. A regression model was proposed. Operating parameters were optimized, and at optimum conditions, the dye removal efficiencies were 98.57% (experimental) and 99.94% (predicted). Kinetic studies were performed at optimum conditions and intra-particle diffusion model fitted the kinetic data.

    Amberlite resin functionalized with phosphorous based solvent for the separation of bisphenol-A: Batch studies

    Batra, SakshiArya, AnkitIqbal, MuzaffarAwasthi, Anjali...
    4页
    查看更多>>摘要:Exposure of endocrine disrupting chemicals into the environment is harmful for the human as well as wildlife. Bisphenol-A (BPA) is mainly used as a monomer for the manufacture of epoxy resins, polysulfone, polycarbonate, etc. Separation of pollutants using solvent impregnated resins becomes an attractive alternative as it combines adsorption, ion exchange and solvent extraction. In this study, removal of BPA was done using tri-n-butyl phosphate, an organophosphorous compound, impregnated Amberlite XAD-7HP resin (PX7). Effect of contact time, adsorbent dosage, initial concentration of BPA, and temperature were investigated on the separation efficiency of the resin. Experiments were performed in batch mode.

    Green extraction of betacyanin from beetroot peel using microwave and ultrasound technology

    Sharma, AlokKeshav, AmitMazumdar, Bidyut
    4页
    查看更多>>摘要:The extraction of phytochemicals from waste food sources and other byproducts has emerged a major step towards sustainable technology. Beetroot is the widely preferred source for commercial extraction of betacyanin. Water was used as a green solvent for the extraction. Microwave and ultrasound technology were used to extract betacyanin from dried and powdered beetroot peel. The recovery was observed to greater at higher temperature for low extraction time. The betacyanin content for microwave extraction and ultrasound extraction was 58.16 mg/g and 55.36 mg/g, respectively. The microwave technology was proved to be better in comparison to ultrasound technology for extraction of betacyanin content.

    Performance analysis of solar energy operated crop cutting machine

    Singh, AbhayDev, RahulSamdarshi, S. K.
    7页
    查看更多>>摘要:The research aims to analyse the performance of solar energy operated crop cutting machine (SEOCCM). During the cutting of crops, farmers face harsh climatic conditions such as summer (for cutting crops of wheat, sugarcane, corn, mustard, etc.), and winter (for cutting crops of rice, sunflower, herbs, etc.). It is a general observation that to avoid such harsh conditions of weather, the farmer used to cut the crop during the night (in summer especially) and sometimes face accidents such as snakebite, insect bite, or wild animal's attacks which lead to the death of several farmers. As manual cutting (i. e. utilising by manpower) takes several hours, sometimes a farmer loses his crop due to a sudden change in weather such as rain. There are various machines available such as harvester which consumes either conventional fuel (Diesel) or electricity which leads to air pollution. Hence, there is a requirement of a machine which consumes no conventional energy, saves both time and cost. To get rid of all, SEOCCM is conceptualized for providing a solution to the farmer who cut the crop manually or using a conventional source of energy. It is fabricated using a PV module (165 W-p), DC motor (250 W, 12 V, 4.2 A, 1500 rpm), cutter (diameter of 250 mm, tips of Tungsten Carbide), charge controller, battery (80 Ah) and iron frame. SEOCCM saves a conventional source of energy (e.g. fuel, or electricity) as it works on solar energy which is a renewable form of energy. The other features of SEOCCM include: (i) provisions for water bottle, (ii) meal, (iii) umbrella, (iv) LED light, (v) Insect rappeler (by ultrasonic sound waves).

    Adsorption of As(III) on surface modified coconut husk in fixed bed column

    Gautam, S. B.Kamsonlian, S.Alam, M. Siraj
    6页
    查看更多>>摘要:Column studies with iron impregnated coconut husk (IICH) were carried out to demonstrate its potential and for practical suitability as an adsorbent for treatment of water containing arsenic(III) i.e. As(III) at industrial scale. The required experimentations were performed and using the data generated, the breakthrough curves were prepared depicting the adsorption of As(III) on IICH at different concentration (10-100 mg/L), different bed depth (10-30 cm) and different flow rate (1-4 ml/L) with the constant initial pH of influent solution 7.5. On analyzing the data, the breakthrough time was observed to decrease with increase in initial As(III) concentration and flow rate but it increases with an increase in bed height. The higher value of bed height is not recommended. The experimental data obtained during this work were fitted with Thomas model at different experimental conditions of inlet concentration, bed height and flow rate. The experimental breakthrough curves were close to the predicted by Thomas model.

    Removal of Acid blue 113 dye in a moving bed biofilm reactor using isolated bacterial species

    Swain, GaneshSonwani, R. K.Singh, R. S.Jaiswal, Ravi P....
    5页
    查看更多>>摘要:Acid blue 113 (AB113), an azo dye, is found in the wastewater released from leather, textile, tannery, and paper printing industries. It is toxic, carcinogenic, and mutagenic, causes adverse effects on the eco-system. In this study, polypropylene-polyurethane foam (PP-PUF) was used as carriers in a lab-scale moving bed biofilm reactor (MBBR) for the removal of AB113. The process variables i.e. pH, dye concentration, and hydraulic retention time (HRT) were optimized by central composite design (CCD) of response surface methodology (RSM). The optimum value of pH and HRT were obtained as 7.0 and 20 h, respectively, for the maximum removal of dye at the highest concentration of 300 mg/L of AB113. At optimized conditions, the maximum removal of AB113 and chemical oxygen demand (COD) were found to be 72.76 and 58.84%, respectively.