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Journal of cleaner production
Butterworth-Heinemann
Journal of cleaner production

Butterworth-Heinemann

周刊

0959-6526

Journal of cleaner production/Journal Journal of cleaner productionEIISTPSCIAHCI
正式出版
收录年代

    Co-pyrolysis-to-co-gasification continuum of Pennisetum hydridum and waste tires: Temperature/atmosphere/synergy characterization of tar/ char/gas products

    Sen LinXin ChenGuopeng KeJingyong Liu...
    147655.1-147655.21页
    查看更多>>摘要:This study characterized the generation and transformation of tars, chars, and gases during the co-pyrolysis-to- co-gasification continuum of Pennisetum hydridum (PHY) and waste tires (WT) as a product of temperature, atmosphere, and synergy. Light tar components (ketones, furans, phenols, and acids) present in primary low- temperature pyrolytic oil underwent deoxygenation and ring-opening, transforming into hydrocarbons. These hydrocarbons were subsequently converted to thermally stable polycyclic aromatic hydrocarbons (PAHs) in high-temperature tar via reforming reactions. WT enhanced the deoxygenation of oxygen-containing compounds derived from PHY and supplied a carbon chain framework, promoting PAHs formation. CO_2 primarily facilitated the thermal cracking of phenols, furans, and ketones into PAHs precursors, thus favoring aromatization. However, at 750 ℃, CO_2 shifted carbon allocation in organic products toward CO, suppressing PAHs formation. For char products, elevated temperatures and CO_2 gasification significantly enhanced the application potential for porous carbon by increasing specific surface area, pore volume, and porosity. At 950 ℃, specific surface area of char increased by 504.08 % in N_2/CO_2 and 643.99 % in pure CO_2 compared to reference conditions. The addition of highly volatile PHY promoted S transfer from the char phase to the gas and oil phases. S retained in the char formed stable aromatic S compounds through cyclization reactions, with its preferential distribution within high- temperature char. These results provide valuable insights for controlling high-temperature tar formation, utilizing char resources, and managing S-containing pollutants during co-pyrolysis-to-co-gasification continuum.

    Climate-sensitive optimization of autonomous hybrid photovoltaic/ battery/hydrogen systems for net-zero energy rural buildings via particle swarm optimization

    Anouar TribicheNiima Es-SakaliSaid LaasriAmine Alaoui Belghiti...
    147667.1-147667.27页
    查看更多>>摘要:To achieve carbon neutrality in the built environment, designers worldwide must prioritize the development of more sustainable buildings, particularly those integrating hybrid solar configurations, to reduce reliance on conventional energy sources. In this context, energy storage systems are quintessential. Although numerous studies have examined the techno-economic performance of hybrid solar Photovoltaic (PV)/battery/hydrogen systems, the substantial potential of hydrogen under different climate zones, load profiles, and parameter variations in the off-grid building stocks remains underexplored. This study seeks to address this gap by comprehensively investigating PV/battery/hydrogen systems through a tailored optimization workflow while accounting for the dynamic interrelation between hourly spatiotemporal variations in solar energy output and energy demand across six different climate zones. In addition to optimizing the number and tilt angle of photovoltaic panels, the battery capacity, and storage modulation coefficient, the workflow optimally sizes the key hydrogen system components, including the electrolyzer, storage tank, and fuel cell. The main objective is to minimize the Levelized Cost of Energy (LCOE) via Particle Swarm Optimization (PSO) and compare it against two other metaheuristic algorithms: Genetic Algorithm (GA) and Ant Colony Optimization (ACO). PSO proved its superiority by providing relatively lower LCOE values of 0.44-0.7 $/kWh, while ensuring the targeted Self- Sufficiency Ratio (SSR) of 100 %. Moreover, incorporating the hydrogen system reduces the LCOE by up to 0.12 $/kWh (15.4 %) in Ifrane, compared to battery-only systems. These findings highlight the importance of climate-sensitive design and hybrid storage strategies in enhancing the economic and energy resilience of off-grid net-zero energy buildings. At an SSR of 90 %, LCOE ranges between 0.28 and 0.37 $/kWh, reflecting a 36.4-54.3 % cost reduction. This shows that fully renewable systems, while feasible, may incur substantially higher costs of electricity. Interestingly, the sensitivity analysis reveals that the optimal configurations are highly sensitive to the discount rate, as a reduction from 5 % to 2 % leads to an LCOE decrease of up to 0.097 $/kWh, followed by the battery's techno-economic parameters. Lastly, the Monte Carlo-based uncertainty analysis further shows that the optimized LCOE values consistently fall within the interquartile range of the probability distributions, confirming the consistency of the optimal solutions.

    Clear skies ahead: How park city construction improved air quality?

    Ming ZengWeike Zhang
    147673.1-147673.11页
    查看更多>>摘要:Park city construction (PCC), as an innovative urban construction concept, has been given a high hope of improving air quality. Chengdu, as the first pilot city to build a park city in China, has made a series of achievements in PCC. This study aims to assess the impact of Chengdu's PCC on its air quality and the underlying mechanisms, using the Synthetic Control Method (SCM). The findings demonstrate a substantial enhancement in air quality in Chengdu due to the PCC. In the four-year period following the implementation of the PCC, it is estimated that the Air Quality Index (AQI) experienced reductions of 7.826, 6.579, 7.817, and 0.861 units, respectively. Nevertheless, the available evidence indicates that the role of Chengdu's PCC in PM2.5 reduction is not significant. Path analysis reveals that the enhanced air quality in Chengdu can be attributed to the expansion of green spaces, acceleration of industrial green transformation, and increased energy efficiency facilitated by the PCC. These findings offer evidence to enhance the PCC in Chengdu, particularly with regard to the mitigation of PM2.5 levels. Additionally, this study presents empirical evidence supporting the advancement of PCC in a greater number of urban areas.

    Carbon footprints of recycling straw waste into building materials: A life cycle assessment (LCA) study

    Xiaoyu ShangHuatong ShiYulin LiJingwei Yang...
    147679.1-147679.25页
    查看更多>>摘要:A life cycle assessment (LCA) was conducted to evaluate the carbon footprint and resource efficiency of recycling straw waste into building materials. Three straw valorization pathways-straw resin-bonded particleboard (SRBP), straw cement-bonded particleboard (SCBP), and straw-based supplementary cementitious material (SCM)-were assessed and compared with the prevailing practice of straw open burning (SOB). Environmental and economic performance was evaluated in terms of greenhouse gas (GHG) emissions, global warming potential (GWP), non-renewable energy consumption, resource expenditure, and cost-carbon synergy indices. The assessment adopts a dual-dimensional framework, combining horizontal comparison among straw management scenarios with vertical benchmarking against conventional wood-based particleboards. Methodological novelty is further achieved by integrating a cost-carbon synergy index with a one-million-iteration Monte Carlo simulation to jointly quantify economic-environmental performance and uncertainty, and by grounding the analysis in region-specific industrial data from Jilin Province to support policy-relevant conclusions. Results show that SCM exhibits the lowest carbon footprint (273.18 kg CO_2eq per ton of straw), whereas SOB produces the highest emissions (2834.80 kg CO_2eq/t). Relative to conventional wood-based boards, SRBP and SCBP reduce GHG emissions by 9.90 % and 4.53 %, respectively, while lowering non-renewable energy demand by up to 3.08 % and 14.88 %. SCM achieves the largest emission mitigation potential, with a unit abatement cost of 0.072 CNY per kg CO_2eq, substantially below representative social carbon cost thresholds, whereas SRBP and SCBP achieve positive cost-carbon synergy without direct fiscal support. Sensitivity analysis identifies transportation distance and molding electricity as dominant GWP drivers, and Monte Carlo simulation confirms the robustness of scenario ranking under parameter uncertainty. Overall, SRBP and SCBP offer economically viable pathways with synergistic emission reductions, while SCM provides substantial climate benefits through deep emission mitigation. These findings support targeted promotion of straw-based particleboards and the development of carbon- trading mechanisms for SCM, alongside logistics optimization and process-level emission reduction strategies.

    Can the urban environmental resilience facilitate the sustainable development of the coastal city: evidence from China

    Ranran LiYekun ZhangHaimin Miao
    147689.1-147689.15页
    查看更多>>摘要:The United Nations' 2030 Agenda for Sustainable Development emphasizes conserving marine resources, making sustainable ocean economies a global priority. Coastal cities, critical hubs for marine-terrestrial systems, face dual pressures: driving growth and managing climate risks. This research examines how urban environmental resilience facilitates the sustainable marine economic development of coastal cities. Using data from 51 Chinese coastal cities spanning 2007 to 2022, the research constructs multidimensional indices for Marine Economy- Society Comprehensive Benefit Index and Environmental Resilience. To analyze the relationships, a two-way fixed-effects model is utilized. The analysis reveals that environmental resilience enhances the sustainable marine economic development, and with the mediating role of Foreign Direct Investment. Results demonstrate a nonlinear threshold effect: resilience significantly boosts sustainability in medium-resilience cities but yields diminishing returns in high-resilience regions. Regional heterogeneity is evident, with southern cities benefiting more due to export-oriented economies and disaster exposure, while northern cities face structural constraints. By integrating environmental and sustainable metrics, this research offers new insights into the resilience- sustainability linkages, enriches coastal studies with threshold and mediation frameworks, and provides actionable foundations for policymakers to tailor development strategies to local capacities.

    Carbon mitigation benefits brought by green manufacturing: Evidence from China's 'green factory' program

    Zhixiang YinZhenbang YueZongyi Yin
    147690.1-147690.15页
    查看更多>>摘要:The green transformation of the manufacturing sector is pivotal for firms to meet carbon emission reduction objectives, acting as a crucial lever in the broader shift toward a low-carbon global economy. This study leverages China's voluntary environmental regulatory initiative-the "green factory" program-to empirically examine the impact of green manufacturing on corporate carbon emissions. Using a staggered difference-in- differences (DID) model and panel data (2012-2023) on China's A-share manufacturing firms, we find that green manufacturing significantly lowers carbon emissions. The findings are robust to parallel trend assumption, placebo tests, and controls for confounding policy effects. Mechanism analysis reveals that green manufacturing fosters substantial improvements in breakthrough green innovation, facilitates the utilization of data element and promotes the diversification of knowledge within enterprises-factors that collectively enhance their emission reduction benefits. Additionally, the heterogeneity analysis reveals that compared with manufacturing enter-prises confronting higher risks of transboundary pollution transfer, operating in heavily polluting industries, and characterized by labor-biased technological progress, the carbon mitigation dividends of green manufacturing are more pronounced in those with lower transboundary pollution transfer risks, belonging to non-heavily polluting industries, and featuring capital-biased technological progress. This study offers valuable empirical insights and policy implications for developing economies striving to align industrial upgrading with environmental sustainability goals.

    Assessment of Rugulopteryx okamurae seaweed as source of sustainable alginate gels with polyphenols from orange peel

    Ismael SantanaManuel FelixSara CabezudoPedro Guerrero...
    147722.1-147722.9页
    查看更多>>摘要:This study explores the utilization of an invasive brown seaweed from the Strait of Gibraltar, Rugulopteryx okamurae (RO), as a source for alginate. Extracted alginate was used to create a hydrogel matrix for the encapsulation of polyphenols extracted from orange peel (OP). This approach addresses two environmental challenges: the ecological threat posed by RO and the significant waste generated by orange production. Around 2.5 Mtons of orange waste are annually produced in the European Union, being OP the main fraction (40-55% w/w). The alginate was gelled using calcium salts, and the resulting gels were then fortified with OP extracts. The addition of these polyphenols significantly improved the mechanical properties of the gels, leading to higher viscoelastic moduli. Although water absorption was not affected, the gels exhibited enhanced water-holding capacity and reduced material loss when immersed in water. This is likely due to the promotion of hydrogen bonding by the polyphenolic compounds, which strengthens the gel network. Spectrophotometric analysis confirmed the successful encapsulation of the OP polyphenols within the alginate matrix. A Life Cycle Analysis (LCA) of the alginate extraction process identified electricity consumption and wastewater treatment as key environmental impact factors. This research highlights a promising, sustainable method to convert an ecological issue into a valuable resource for developing encapsulation systems with improved functional properties.

    Biodegradable and non-biodegradable microplastics on methane emissions from sewer sediments: changes in enzyme activity and microbial communities

    Yan WuLuyue ZhangSongtao LiuJinhui Chen...
    147726.1-147726.10页
    查看更多>>摘要:Microplastics (MPs) are widespread in sewer systems, but how different MPs affect methane emissions from sewer systems remains unclear. Three typical MPs, non-biodegradable MPs (polypropylene (PP) and polyamide (PA)), and biodegradable MPs (polylactic acid (PLA)), were added to the sewer sediments at different concen-trations (7 and 20 particles/gww TS) and incubated for 70 days. The effects of PP and PA on methane production were concentration-dependent: the addition of PP increased methane production by 16.90%-20.40%, while the addition of PA decreased it by 9.11%-54.67%. By contrast, 20 particles/gww PLA produced the most significant increase in methane relative to the control. MPs promote the decomposition of 15%-50% of organic matter in sewage sludge. Simultaneously, the change in enzyme activity depends on the properties of the MPs. Microbial community analysis indicates that MPs reduce microbial diversity, with variations observed. These findings reveal the effect of MPs on methane emissions in sewers and the mechanisms by which MPs modulate the "organic matter-reactive oxygen species-enzyme activity-microorganisms" pathway to affect methanogenesis. The study provides valuable insights into the environmental impact of MPs in sewer systems and their effect on methane production.