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Waste and biomass valorization
Springer
Waste and biomass valorization

Springer

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1877-2641

Waste and biomass valorization/Journal Waste and biomass valorizationEISCIISTP
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    Microalgal Biomass as Renewable, Sustainable, and Peerless Biorefinery Resource for Bioenergy Production: A Narrative Overview

    Subramaniapillai NijuKamaraj SriramSundramurthy Venkatesa PrabhuLata Deso Abo...
    2461-2493页
    查看更多>>摘要:Abstract The rate of depletion of fossil fuels triggered the global community to look for different non-conventional energy sources. In this line, numerous recently discovered renewable energy sources are being investigated for their potential to serve as sustainable fuel sources. Among them, biofuel production technologies are emerging as a key solution to this energy crisis since it has mass production capacity through environment friendly techniques. The first-generation biofuel involves the utilization of food crops, such as sugar cane, sugar beet and some edible oils, however, it arises a question of food or fuel crisis in consumption chain. The second-generation biofuel replaced the usage of food crops with non-edible lignocellulose feedstocks, such as agricultural wastes and non-food crops. Even though it reduced the usage of food crops for the fuel production, the sources for the second-generation biofuel are non-reliable; infusing pressure on land utility for the cultivation of non-food crops. In essence, microalgal biomass represents a third-generation biofuel feedstock that addresses many limitations of first and second-generation biofuels. The potential of micro algae for biofuel production at cheap cost without environmental damage, as well as their ability to grow in large quantities even in limited area, raise hopes for biofuels as a potential future energy source. Its inherent renewability, sustainable cultivation practices, and the potential for a multi-product biorefinery approach, microalgae represent a valuable resource for advancing global bioenergy production and promoting a more sustainable future. Microalgae are rich in lipids, carbohydrates, and proteins that can be converted into various bioenergy products, such as biodiesel, bioethanol, biogas, and biohydrogen. Their high lipid content, in particular, makes them an exceptional candidate for biodiesel production, with certain species accumulating up to 50–70% of their dry weight as lipids under optimized condition. While challenges related to large-scale cultivation and cost-effective downstream processing persist, ongoing research and technological advancements are enhancing the feasibility of microalgae as a cornerstone of the bioenergy landscape. In view of this review has been articulated toward to look over the prominence of microalgae as an alternative futuristic biofuel resource. Herein, emphasis is given on recent microalgae research outcomes on design of microalgae cultivation systems, conditions that impact the biomass yield, harvesting strategies, and various approaches of biofuel production from the microalgae biomass.

    Deep Eutectic Solvents in the Valorization of Spent Coffee Grounds: A Review of High-Value Compound Extraction

    Cristiane Nunes da SilvaAilton Cesar LemesBernardo Dias Ribeiro
    2495-2524页
    查看更多>>摘要:Abstract Coffee processing is one of the largest agricultural sectors in the world, but it is responsible for generating 15–20 million tons of coffee by-products per year. These by-products are generated at all supply chain stages, from harvesting to brewing, with spent coffee grounds (SCG) being the by-product generated after brewing the coffee beverage. For every 1 kg of coffee powder, 2 kg of spent coffee grounds are generated with a moisture content of around 60–80%. Improper disposal can significantly impact the environment by polluting natural resources and increasing the growth of disease-carrying microorganisms and insects. On the other hand, some chemical compounds in the composition of SCG can have toxic effects, inhibiting plant growth and soil microbiota. SCG contains chlorogenic acids (0.04–0.10 g/100 g), caffeine (0.46–0.83 g/100 g), oil (9.95–24.30 g/100 g), fiber (47.30–60.46 g/100 g), proteins (2.29–16.12 g/100 g), carbohydrates (24.09–69.46 g/100 g). These components can be isolated and converted into high-added-value products, which may exhibit different biological properties. After proper extraction and processing, these components can be applied in the pharmaceutical, food, and cosmetic industries. Deep eutectic solvents (DES) stand out for being sustainable, biodegradable, and less toxic, making them promising solvents for the recovery of high-added-value compounds from SCG. One of DESs main advantages is its possible recovery and reuse in other extraction processes. Therefore, this paper explores using DES in extracting high-aggregate compounds from SCG, showing their advantages, classifications, and physicochemical properties as a possible alternative to conventional extraction methods.Graphical Abstract

    Processing of Marine Derived By-Products and Their Applications: A Review

    Abdul RahamanAnkita KumariXin-An ZengAli Korin...
    2525-2541页
    查看更多>>摘要:Abstract The seafood processing industry produces large volumes of by-products such as skins, bones, shells, and viscera that are rich in valuable proteins and polysaccharides but remain underutilized. With up to 60% of marine biomass discarded as waste, innovative valorization strategies offer a way to enhance resource efficiency and reduce environmental impact. Marine proteins possess excellent emulsifying, gelling, and water-binding properties, making them ideal for use in plant-based meats, dairy alternatives, and nutritional products. Marine polysaccharides function as natural preservatives, edible coatings, and fat replacers, supporting clean-label food innovations and extending shelf life. In addition to their functional roles, these compounds offer nutritional advantages, including complete amino acid profiles and bioactive peptides with health-promoting effects. Their incorporation into food systems supports the circular economy and aligns with UN Sustainable Development Goals by minimizing waste and promoting sustainable consumption. However, scaling production, ensuring affordability, and achieving consumer acceptance remain key challenges. This review explores the applications, benefits, and commercialization barriers of marine-derived proteins and polysaccharides, highlighting their potential to drive sustainable and functional food innovation.

    Enhanced Household Food Waste Composting Through Biochar and Green Waste Mixture Utilization as Bulking Agent

    Rajendra Prasad SinghYixin YanAozhan LiuQingyu Shang...
    2543-2553页

    Biorefinery Process and Mass Balance Study of Sugarcane Straw for Sugar and Lignin Production Through One- and Two-Step Pretreatments

    Fahriya Puspita SariAzizatul KarimahMaya IsmayatiNissa Nurfajrin Solihat...
    2555-2568页
    查看更多>>摘要:Abstract The use of cellulose for reducing sugars and lignin for biosurfactants may provide a promising strategy for establishing a sugarcane straw (SS) biorefinery. Selecting a suitable pretreatment method is crucial for assessing the effectiveness of the biomass conversion process. This study aimed to establish an efficient biorefinery pathway for sugar production as well as mass balance studies of component fractions for each step of pretreatment. Currently, a two-step pretreatment method was developed consisting of microwave (MW)-assisted maleic acid pretreatment, as the 1st step, followed by the 2nd step by either MW-assisted or autoclave-assisted alkali pretreatment. The comprehensive mass balance of the SS during both one-step (1-S) and two-step (2-S) pretreatments, as well as the enzymatic hydrolysis process, was assessed. During the 1-S pretreatment, 71% of the hemicellulose in the liquid fraction was solubilized as xylose, whereas during the 2-S pretreatment, the majority of the lignin in the liquid fraction was dissolved. A significant disruption in the fiber structure was observed during autoclave-alkali pretreatment. This treatment increased the surface area and pore volume of the fibers, facilitating enzymatic accessibility. 1-S pretreatment resulted in the highest xylose and glucose concentrations of 21.52 g and 18.66 g, respectively. Moreover, 6.9 g and 7.8 g of isolated lignin were obtained from the MW-alkali and autoclaved alkali solutions, respectively. These findings highlight the importance of pretreatment in optimizing value-added product yields from SS, contributing to the development of an efficient and sustainable biorefinery.

    Coupling Mechanisms and Synergistic Effects in Portland Cement-Ceramic Powder-Ground Granulated Blast Furnace Slag-CFB Desulfurization Ash Composite Binder

    Yannian ZhangWenliang LiuQingJie WangLin Zhang...
    2569-2580页
    查看更多>>摘要:Abstract The development of sustainable cementitious materials has become a critical issue in the construction industry, particularly in enhancing the performance of Portland cement-based binders while reducing environmental burden. Based on the coupling mechanism and synergistic effect of raw materials, a composite binder was prepared in this study using ordinary portland cement (OPC) combined with ceramic powder (CP), ground granulated blast furnace slag (GGBFS), circulating fluidised bed desulphurisation ash (CFBDA). Comprehensive experimental methods, including activity index analysis, water absorption tests, X-ray diffraction (XRD), thermogravimetric analysis (DTG/TG), and scanning electron microscopy (SEM), were employed to assess the material performance. The results showed that the incorporation of CP, GGBFS, and CFBDA significantly enhances the pozzolanic reactivity and reduces water absorption, indicating improved mechanical properties and microstructural compactness. XRD and DTG/TG analyses confirmed that the addition of CFBDA and GGBFS accelerated the formation of C-S-H gel and promoted the consumption of CH, thereby enhancing hydration efficiency. SEM imaging further revealed a highly compact microstructure with C-S-H gels encapsulating CH crystals in the ternary system. The study concludes that the synergistic effect between CP, GGBFS, and CFBDA promoted hydration reactions, refined the microstructure, and improveds the overall performance of the composite binder. These findings offer valuable insights into the design of sustainable cementitious materials, which not only contribute to enhancing the durability of concrete but also help in the effective utilization of industrial by-products, promoting sustainability in the construction industry.

    Cultivation of Microalgae in Combined Piggery and Domestic Wastewater: Induced C16-C18 Fatty Acids, Nutrient Removal, and Biodiesel Production

    Monika SharmaMabkhoot AlsaiariMohammed JalalahFarid A. Harraz...
    2581-2595页
    查看更多>>摘要:Abstract Microalgal cultivation in single wastewater limits their scale-up due to insufficient or extremely high nutrient levels. Thus, a combination of different wastewaters is a potential approach for microalgal cultivation, as it regulates the nutrient levels among the wastewaters. In this study, primary domestic wastewater (PDW) and primary piggery wastewater (PPW) were collected and subjected to comprehensive physicochemical characterization. The wastewaters were subsequently mixed at volumetric ratios of 1.25%, 2.5%, and 5% (PPW: PDW) to serve as growth media for microalgal cultivation. The optimal microalgal growth (1.105 g L− 1) and maximal nutrient removal efficiencies (93.58% total nitrogen; 97.74% total phosphorus) were highest in the 1.25% PPW treatment. Gas chromatography analysis revealed a predominance of four major fatty acids (FAs) as palmitic acid (33.18%), trans-9-elaidic acid (25.39%), linoleic acid (16.96%), and oleic acid (14.22%). The 1.25% PPW treatment showed particularly favourable biodiesel feedstock characteristics, evidenced by high monounsaturated fatty acid content (45.97% of total FAs) and dominant C16-C18 (97.64% of total FAs). The 1.25% PPW ratio was identified as the optimal condition, which significantly maximized nutrient removal, promising the potential for biodiesel production. The dual function of microalgal systems emphasizes their ability to produce high-value biomass while also treating wastewater.Graphical Abstract

    Development of Phytocompounds Decorated Sustainable Aa-ZnO Nanoparticles Using Leaf Extract of Agave americana Plant for Anticancer Application

    Siva Chander ChabattulaSrishti RaiKavitha GovarthananKalpana Balakrishnan...
    2597-2609页
    查看更多>>摘要:Abstract In recent years, the green synthesis of metal nanoparticles (MNPs) has gained enormous attention for imaging and therapeutic applications due to their lesser toxicity, biodegradability, and cost-effectiveness. The phytocompounds decorated MNPs have also shown promising results during cancer treatment as an alternative approach to chemotherapy. This study uses the Agave americana (Aa) plant’s leaf extract to synthesize Aa-ZnO NPs. The obtained NPs were physicochemically and biologically characterized. XRD results confirmed the crystalline structure of NPs. During the DLS experiment, the average hydrodynamic size and average zeta potential of NPs were calculated to be 538.61 ± 34.95 d.nm and − 12.03 ± 5.68 mV, respectively. FE-SEM and HR-TEM revealed the triangular shape of NPs. Next, Aa-ZnO NPs were found to be biocompatible and hemocompatible in nature when tested on mouse fibroblasts and 2% RBC suspension, respectively. In addition, Aa-ZnO NPs also exhibited potent anticancer activity against A549 and HeLa cells, inducing apoptosis in cancer cells. These findings show that Aa-ZnO NPs may be used as therapeutic agents during cancer treatment.Graphical Abstract

    Utilization of Secondary Aluminum Ash: Synthesis, Characterization of Crystalline Al2O3 and Performance Study of Aluminum - based Phase Change Materials

    Tao JingXufei ZhouYikun KangMin Li...
    2611-2629页
    查看更多>>摘要:Abstract This study focus on recycling secondary aluminum ash (SAA), a hazardous industrial waste with low reusability and high environmental pollution, into high-performance energy storage materials. The methodology involves a modified low-temperature alkaline melting-acid leaching process: SAA is sintered at 200–600 °C, leached with water/acid, and calcined at 550–1100 °C to synthesize four crystalline Al2O3 phases (γ-, δ-, θ-, α- Al2O3), whose transformation mechanisms are analyzed via XRD, SEM, and FTIR. For the Al/ Al2O3 composite phase change materials (PCMs), metallic aluminum serves as the primary phase change component, and the optimal pressing conditions are determined as 10 MPa pressure and 10-minute holding time, with a mass ratio of Al to Al2O3 optimized at 4:6. Key results show that the Al/δ- Al2O3 PCM exhibits the highest initial heat storage density of 950.33 kJ/kg, retaining 54% (509.82 kJ/kg) after 30 thermal cycles without leakage or structural failure, while all composites have weight loss < 15%. The study highlights that Al2O3 crystal forms influence PCM performance: γ-/δ- Al2O3 enhance heat storage capacity, and α- Al2O3 improves thermal conductivity. This work not only provides an innovative recycling approach for SAA but also develops sustainable high-temperature PCMs, offering environmental benefits through reduced industrial waste and promoting the circular economy, with results aligning closely with conclusions on waste-to-energy conversion and material performance.

    Mixture Design for Mixed Plastic Pyrolysis: Modelling of Yield, Oil Quality and Oil Composition by Feed Composition

    Rasmus U. HennebergJesper ThygesenRudi P. NielsenMorten E. Simonsen...
    2631-2647页
    查看更多>>摘要:Abstract Pyrolysis of plastics has been shown to form oil, gas, and char. Interaction effects affect the distribution of the product phases as well as the oil and gas compositions, making it difficult to predict the pyrolysis product of polymer mixtures. This project aimed to create predictive models for the prediction of oil and char yield as well as acid number, viscosity of the oil and oil composition. This was done utilizing a simplex lattice mixture design and Scheffé polynomial models. Pyrolysis of a fixed amount of polypropylene (PP), polyethylene (PE), and polyethylene terephthalate (PET) and 0–20 wt.% of polyamide 6 (PA6), polystyrene (PS), and ethylene–vinyl acetate (EVA) were performed in a batch reactor with fixed process variables. The main oil compounds were 2,4-dimethyl-1-heptene due to PP and styrene due to PS. Predictive models were successfully developed for determining the oil composition based on the feedstock composition, most with an explanation degree ranging from 0.503 to 0.985. The composition was severely affected by the PS content, due to the large amount of styrene and toluene affecting the composition. A significant interaction effect between PA6 and EVA, as well as EVA and PS was shown to increase oil yield. Increasing the PA6 content decreased the oil production and increased the char product. The acid number increases with EVA and the viscosity increases with the PA6 content.Graphical Abstract