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材料科学技术(英文版)
材料科学技术(英文版)

胡壮麟

月刊

1005-0302

jmst@imr.ac.cn

024-83978208

110016

沈阳市沈河区文化路72号

材料科学技术(英文版)/Journal Journal of Materials Science & TechnologyCSCDCSTPCD北大核心EISCI
查看更多>>本刊简称《JMST》,(ISSN 1005-0302,CN 21-1315/TG)。1985年创刊。是中国科协主管,中国金属学会,中国材料研究学会和中国科学院金属研究所联合主办的国际性英文期刊,以“加强国际交流,扩大学术影响,服务经济建设”为办刊宗旨,刊登世界各国的具有创新性和较高学术水平的原始性论文,并设有物约综述、快报、简讯及国内外材料界杰出学者简介等栏目,内容包括金属材料、无机非金属材料、复合材料及有机高分子材料等。
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    Synthesis of surface imprinted polymers based on wrinkled flower-like magnetic graphene microspheres with favorable recognition ability for BSA

    Zuoting YangKe YangYuhong CuiTariq Shah...
    203-215页
    查看更多>>摘要:Nowadays,the employing of molecular imprinting technique in the analysis and separation of proteins from complex biological samples has been widely favored by researchers.To enrich the types of surface protein imprinted materials and expand the application fields of graphene materials,novel surface molecular imprinted polymers (MIPs) based on magnetic graphene microspheres Fe304@rGO@MIPs are first synthesized in this paper.Fe304@rGO@MIPs are prepared by oxidative self-polymerization of dopamine on the surface of magnetic graphene (Fe304@rGO) composite microspheres.Bovine serum albumin (BSA) is selected as protein template.Fe3O4@rGO microspheres with wrinkled flower-like structure are obtained by compounding Fe3O4 and graphene oxide in an appropriate ratio via the method of high-temperature reduction self-assembly.The microspheres exhibit promising dispersibility,high external surface area,rich pore structure,and sufficient magnetic properties.These advantages not only prevent the agglomeration of imprinted microspheres in the aqueous phase,which is conducive to contact and static adsorption,but also increase the amount of protein imprinting.Additionally,sufficient magnetic properties ensure fast and effective separation of the adsorbents.While the adsorption capacity is increased,the separation procedure becomes simple.The binding capacity of Fe304@rGO@MIPs for BSA can reach 317.58 mg/g within 60 min,and the imprinting factor (IF) is 4.24.More importantly,Fe3O4@rGO@MIPs can specifically recognize the target BSA from the mixed proteins and the actual sample.There is no significant decrease in the adsorption amount,IF,and magnetic properties after eight runs.It is promising to be used in the separation of proteins from the actual biological samples.

    Binary Zn-Ti alloys for orthopedic applications: Corrosion and degradation behaviors, friction and wear performance, and cytotoxicity

    Kun WangXian TongJixing LinAiping Wei...
    216-229页
    查看更多>>摘要:Zinc (Zn) and its biocompatible and biodegradable alloys have substantial potential for use in orthopedic implants.Nevertheless,pure Zn with a hexagonal close-packed crystal structure has only two independent slip systems,therefore exhibiting extremely low elongation and yield strength in its ascast condition,which restricts its clinical applications.In this study,as-cast Zn-xTi (titanium) (x =0.05,0.10,0.20,and 0.30 wt.%) binary alloys were hot-rolled and their microstructures,mechanical properties,wear resistance,and cytocompatibility were comprehensively investigated for orthopedic implant applications.The microstructures of both as-cast and hot-rolled Zn-xTi alloys consisted o fan α-Zn matrix phase and a TiZn16 phase,while Zn-0.2Ti and Zn-0.3Ti exhibited a finer α-Zn phase due to the grainrefining effect of Ti.The hot-rolled Zn-0.2Ti alloy exhibited the highest yield strength (144.5 MPa),ultimate strength (218.7 MPa),and elongation (54.2%) among all the Zn-xTi alloys.The corrosion resis-tance of Zn-xTi alloys in Hanks' solution decreased with increasing addition of Ti,and the hot-rolled Zn-0.3Ti alloy exhibited the highest corrosion rates of 432 μm/y as measured by electrochemical testing and 57.9 μm/y as measured by immersion testing.The as-cast Zn-xTi alloys showed lower wear losses than their hot-rolled counterparts.The extracts of hot-rolled Zn-xTi alloys at concentrations of ≤ 25% showed no cytotoxicity to MG-63 osteosarcoma cells and the extracts of Zn-xTi alloys exhibited enhanced cytocompatibility with increasing Ti content.

    Insights into the Ti4+ doping in P2-type Na0.67Ni0.33Mn0.52Ti0.15O2 for enhanced performance of sodium-ion batteries

    Shi TaoWei ZhouDajun WuZhicheng Wang...
    230-236页
    查看更多>>摘要:Due to the sodium abundance and availability,sodium-ion batteries (SIBs) have the potential to meet the worldwide growing demand of electrical energy storage.P2-type sodium transition-metal layer oxides with a high energy density are considered as the most promising cathode materials for SIBs.We present here a detailed study of the enhanced rate capability and cyclic stability of the Ti-doped Na0.67Ni0.33Mn0.67O2 cathode material.The combined analysis of ex-situ X-ray absorption fine structure (XAFS) spectroscopy,aberration-corrected high resolution transmission electron microscopy (AB-HRTEM) and X-ray diffraction (XRD) show that the strong Ti-O bond in the transition metal layers stabilizes the local structure,destroy the Na+-vacancy ordering and arrest the irreversible multiphase transformation that occurs during the intercalation/deintercalation process.Actually,Na0.67Ni0.33Mn0.52Ti0.15O2 exhibits a reversible capacity of 89.6 mA h g-1 even at 5 C,an excellent cyclability with 88.78 % capacity retention after 200 cycles at 0.5 C.This study provides a better understanding in optimization of the design of high-energy cathode materials based on titanium doped layered oxides for SIBs.

    Trace bis-(3-sulfopropyl)-disulfide enhanced electrodeposited copper foils

    Lingling LiuYeqiang BuYue SunJianfeng Pan...
    237-245页
    查看更多>>摘要:Smooth and strong copper foils are highly required for the development of printed circuit boards and Li-ion batteries.Adding additives is an efficient and low-cost method to enhance electrodeposited copper foils.Here we chose Bis-(3-sulfopropyl)-disulfide (SPS) as the additive and investigated its concentration on the surface roughness and tensile strength of the electrodeposited copper foils.A copper foil with the smoothest surface (Rz=2.1 μm) and the highest tensile strength (~338 MPa) was prepared with 1.5 mg/L SPS.The contact angle on the copper foil decreased with the reduction of surface roughness.The enhancing mechanism of the SPS was investigated by scanning electron microscopy and X-ray diffraction.The refined grain and enhanced (220) texture were considered to be the radical reason for the smooth and strong copper foils.The electrochemical results prove the suppressing effect is related to the SPS adsorption.

    Optimizing microstructure, shrinkage defects and mechanical performance of ZL205A alloys via coupling travelling magnetic fields with unidirectional solidification

    Lei LuoLiangshun LuoYanqing SuLin Su...
    246-258页
    查看更多>>摘要:ZL205A alloys tend to form disordered and defective microstructure due to the large solidification intervals and multi-phase.Accordingly,finding ways to effectively optimize the microstructure and mechanical performance is of great significance.In this regard,the coupling of travelling magnetic fields (TMF) with unidirectional solidification was used to continuously regulate the mushy zones of ZL205A alloys.Additionally,experiments are combined with simulations to systematically reveal the mechanisms on the optimizations at each stage of solidification process.Current findings demonstrate that different directional strong melt flows generated by TMF are responsible for these optimizations.Additionally,the effects of TMF on microstructure are different at each stage of solidification process.Specifically,downward TMF coupled with unidirectional solidification can refine and uniform the microstructure,decrease the formation of precipitation,promote the growth consistency of matrix phase α-Al growing along the <001 > crystal orientation,reduce the secondary dendrites and overlaps between dendrites,eliminate the shrinkage defects,and increase the ultimate tensile strength,yield strength,elongation and hardness from 198.3 MPa,102.2 MPa,7.5 % and 82.3 kg mm-2 without TMF to 225.5 MPa,116.1 MPa,13.6 % and 105.2 kg mm-2.Contrastively,although upward TMF can reduce Al3Ti and refine α-Al,it increases the formation of Al6Mn,Al2Cu,secondary dendrites,overlaps between dendrites,and shrinkage defects;then it deflects and disorders the growth of α-Al,further to decrease the overall performance of alloys.

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