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材料科学技术(英文版)
材料科学技术(英文版)

胡壮麟

月刊

1005-0302

jmst@imr.ac.cn

024-83978208

110016

沈阳市沈河区文化路72号

材料科学技术(英文版)/Journal Journal of Materials Science & TechnologyCSCDCSTPCD北大核心EISCI
查看更多>>本刊简称《JMST》,(ISSN 1005-0302,CN 21-1315/TG)。1985年创刊。是中国科协主管,中国金属学会,中国材料研究学会和中国科学院金属研究所联合主办的国际性英文期刊,以“加强国际交流,扩大学术影响,服务经济建设”为办刊宗旨,刊登世界各国的具有创新性和较高学术水平的原始性论文,并设有物约综述、快报、简讯及国内外材料界杰出学者简介等栏目,内容包括金属材料、无机非金属材料、复合材料及有机高分子材料等。
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    PVDF/6H-SiC composite fiber films with enhanced piezoelectric performance by interfacial engineering for diversified applications

    Linlin ZhouTao YangChunyu GuoKang Wang...
    238-245页
    查看更多>>摘要:Piezoelectric silicon carbide(SiC)has been quite attractive due to its superior chemical and physical properties as well as wide potential applications.However,the inherent brittleness and unsatisfactory piezoelectric response of piezoelectric semiconductors remain the major obstacles to their diversified ap-plications.Here,flexible multifunctional PVDF/6H-SiC composite fiber films are fabricated and utilized to assemble both piezoelectric nanogenerators(PENGs)and stress/temperature/light sensors.The open cir-cuit voltage(Voc)and the density of short circuit current(Isc)of the PENG based on the PVDF/5 wt%6H-SiC composite fiber films reach 28.94 V and 0.24 pA cm-2,showing a significant improvement of 240%and 300%compared with that based on the pure PVDF films.The effect of 6H-SiC nanoparticles(NPs)on inducing interfacial polarization and stress concentration in composite fiber films is proved by first-principles calculation and finite element analysis.The stress/temperature/light sensors based on the composite fiber film also show high sensitivity to the corresponding stimuli.This study shows that the PVDF/6H-SiC composite fiber film is a promising candidate for assembling high-performance energy har-vesters and diverse sensors.

    Injection molding of highly filled microcrystalline cellulose/polycaprolactone composites with the aid of reversible Diels-Alder reaction

    Ze Pu WangWen Hong RuanMin Zhi RongMing Qiu Zhang...
    246-254页
    查看更多>>摘要:To tackle the challenge of producing highly filled polymer composites using the traditional injection molding technique,which is characterized by the fairly high melt viscosity that makes mold filling diffi-cult,the authors propose a solution based on dynamic covalent chemistry.As demonstrated by the proof-of-concept experiments,the 4-arm star-shaped polycaprolactone(PCL)oligomers and microcrystalline cel-lulose(MCC)are crosslinked by the reversible Diels-Alder(DA)bonds.The flowability of the compounds greatly decreases due to the dissociation of the intercomponent DA bonds at the retro-reaction tempera-ture,and the networked architecture is reconstructed during cooling as a result of the forward DA reac-tion.Consequently,the high-loading MCC fillers are well distributed in the matrix and covalently bonded to the nearby PCL,forming a striking contrast to the control in which linear PCL acts as the matrix.The DA bonds crosslinked biodegradable PCL composites exhibit decent mechanical strength(20.7 MPa)even at the MCC fraction of 65 wt%,which is superior to those(5-12.2 MPa)of the highly filled PCL composites(with filler contents of 50-63.8 wt%)reported so far.The proposed approach has sufficient expansibility for the fabrication of the highly filled polymer composites constructed by other types of matrix and fillers.

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