查看更多>>摘要:The Huoshaoyun deposit in the Karakorum area of NW China is the world's largest zinc-lead carbonate ore deposit.Here we investigate the genesis of the mineralization based on multiproxy investigations.The deposit contains zinc-lead carbonate and sulfide minerals,with smithsonite(Smt),cerussite(Cer),and sulfides accounting for 85%,10%,and 5%of the total lead and zinc resources,respectively.Three ore-forming stages,involving Smt,Cer,and sulfides ores were summarized.The Smt mineralization is characterized by veined,massive,and stratified Smt forming horizontal sedimentary layered ore and ver-tical feeder veins similar to the SEDEX-type deposits.The sulfide and Cer veins display typical hydrother-mal characteristics and are superimposed on the massive Smt ores.The Smt ores show high Li,Be,Cr,Y,Ba,Nd,Yb,and Zr contents,whereas the Cer veins have extremely high Sr contents(up to 3814-9174 ppm)and low Zr contents(less than 0.01 ppm).Galena and sphalerite show higher Cd concentra-tions compared to Smt and Cer ores.The Smt ores differ with different spatial locations,with Smt ores formed at the vent have δ66Zn values of+0.15‰ to+0.21‰,the massive Smt formed close to the vent show a value of+0.13‰,and those formed away from the vent show a value of 0.05‰,all values being close to 0.The sulfides have δ66Zn values of-0.09‰ to+0.04‰.The C-O isotopes of Smt ores are similar to both altered and unaltered host limestone,suggesting that the limestone was a potential source for carbon and oxygen.Quartz with veined Smt shows magmatic signatures with δ18OVSMOW of+1.14‰ to+2.23‰,high Pb(115-401 ppm)and Zn concentrations(390-997 ppm),whereas quartz associated with sulfide has meteoric fluid signa-ture with the lowest δ18OVSMOW(-14‰ to-10.7‰),low Pb(11.6-49.0 ppm)and Zn(18.1-72.8 ppm)concentrations.The temperature of equilibration computed based on oxygen isotope fractionation between Smt and coeval quartz indicate a dual source with that of quartz derived from an aqueous fluid,whereas the source for Smt might involve CO2 or HCO3-.We trace multiple metallogenic stages for this deposit including exhalation,hydrothermal deposition,and fault-controlled sulfide vein formation.The largest orebody(Ⅲ-1)preserves a 16 Mt reserve of Zn and was formed by crust-mantle interaction at ca.195 Ma in the early development of the Linjitang post-arc rift system.Fluid convection,zinc enrichment driven by granitic magma,volcanic activity,and karst alteration induced by acid rain in a lagoonal environment promoted ore enrichment.