首页|含氟丙烯酸酯改性制备铝颜料及其漂浮性能研究

含氟丙烯酸酯改性制备铝颜料及其漂浮性能研究

扫码查看
通过两步法制备一种含氟丙烯酸酯改性制备铝颜料.首先,以丙烯酸硅烷偶联剂与正硅酸乙酯在碱性环境下协同水解,在铝颜料表面形成双键功能化二氧化硅包覆层;接着通过原位聚合再形成一层含氟包覆层,得到一种含氟丙烯酸酯改性铝颜料.利用FTIR、TG、XPS、接触角测试、光泽度测试、耐酸碱腐蚀性能测试、漂浮性能测试等一系列分析手段对改性后的铝颜料进行结构和性能的表征.结果表明:与未改性铝颜料相比,改性后的铝颜料在古马隆树脂和乙二醇丁醚中的漂浮力、对水面的遮盖力和耐酸碱性都有较大程度的提升.
Preparation of aluminium pigment modified by fluorine-containing acrylate and its floating properties
In this study,a fluorine-containing acrylate modified aluminum pigment was prepared by two-step process.Firstly,a double-bond functionalized silica coating layer was formed on the surface of aluminum pigment by the synergic hydrolysis of acrylate silane coupling agent and ethyl orthosilicate under alkaline environment.Then a fluorine-containing coating layer was formed by in-situ polymerization to obtain a fluorine-containing acrylate modified aluminum pigment.The structure and properties of the modified aluminum pigment were characterized by FTIR,TG,XPS,contact Angle test,gloss test,acid and alkali corrosion resistance test,flotation test and other analytical methods.The results showed that compared with the unmodified aluminum pigments,the modified aluminum pigments had better floatability,covering power to water surface and acid and alkali resistance in coumarone resin and ethylene glycol butyl ether.

aluminum pigmentfloatingfluorine acrylatesurface modificationin situ poly merization

佘娜、王智鑫、董前年、陈国庆、曹明、夏茹、陈鹏、钱家盛

展开 >

安徽大学化学化工学院,绿色高分子材料安徽省重点实验室,安徽 合肥 230601

合肥旭阳铝颜料有限公司,安徽 合肥 231131

铝颜料 漂浮 含氟丙烯酸酯 表面改性 原位聚合

2025

安徽大学学报(自然科学版)
安徽大学

安徽大学学报(自然科学版)

北大核心
影响因子:0.49
ISSN:1000-2162
年,卷(期):2025.49(1)