首页|纳米二氧化硅作为电解液对铅蓄电池性能的影响研究

纳米二氧化硅作为电解液对铅蓄电池性能的影响研究

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纳米二氧化硅在铅酸电池电解液中分散,形成硅溶胶电解质,通过纯铅在电解液中的性能测试,发现添加该种电解液可以显著提高铅酸电池的性能.通过CV、LSV、EIS和OCPT等电化学测试方法,模拟铅酸电池正极板在电解液中的性能,验证了二氧化硅添加剂对于铅酸电池的电容提升,增加浮充电位下的析氧过电位.利用FESEM、XRD和XPS等表征方法,证明了二氧化硅作为添加剂最优含量为0.3%,可以改善腐蚀层的颗粒均匀性,细化腐蚀层晶粒,抑制电解液对铅酸电池中极板材料的腐蚀作用.
Study on the Influence of Nano-Silica as Electrolyte on the Performance of Lead Storage Batteries
Nano silica is dispersed in the electrolyte of lead-acid batteries to form silica sol electrolytes, and through the performance test of pure lead in electrolytes. It is found that the addition of this electrolyte can significantly improve the battery performance of lead-acid batteries. In this paper, electrochemical test methods such as CV, LSV, EIS and OCPT are used to simulate the performance of the positive plate of lead-acid battery in electrolyte, and verify the capac-itance improvement of silica additives on lead-acid batteries and increase the oxygen evolution overpotential under the float charging position. FESEM, XRD and XPS characterization methods were used to prove that the optimal content of silica as an additive was 0.3%, and the addition of silica could improve the particle uniformity of the corrosion layer, refine the grains of the corrosion layer, and inhibit the corrosion effect of electrolyte on the plate materials in lead-acid batteries.

lead-acid batteryelectrolytesilica solcorrosion resistance

韩尚辰、李贝贝、李超雄、李冰

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合肥工业大学化学与化工学院,安徽合肥 230009

天能电池(安徽)有限公司,安徽界首 236516

铅酸电池 电解液 硅溶胶 耐蚀性能

安徽省科技重大专项校企合作项目

202103a05020012W2022JSFW0134

2024

安徽化工
安徽省化工研究院

安徽化工

影响因子:0.229
ISSN:1008-553X
年,卷(期):2024.50(2)
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