首页|一锅法制备MgO/蓝藻基碳介孔复合材料及CO2吸附性能研究

一锅法制备MgO/蓝藻基碳介孔复合材料及CO2吸附性能研究

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采用一锅法,以KOH活化后的蓝藻粉为碳源,以六水硝酸镁为镁源,通过简单研磨固相反应,成功制备了MgO/C复合材料,并探究了镁源和碳源的投料比对介孔MgO/C复合材料结构的影响,同时采用X-射线衍射法、N2等温吸脱附曲线法、扫描电镜法、红外光谱法、拉曼光谱法等现代技术对复合材料的组织结构进行表征.结果表明,MgO/C复合材料具有介孔结构,随着MgO负载量的增加,复合材料的比表面积和孔容下降;CO2等温吸附性能研究表明,氧化镁与碳复合后对CO2吸附能力有明显的改善,样品的孔结构对CO2吸附能力有一定程度影响.
Study on One-Potpreparation of MgO/Cyanobacteria-Based Carbon Mesoporous Composites for CO2 Capture
In this paper, the MgO/C composite was successfully prepared by using KOH activated cyanobacteria powder as carbon source and magnesium nitrate hexahydrate as magnesium source through simple grinding solid reaction. The struc-ture of mesoporous MgO/C composite was explored by comparing the feeding of magnesium source and carbon source. At the same time, X-ray diffraction, N2 isothermal adsorption and desorption curve, scanning electron microscopy, infrared spec-troscopy, Raman spectroscopy and other modern techniques were used to characterize the structure of the composite. The re-sults showed that the MgO/C composite exhibited mesoporous structure, and the specific surface and pore volume of the composite decreased with the increase of MgO/ load content. The study of CO2 isothermal adsorption performance showed that the CO2 adsorption capacity was obviously improved after the combination of MgO and carbon, and the pore structure of the sampleaffected on the CO2 adsorption capacity.

cyanobacteria powderMgO/C mesoporous compositesCO2 capture

夏煜涛、韩林松、史梦婷、张汉雨、廖永旭、丁波、齐佳慧、金效齐

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蚌埠学院材料与化学工程学院,安徽蚌埠233000

蓝藻粉 介孔MgO/C复合材料 CO2吸附

高水平科研培育项目蚌埠学院科研启动基金大学生创新创业训练计划

2021pyxm09BBXY2018KYQD22202111305006

2024

安徽化工
安徽省化工研究院

安徽化工

影响因子:0.229
ISSN:1008-553X
年,卷(期):2024.50(2)
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