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一种含有机磷清洗废水的处理技术探讨

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采用H2O2/Fe2+构成的氧化体系对含有机磷清洗废水进行催化氧化后,再采用常规的物理化学处理方法进行处理,达到有机磷的去除及降低COD指标的目的.实验分析了影响芬顿体系反应的各种因素如H2O2添加量、FeSO4添加量、反应pH、反应时间,最后总结出该反应的最佳条件:H2O2添加量50 mL/L,FeSO4添加量15 g/L,初始pH=3.0,反应时间2 h.实验中的含有机磷清洗废水源于清洗汽车玻璃表面沾染的胶状物所排放的含羟基乙叉二膦酸的废水.
Exploration of Treatment Technology for Cleaning Wastewater Containing organophosphorus
In this paper, an oxidation system composed of H2O2/Fe2+ is used to catalytically oxidize the cleaning wastewater containing organophosphorus, and then conventional physical and chemical treatment methods are used to treat it, so as to achieve the purpose of removing organophosphorus and reducing COD index. Various factors affecting the reaction of Fenton system were analyzed, including the addition amount of H2O2, the addition amount of FeSO4, the reaction pH and the reac-tion time. Finally, the optimal reaction conditions were summarized: the addition amount of H2O2 was 50 mL/L, the addition amount of FeSO4 was 15 g/L, the initial pH was 3.0, and the reaction time was 2 h. The organophosphorus-containing cleaning wastewater in the experiment was derived from the waste water containing hydroxy-ethylenediphosphonic acid dis-charged by cleaning the glue on the surface of automobile glass.

organophosphorus wastewaterFenton oxidation system:automobile glass

王振宇、王强、朱海杰、王臣、彭帅帅、郑传扬

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安徽浩悦环境科技股份有限公司,安徽合肥 231145

有机磷废水 芬顿氧化体系 汽车玻璃

2024

安徽化工
安徽省化工研究院

安徽化工

影响因子:0.229
ISSN:1008-553X
年,卷(期):2024.50(2)
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