首页|镁合金表面TiO2二维薄膜的制备及其耐腐蚀性能研究

镁合金表面TiO2二维薄膜的制备及其耐腐蚀性能研究

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由于镁是一种较为活泼的金属,容易被氧化,且生成的氧化膜不具备保护性,这会进一步加快镁的腐蚀速率.通过在镁合金表面制备一层保护膜来阻断其与腐蚀物质的接触,从而增强镁合金的耐腐蚀性.首先根据已有文献制备TiO2胶体,然后利用电泳沉积法,以镁合金基样为阳极,在其表面制备TiO2薄膜,电泳液为上述TiO2胶体,并探究了制备过程中的各项实验参数(不同电泳时间和不同沉积时间)对样品的影响.采取XRD、SEM等测试方法对制备的TiO2薄膜进行分析,并进一步测试样品的极化曲线并做出分析.通过一系列参数优化可知,最优参数为电泳电压20 V,沉积时间90 s,此时制备的TiO2薄膜的腐蚀电位最正,为-1.26 V,同时腐蚀电流密度也最低,为4.21×10-6 A/cm2.
Preparation and Corrosion Resistance of TiO2 Two-dimensional Thin Films on Magnesium Alloy Surface
As magnesium is a relatively reactive metal,it is easy to be oxidized,and the generated oxide film is not protective,which further leads to a higher corrosion rate of magnesium easily.By preparing a protective film on the surface of magnesium alloy to hinder contact with corrosive media,the contact with corrosive substances can be blocked,thus the corrosion resistance of magnesium alloy can be en-hanced.Firstly,TiO2 colloid was prepared according to the existing literature,and then TiO2 thin film was prepared on the surface of magnesium alloy base sample using electrophoretic deposition method with the above mentioned TiO2 colloid as the anode,and the effect of each experimental parameter (dif-ferent electrophoretic time and different deposition time)on the sample in the preparation step was in-vestigated.The prepared TiO2 films were analyzed by XRD,SEM and other testing methods,and the po-larization curves of the samples were further tested and analyzed.Through a series of parameter optimi-zation,it is found that the optimal parameters are electrophoresis voltage of 20 V and deposition time of 90 s.In this case,the TiO2 film prepared has the most positive corrosion potential,which is -1.26 V, and the lowest corrosion current density is 4.21×10-6 A/cm2 .

magnesium alloyselectrophoresis depositiontwo-dimensional nanomaterialsTiO2corrosion resistance

鲍钉杰、郑梦姣、刘子义、武恒、刘琪

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安徽工程大学 材料科学与工程学院,安徽 芜湖 241000

安徽信息工程学院 机械学院,安徽 芜湖 241000

镁合金 电泳沉积法 二维纳米材料 TiO2 耐腐蚀性能

安徽省自然科学基金项目

2008085ME132

2024

安徽工程大学学报
安徽工程大学

安徽工程大学学报

影响因子:0.289
ISSN:2095-0977
年,卷(期):2024.39(2)
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