首页|不同抑爆剂对锂离子电池热失控的抑制效果试验研究

不同抑爆剂对锂离子电池热失控的抑制效果试验研究

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为探究不同抑爆剂对锂离子电池热失控的抑制效果,采用七氟丙烷和全氟己酮作为抑爆剂对 18650 三元锂离子电池进行灭火抑爆试验.试验结果显示:七氟丙烷和全氟己酮均可对锂离子电池燃爆产生抑制效果,降低燃爆温度,减弱燃爆效果,抑制其热失控传播;全氟己酮抑制锂离子电池模组热失控传播的能力优于七氟丙烷,在试验中,当释放七氟丙烷抑爆剂的质量体积浓度低于3.06 kg/m3 时便无法抑制电池模组的热失控传播;全氟己酮可抑制锂离子电池模组燃爆后的环境温度,并降低温升速率,最低可降低至-22.3℃/s,且可对电池燃爆后的压力峰值起到抑制作用;效果最好的电池模组首次燃爆与第二次燃爆的压力峰值差为0.04 MPa.
Experimental Study on the Suppression Effect of Different Explosion Suppressant on Thermal Runaway of Lithium-ion Batteries
In order to explore the suppression effect of different explosion suppressants on the thermal runaway of lithium-ion batteries,HFC-227ea and PERFLUORO were used as explosion suppressants to carry out the test of extinguishing and inhib-iting the 18650 ternary lithium-ion battery fires.The test results show that HFC-227ea and PERFLUORO can inhibit the lith-ium-ion battery fire blast,reduce the fire blast temperature,weaken the fire blast effect,and inhibit the thermal runaway propagation;that the capacity to inhibit the propagation of the thermal runaway of the lithium-ion battery module by PER-FLUORO is better than HFC-227ea,and when the mass volume concentration of the HFC-227ea explosion suppression a-gent is lower than 3.06 kg/m3,the thermal runaway propagation of the battery module cannot be inhibited;that PERFLUO-RO can inhibit the ambient temperature after the lithium-ion battery module fire blast happens,and reduce the temperature rate of the temperature rise,decrease the ambient temperature to-22.3℃/s,and play an inhibitory role to the pressure peak after the battery fire blast happens;and that the peak pressure difference between the first fire blast and the second fire blast of the battery module is 0.04 MPa at the best of scenario.

lithium-ion batterythermal runawayHFC-227eaPERFLUOROthermal abuseexplosion suppression effect

赵天成、余思瀚

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武汉理工大学安全科学与应急管理学院,湖北 武汉 430070

锂离子电池 热失控 七氟丙烷 全氟己酮 热滥用 抑爆效果

火灾科学国家重点实验室开放课题

HZ2022-KF08

2024

安全
北京市劳动保护科学研究所 中国职业安全健康协会

安全

影响因子:0.186
ISSN:1002-3631
年,卷(期):2024.45(9)
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