首页|壳聚糖改性生物炭对海南酸性红壤的改良试验研究

壳聚糖改性生物炭对海南酸性红壤的改良试验研究

扫码查看
针对海南酸性红壤结构退化、地力贫瘠以及利用大量农业废弃物制备生物炭用于改良土壤的问题,通过盆栽试验筛选了适宜海南酸性红壤的改良剂.为了提高生物炭的性能,采用壳聚糖(Chitosan,C)对稻壳(Rice husk biochar,BR)、玉米芯(Corncob biochar,BC)、甘蔗渣(Sugarcane biochar,BS)、香蕉假茎(Banana pseudostem biochar,BB)4 种生物炭进行改性,并分析不同生物炭和壳聚糖改性生物炭对土壤理化性质的改良效果.扫描电镜(SEM)、傅里叶红外光谱(FT-IR)等表征结果显示:壳聚糖改性后引入了新官能团,但壳聚糖颗粒造成了生物炭孔隙结构堵塞,致使材料比表面积减少;添加改性生物炭可使土壤pH值提升0.61~2.28,铵态氮质量浓度提升10%~43%,有效磷质量浓度提升8%~34%,速效钾质量浓度提升17%~77%,阳离子交换量(Cation Exchange Capacity,CEC)提升 26%~89%,有机质质量比提升26%~107%,蔗糖酶(Sucrase,SUC)酶活性提升 5%~34%,脲酶(Urease,URE)酶活性提升 7%~58%.其中BB-C对土壤pH值、铵态氮质量浓度和脲酶酶活性提升效果显著,BB对土壤有效磷质量浓度、CEC和有机质质量比改良效果显著,BR对土壤速效钾质量浓度改良效果显著,BS-C对土壤蔗糖酶酶活性改良效果显著.对于土壤有效磷质量浓度、速效钾质量浓度、CEC和有机质质量比,生物炭改良效果更好;对于土壤pH值、铵态氮质量浓度、蔗糖酶酶活性、脲酶酶活性,壳聚糖改性生物炭改良效果更好.
Application of different biomass charcoal modified by chitosan to the improvement of acidic red soil in Hainan
The purpose of this paper is to prepare biochar from agricultural wastes to reduce the structural degradation and soil fertility poverty of acid soil in Hainan.The measure we would like to take may include a batch of experiments,a set of control measures without any amendment(CK),rice husk biochar(BR),corncob biochar(BC),bagasse biochar(BS),banana pseudostem biochar(BB),chitosan modified rice husk biochar(BR-C),chitosan modified corncob biochar(BC-C),chitosan modified bagasse biochar(BS-C),chitosan modified banana pseudostem biochar(BB-C).To achieve the predetermined purpose,we evaluated the remediation effect by analyzing the characteristics of biochar and the content soil's physical and chemical properties,to select the modifiers suitable for acidic soil.Scanning electron microscope and Fourier transform infrared spectroscopy showed that new functional groups were introduced after chitosan modification,but chitosan particles also blocked the pore structure of biochar and reduced the specific surface area of the material.On the other hand,the addition of biochar and chitosan-modified biochar.The pH value increased by 0.61-2.28,the content of ammonium nitrogen increased by 10%-43%,the content of available P increased by 8%-34%,the content of available K increased by 17%-77%,the CEC content increased by 26%-89%,the content of organic matter increased by 26%-107%,the content of sucrase increased by 5%-34%,and the content of urease increased by 7%-58%.In addition,BB-C had a significant improvement effect on soil pH,ammonium nitrogen and urease,BB had a significant effect on soil-available phosphorus,CEC,and organic matter.BR had a significant effect on soil-available potassium,and BS-C had a significant effect on soil sucrase.In addition,we also found that the improvement of biochar was greater than that of chitosan-modified biochar in terms of available phosphorus,available potassium,CEC,and organic matter content,while chitosan-modified biochar had better improvement ability in pH,ammonia nitrogen,sucrase,and urease content.Thus,it can be concluded that the results of our finding are in a position to provide a valuable reference for the improvement of chitosan-modified biochar improving the Hainan red-acid soil quality in a way.

environmentalologyHainan areaacid red-soilbiocharchitosan modificationsoil improvement

卢徐节、符帝俊、黄华集、王浩天、陈安琦、齐丹

展开 >

海南热带海洋学院崖州湾创新研究院,海南三亚 572022

海南省近岸海洋生态环境过程与碳汇重点实验室,海南三亚 572022

环境学 海南 酸性红壤 生物炭 壳聚糖改性 土壤改良

三亚市农业科技创新项目

2019NK04

2024

安全与环境学报
北京理工大学 中国环境科学学会 中国职业安全健康协会

安全与环境学报

CSTPCD北大核心
影响因子:0.943
ISSN:1009-6094
年,卷(期):2024.24(1)
  • 41