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低压环境下RP-3航空煤油自燃特性研究

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开展了低压环境下RP-3航空煤油的自燃特性研究,测试了 101 kPa、80 kPa、60 kPa、40 kPa、20 kPa 五种压力环境下航空煤油自燃点及着火延迟时间数据.结果表明,随着环境压力降低,自燃点升高,并基于谢苗诺夫热自燃理论,建立了耦合压力参数的自燃点预测模型.分析了环境压力对着火延迟时间的影响机制,建立了不同环境压力下的着火延迟时间预测模型.分析了 GB/T 5332-2007标准在低压环境下测试存在的问题,并提出了相关改进方法.
Auto-ignition characteristics of RP-3 kerosene under low pressure
In this paper,the auto-ignition characteristics of RP-3 aviation kerosene under a low-pressure environment are studied.According to the GB/T 5332-2007 standard,an auto-ignition point test instrument under a low-pressure environment is designed and built,and the criterion of auto-ignition,and delay time data are determined.The auto-ignition point and ignition delay time of aviation kerosene are tested under five pressure environments of 101 kPa,80 kPa,60 kPa,40 kPa,and 20 kPa.The test results show that the auto-ignition point increases with the decrease of ambient pressure.The auto-ignition point will exceed 923 K on the condition that the ambient pressure is reduced below 20 kPa,which exceeds the temperature range of the instrument.Based on combustion chemical reaction theory,the ignition process of fuel vapor is revealed,and the critical condition of auto-ignition is determined.A prediction model of auto-ignition point under low pressure is established,which agrees well with the experimental data.The influence mechanism of ambient pressure on ignition delay time is analyzed,and it is found that the ignition delay time and ambient 1/T show a linear relationship.A prediction model of ignition delay time under various ambient pressures is established,which also agrees well with the experimental data.The combustion chemical reaction of RP-3 aviation kerosene with air is analyzed,and the equivalent ratio of the combustion reaction is obtained.The actual fuel-air ratio in the experiment in this paper is calculated.Compared with the equivalent ratio,it's shown that the fuel-air ratio is higher than the equivalent ratio.Other influence factors for auto-ignition characteristics are analyzed,and it is found that the reaction container volume,wall reaction,and reactant concentration have a significant influence on the auto-ignition of liquid.The problems of GB/T 5332-2007 standard method in low-pressure condition test is analyzed,the main problem is that the vapor concentration is hard to precisely determined,and some improvement methods were put forward.

safety engineeringRP-3 aviation kerosenelow-pressure environmentauto-ignition pointignition delay time

张沛、王学辉、王娟、王丹、汪箭

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航空工业第一飞机设计研究院机电系统研究所,西安 710089

中国科学技术大学火灾科学国家重点试验室,合肥 230026

安全工程 RP-3航空煤油 低压环境 自燃点 着火延迟时间

国家科技重大专项

J2019-Ⅷ-0010-0171

2024

安全与环境学报
北京理工大学 中国环境科学学会 中国职业安全健康协会

安全与环境学报

CSTPCD北大核心
影响因子:0.943
ISSN:1009-6094
年,卷(期):2024.24(2)
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