首页|超临界二氧化碳泄漏减压模型构建及泄漏量分析

超临界二氧化碳泄漏减压模型构建及泄漏量分析

扫码查看
为了解决超临界二氧化碳管道泄漏风险评估问题,基于工业规模超临界二氧化碳小孔泄漏试验结果,提出分别构建超临界泄漏阶段、气液两相泄漏阶段、气相泄漏阶段的理论模型,并通过确定各阶段的传递参数,实现二氧化碳减压过程的理论建模。采用MATLAB软件编制了模型求解程序。通过试验数据验证了理论模型的可靠性。基于理论模型计算结果定量探讨了初始压力、初始温度和泄漏口径对泄漏减压过程压力及质量流量的影响。结果表明:初始压力在8~9。5 MPa变化时,对减压过程压力及泄漏质量流量影响较小;初始温度在33-39℃变化时,压力降至临界值的时间逐渐增加;泄漏口径减小,压降时间显著变长;在泄漏减压初期,泄漏质量流量均出现波动,随后随压力降低而逐渐降低。构建的理论模型能够实现超临界二氧化碳泄漏质量流量预测。
Construction of decompression model and analysis of leakage flow rate of supercritical carbon dioxide in pipelines
By using an industrial scale pipeline of DN250 in nominal diameter and 260 m in length,the supercritical carbon dioxide leakage tests in small holes were performed.The phase change process in the pipeline during supercritical carbon dioxide leakage was discovered,including supercritical phase carbon dioxide release,gas-liquid two-phase carbon dioxide release,and gas phase carbon dioxide release successively.Based on the results,a method for establishing carbon dioxide leakage theoretical models was raised by setting up the supercritical phase leakage model,the gas-liquid phases leakage model,and the gas phase leakage model respectively.The transferring parameters of different carbon dioxide phase leakage models were determined.The theoretical model of the carbon dioxide decompression process was realized.The calculation flow chart of every leakage phase model was set up.A calculation program was compiled by using MATLAB software to solve the theoretical model.The reliability of the model is verified by comparing the calculated pressure drop curve with the experimental data obtained in industrial-scale pipelines.Based on the theoretical calculation results,the influences of the initial pressure,initial temperature,and leakage diameter on the leakage mass flow rate were discussed.Results show that the biggest deviation between the pressure curves of theoretical calculation and the experimental test is about 22.8%.When the initial pressure varies from 8 MPa to 9.5 MPa,the influences of initial pressure on pressure drop and mass flow rate are small.When the initial temperature varies from 33 ℃ to 39 ℃,the time of pressure decreasing down to the critical value gradually increases.The pressure decreasing time obviously larges with the decrease of leakage diameter.The leakage mass flow rate fluctuates at the initial decompression stage,then decreases with the pressure decreasing.Results can provide a reference for understanding the decompression mechanism of supercritical carbon dioxide and pipeline leakage risk.

safety engineeringsupercritical carbon dioxidepipelineleakage decompressiontheoretical modelleakage flow rate

辛保泉、曹琦、党文义、于帅、喻健良、闫兴清

展开 >

中石化安全工程研究院有限公司,化学品安全全国重点实验室,山东青岛 266071

中石化国家石化项目风险评估技术中心有限公司,山东青岛 266071

大连理工大学化工学院,辽宁大连 116024

安全工程 超临界二氧化碳 管道 泄漏减压 理论模型 泄漏流量

化学品安全全国重点实验室开放课题

36550000-22-ZC0613-0192

2024

安全与环境学报
北京理工大学 中国环境科学学会 中国职业安全健康协会

安全与环境学报

CSTPCD北大核心
影响因子:0.943
ISSN:1009-6094
年,卷(期):2024.24(3)
  • 21