首页|交直流混合干扰下涂层破损X70钢腐蚀特性研究

交直流混合干扰下涂层破损X70钢腐蚀特性研究

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油气管道经过电气化铁路和高压输电线路易出现交直流混合干扰腐蚀现象。针对目前交直流混合干扰下涂层破损管道的腐蚀行为研究尚不充分的情况,采用失重、电化学试验,并结合光学显微镜、激光光谱共聚焦显微镜、X射线衍射(X-Ray Diffraction,XRD)等检测手段,开展了微小涂层破损X70钢在交直流混合干扰下的腐蚀特性研究。结果表明:(1)相同电流密度下试样最大腐蚀坑深度由深到浅排序为:涂层破损直径D=5 mm试样、D=2 mm试样、D=1 mm试样、无涂层试样;(2)存在临界电流密度,当i<120 A/m2时,随电流密度的增加最大腐蚀坑深度缓慢增加,当i≥120 A/m2时,随电流密度的增加最大腐蚀坑深度急剧增加;(3)当i=180 A/m2时,D=5 mm试样腐蚀深度达1 883。18 μm,涂层破损直径由原来5 mm扩展到7 mm。
Research on the corrosion characteristics of X70 steel with coating damage under mixed Alternating Current(AC)and Direct Current(DC)interference
Given the insufficient research on the corrosion behavior of coating damaged pipelines under mixed Alternating Current(AC)and Direct Current(DC)interference,the corrosion characterization of X70 steel with tiny coating damage under mixed AC and DC interference was carried out using weightlessness and electrochemical experiments,combined with optical microscopy,laser spectroscopic confocal microscopy,XRD,and other inspection methods.The results show that:(1)the corrosion morphology of the damaged coating specimens under mixed AC and DC interference is mainly pitting corrosion,and the maximum depth of the corrosion pits increases with the increase of AC and DC density.The larger the diameter of the coating damage is,the deeper the maximum depth of the corrosion pit is.(2)When i=180 A/m2,the larger the diameter of coating damage,the more serious the local corrosion of the coating damage area is.The corrosion depth of the damaged coating 5 mm specimen reaches 1883.18 μm and the diameter of the damaged coating extends from the original 5 mm to 7 mm in diameter.(3)The mixed AC and DC interference causes more severe corrosion on the oil and gas pipelines with coating damage,and the maximum corrosion pit depth of the uncoated specimens is much lower than that of the coating-damaged specimens at the same mixed AC and DC density.(4)Different mixed AC and DC densities may destroy the integrity of the corrosion product film.There is a critical current density of 120 A/m2.When i<120 A/m2,with the increase in current density,the maximum depth of corrosion pits slowly increases;when i≥120 A/m2,with the increase in current density,the maximum depth of corrosion pits increases dramatically.the growth decreases with increasing the area of the coating damage.(5)AC and DC are not simple superposition effects;with the increase of mixed AC and DC density,the oscillating effect of AC is strengthened,which promotes the generation of pitting corrosion.Besides,The increase in DC density intensifies corrosion.

safety engineeringcorrosionmixed alternating current and direct current interferenceburied pipelinescoating damage

贺三、余锐、李彬、杜铭轩、唐凯、韩雨

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西南石油大学石油与天然气工程学院,成都 610500

中国石化胜利油田分公司现河采油厂,山东东营 257068

中国石化西北油田分公司油气运销部,新疆轮台 841600

安全工程 腐蚀 交直流混合干扰 埋地管道 涂层破损

2024

安全与环境学报
北京理工大学 中国环境科学学会 中国职业安全健康协会

安全与环境学报

CSTPCD北大核心
影响因子:0.943
ISSN:1009-6094
年,卷(期):2024.24(12)