首页|淮河(淮南至蚌埠段)沉积物柱芯中多溴联苯醚的污染特征及生态风险评价

淮河(淮南至蚌埠段)沉积物柱芯中多溴联苯醚的污染特征及生态风险评价

扫码查看
采用210Pb同位素定年法、运用GC-MS气质联用仪分别对沉积物柱芯年龄及多溴联苯醚(PBDEs)含量进行测定,利用风险熵值法对采样点进行生态风险评价.结果表明:商业十溴二苯醚(Deca-BDE)、八溴二苯醚(Octa-BDE)和五溴二苯醚(Penta-BDE)产品以及溴化程度较高的溴二苯醚化合物的脱溴可能是淮河中多溴二苯醚的来源.BDE-47在沉积物柱芯中的普遍存在归因于该地区广泛使用溴化70-5二苯醚(Bromkal 70-5DE)和五溴联苯醚(Bramkal DE-71).沉积物中的还原脱溴作用,使得BDE-28普遍存在.多溴二苯醚自二十世纪八十年代以来大量的商业使用,可能造成三个采样地区的多溴二苯醚浓度急剧增加.三个采样点各时间段绝大部分风险熵值小于0.01,生态风险较小.
Pollution Characteristics and Ecological Risk Assessment of Polybrominated Diphenyl Ethers Between Huainan and Bengbu Section of the Huaihe River
The age of the sediment core was determined by using the 210 Pb isotope dating method,and the content of polybrominated diphenyl ethers ( PBDEs) was analyzed by using GC-MS.The ecological risk assessment of the sampling points was conducted by using the risk entropy method.The results indicated that commercial Deca-BDE,Octa-BDE,Penta-BDE products,and debromination of higher degree bromo-diphenyl ether compounds may serve as sources for polybrominated diphenyl ethers in the Huaihe River.The prevalence of BDE-47 in the sediment cores can be attributed to widespread usage of Bromkal 70-5 diphenyl ether (Bromkal 70-5DE) and Bramkal DE-71 in this region.Reduction debromination within the sediments resulted in a higher occurrence of BDE-28.Since the 1980s,extensive commercial use of poly-brominated diphenyl ethers has led to a significant increase in their concentration across all three sampling areas.Most time periods exhibited a low ecological risk with a risk entropy value below 0.01.

Huaihe River( Anhui section)sedimentpolybrominated diphenyl ethersecological risk assessment

周亚磊、陈志远、程晋静、笪春年

展开 >

合肥大学 生物食品与环境学院,安徽 合肥 230601

淮河(安徽段) 沉积物 多溴联苯醚 生态风险评价

国家自然科学基金安徽省自然科学基金项目

417730992008085MD119

2024

蚌埠学院学报
蚌埠学院

蚌埠学院学报

影响因子:0.231
ISSN:2095-297X
年,卷(期):2024.13(2)
  • 31