首页|Ta/Ta2O5/Cu结构制备及应用性能研究

Ta/Ta2O5/Cu结构制备及应用性能研究

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介绍了以Ta/Ta2O5/Cu为结构的平板MIM电容器的制备方法和性能测试,探究金属Cu直接作为钽电解电容器阴极层的可行性.通过阳极氧化法在钽箔表面制备非晶态的Ta2O5薄膜,以化学镀铜、磁控溅射镀铜两种镀铜工艺制备Ta/Ta2O5/Cu结构,并对所得结构进行结构表征和性能测试.实验结果表明:不同镀铜方式制备的Ta/Ta2O5/Cu结构在电学性能测试过程中都没有表现出电容特性,正负极之间的电阻仅有0.7Ω;以金属Cu直接作为钽电容器的阴极层会导致金属铜在测试过程中被氧化成铜离子从而进入Ta2O5介质层中,进而导致Ta2O5的击穿,因此金属铜不适合直接作为钽电容的阴极层.
Fabrication and Performance of Flat MIM Capacitors with Ta/Ta2O5/Cu Structure
This study explored the feasibility of employing metallic copper(Cu)as the cathode layer in tantalum electrolytic capacitors.The focus was on fabrication methods and performance testing of flat metal-insulator-metal(MIM)capacitors with a Ta/Ta2O5/Cu structure.An amorphous Ta2O5 thin film was deposited on Ta foil surfaces via anodization.Two Cu deposition techniques,namely chemical Cu plating and magnetron sputtering,were utilized to create the Ta/Ta2O5/Cu structures.These structures were subjected to extensive characterization and performance evaluation.The experimental results demonstrate the absence of capacitive characteristics in the Ta/Ta2O5/Cu structures fabricated via different Cu deposition methods during electrical performance testing,the resistance measured between the positive and negative electrodes was only 0.7 Ω.And direct utilization of metallic Cu as the cathode layer in Ta capacitors leads to the oxidation of Cu into copper ions during the testing process,subsequently infiltrating the Ta2O5 dielectric layer and causing the breakdown of Ta2O5.Thus,it can be concluded that metallic Cu is unsuitable as a direct cathode layer in Ta capacitors.

pentoxide tantalumMIM capacitoranodic oxidationelectroless copper platingmagnetron sputtering copper plating

梁桃华、雍欢、季静欣、杨仕清、王焱

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四川省热电材料与器件应用工程研究中心,成都 610041

成都职业技术学院,成都 610041

电子科技大学材料与能源学院,成都 610054

五氧化二钽 MIM电容器 阳极氧化 化学镀铜 磁控溅射镀铜

国家自然科学基金四川省自然科学基金四川省科技厅应用基础研究项目

623711032023NSFSC041019YYJC0624

2024

半导体光电
中国电子科技集团公司第四十四研究所

半导体光电

CSTPCD北大核心
影响因子:0.362
ISSN:1001-5868
年,卷(期):2024.45(2)
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