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高铁酸钾强化剩余污泥厌氧发酵产挥发性脂肪酸研究

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针对剩余污泥(ES)厌氧发酵产挥发性脂肪酸(VFA)效率低的现状,开展了高铁酸钾(PF)强化ES厌氧发酵产VFA的探究,并分析了PF强化ES厌氧发酵的作用机制.研究结果表明,适量提高PF浓度利于VFA的积累,且当PF含量为5%时,VFA最大产量为251.6 mg/g VSS,约为对照组的2.45 倍.PF提高了ES内有机质释放,且溶解性COD(SCOD)最大为1 856 mg/L.PF促进了ES内溶解性蛋白质和多糖浓度,利于后续酸化过程.高浓度PF降低了ES发酵内沼气积累,减少了VFA的消耗.酶学分析表明PF促进了与水解和酸化过程相关酶的活性,但降低了产甲烷过程相关酶的活性.研究结果为ES厌氧发酵积累VFA提供了一种备选方案.
Potassium Ferrate Enhanced Anaerobic Fermentation of Excess Sludge to Produce Volatile Fatty Acids
In view of the low efficiency of volatile fatty acid production by excess sludge(ES)anaerobic fermentation,this sutdy ana-lyzed the method to produce VFA potassium ferrate(PF)by enhanced ES anaerobic fermentation.The mechanism of PF enhanced ES an-aerobic fermentation was analyzed.The results showed that increasing the concentration of PF was beneficial to the accumulation of VFA,and when the content of PF was 5%,the maximum yield of VFA was 251.6 mg/g VSS,which was about2.45 times that in the control.PF increased the release of organic matter from ES,and the maximum soluble COD(SCOD)was 1856 mg/L.PF promoted the concentra-tion of soluble proteins and polysaccharides in ES,which was beneficial to the subsequent acidification process.High concentration of PF reduced the biogas accumulation in ES fermentation and reduced the consumption of VFA.Enzymatic analysis showed that PF promoted the activity of enzymes related to hydrolysis and acidification,but decreased the activity of enzymes related to methanogenesis.The results provide an alternative for ES anaerobic fermentation to accumulate VFA.

excess sludgeanaerobic fermentationpotassium ferrateVFAhydrolysis

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山东省德州生态环境监测中心,山东 德州 253034

剩余污泥 厌氧发酵 高铁酸钾 VFA 水解

2025

环境科学与管理
黑龙江省环境保护科学研究院

环境科学与管理

影响因子:0.681
ISSN:1673-1212
年,卷(期):2025.50(1)