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白云鄂博矿中稀土镧在高炉炼铁过程的传承机理

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文章以稀土镧为对象,研究了白云鄂博矿中稀土元素镧在高炉炼铁过程的传承机理.通过热力学计算和实验表征分析了高炉炼铁过程中镧元素在渣-铁之间的微观行为.结果表明,高炉渣中的La2O3在高炉炼铁过程中可以被还原成LaC2,随后LaC2溶于铁水中且镧被多孔状石墨上的含氧官能团吸附,从而使稀土能够传承到后续的炼钢工艺过程中.弥补了传统观点认为的高炉渣中稀土氧化物在高炉炼铁时很难被还原,无法继续往后续流程传承的问题.
Inheritance Mechanism of Rare Earth Lanthanum in Baiyuneboite during Process of Blast Furnace Ironmaking
The inheritance mechanism of rare earth element lanthanum in baiyuneboite during process of blast furnace ironmaking is studied by taking rare earth lanthanum as the object. The microscopic behaviors of lanthanum from slags to i-ron during process of blast furnace ironmaking are analyzed by thermodynamic calculations and experimental characteriza-tion. The results indicated that La2O3 in blast furnace slags could be reduced to LaC2 during process of blast furnace iron-making,and then LaC2 is dissolved in molten iron and La is adsorbed by the oxygen functional groups on porous graphite so that the rare earth could be inherited to subsequent steelmaking processes,which makes up for the problem in traditional view that the rare earth oxides in blast furnace slags are difficult to be reduced during process of blast furnace ironmaking and cannot be inherited to subsequent processes.

baiyuneboiterare earth elementblast furnace ironmakinginheritance mechanism

瞿伟、任慧平、智建国、董方、宋海、麻晓光

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内蒙古科技大学,内蒙古 包头 014010

内蒙古包钢钢联股份有限公司,内蒙古 包头 014010

内蒙古包钢钢联股份有限公司炼钢厂,内蒙古 包头 014010

内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010

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白云鄂博矿 稀土元素 高炉炼铁 传承机理

2024

包钢科技
内蒙古包钢钢联股份有限公司技术中心

包钢科技

影响因子:0.115
ISSN:1009-5438
年,卷(期):2024.50(4)
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