首页|稀土Ce对BT700L钢中TiN夹杂物形成的热力学分析

稀土Ce对BT700L钢中TiN夹杂物形成的热力学分析

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汽车大梁钢主要用作重卡汽车底盘上的纵梁、衬梁、横梁等结构件,钢的综合性能对整车的行驶安全和使用寿命至关重要.大尺寸的TiN夹杂物严重危害BT700L钢的加工和使用性能,而稀土能够改善钢中夹杂物数量、形态,提高钢的低温冲击、耐腐蚀性能等.文章基于工业试验和热力学计算,研究了稀土Ce对BT700L钢中TiN夹杂物形成的影响.研究结果表明,不加Ce的BT700L钢中形成的主要是纯TiN夹杂物和复合Al-O+TiN夹杂物,而加Ce后BT700L钢中形成的主要是纯TiN夹杂物和复合Ce-Al-O(-S-Ca)+TiN夹杂物.热力学计算结果表明BT700L钢中随Ce含量增加,TiN夹杂物的析出温度会降低,从而抑制了TiN夹杂物的析出.可采取降低钢中氮和钛含量、增大凝固速率等方式降低TiN夹杂物的尺寸.
Thermodynamic Analysis of Rare Earth Ce on Formation of TiN Inclusions in BT700L Steel
The automobile beam steel is mainly used for such structural components as longitudinal beam,lining beam and cross beam on the chassis of heavy truck,so its comprehensive performances are vital to the driving safety and service life of the whole vehicle. The TiN inclusions with large size seriously harm the processability and usability of BT700L steel,while the amount and morphology of inclusions in steel as well as low-temperature impact and corrosion resistance of steel could be improved by rare earth. In the paper,the effects of rare earth Ce on formation of TiN inclusions in BT700L steel are studied based on the industrial tests and thermodynamic calculations. The study results showed that pure TiN inclusions and composite inclusions of Al-O+TiN were mainly formed in the BT700L steel without Ce,while pure TiN inclusions and composite inclusions of Ce-Al-O(-S-Ca)+TiN were mainly formed in the BT700L steel with Ce. The results of thermodynamic calculations showed that precipitation temperature of TiN inclusions could be decreased with the increase of Ce content in BT700L steel so that the precipitation of TiN inclusions was restrained. Such methods as reducing contents of nitrogen and titanium in steel as well as increasing solidification rate could be taken to decrease the sizes of TiN inclusions.

BT700L steelrare earth CeTiNinclusions

史超、刘锦文

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内蒙古科技大学稀土产业学院,内蒙古 包头 014010

内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010

北京科技大学冶金与生态工程学院,北京 100083

BT700L钢 稀土Ce TiN 夹杂物

2024

包钢科技
内蒙古包钢钢联股份有限公司技术中心

包钢科技

影响因子:0.115
ISSN:1009-5438
年,卷(期):2024.50(4)
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