包钢科技2024,Vol.50Issue(5) :82-88.

镧铈混合稀土和开轧温度对HRB400E钢组织及耐蚀性的影响

Effects of Lanthanum-cerium Mischmetal and Rolling-start-temperature on Microstructure and Corrosion Resistance of HRB400E Steel

陆斌 黄飞 李晶
包钢科技2024,Vol.50Issue(5) :82-88.

镧铈混合稀土和开轧温度对HRB400E钢组织及耐蚀性的影响

Effects of Lanthanum-cerium Mischmetal and Rolling-start-temperature on Microstructure and Corrosion Resistance of HRB400E Steel

陆斌 1黄飞 2李晶2
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作者信息

  • 1. 内蒙古包钢钢联股份有限公司技术中心,内蒙古 包头 014010;北京包钢钢铁技术有限公司,北京 100083
  • 2. 北京科技大学绿色低碳钢铁冶金全国重点试验室,北京 100083
  • 折叠

摘要

为了改善HRB400E钢的耐蚀性能,在精炼过程向钢中加入镧铈混合稀土合金,控制开轧温度对试验钢进行轧制.采用扫描电镜、能谱仪和光学金相显微镜对夹杂物和显微组织进行表征,结合中性盐雾腐蚀试验,分析稀土和开轧温度对试验钢耐蚀性的影响.结果表明,经镧铈混合稀土处理后,Mn-Si-O 夹杂物被完全转变为(Ce,La)2O3和(Ce,La)2O2S,部分Mn和S在其周围形核生成稀土复合夹杂物,仍有少量单独MnS析出.在试验条件下,开轧温度为900℃、混合稀土含量为0.011 6%的2#试验钢腐蚀速率为1.577 g/(m2·h),耐蚀性能最佳.

Abstract

In order to improve the corrosion resistance of HRB400E steel,test steel is rolled by adding lanthanum-cerium mischmetal into it in refining process and controlling rolling-start-temperature.The inclusions and microstructure are characterized with scanning electron microscope,energy dispersive spectrometer and optical metallographic microscope as well as the effects of rare earth and rolling-start-temperature on corrosion resistance of test steel are analyzed combi-ning with neutral salt spray test.The results showed that the Mn-Si-O inclusions were completely transformed into(Ce,La)2O3 and(Ce,La)2O2S after treatment with lanthanum-cerium mischmetal as well as part of Mn and S were nucleated around them to form complex inclusions of rare earth,but a small amount of individual MnS inclusion was still precipitated.Under the experimental conditions,the corrosion resistance of 2#test steel is optimal when rolling-start-temperature is 900℃,content of mischmetal is0.011 6%and corrosion rate is1.577 g/(m2·h).

关键词

镧铈混合稀土/开轧温度/HRB400E钢/夹杂物/显微组织/耐蚀性能

Key words

lanthanum-cerium mischmetal/rolling-start-temperature/HRB400E steel/inclusions/microstruc-ture/corrosion resistance

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出版年

2024
包钢科技
内蒙古包钢钢联股份有限公司技术中心

包钢科技

影响因子:0.115
ISSN:1009-5438
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