Abstract
In order to improve the energy output consistency of 3,3'-diamino-4,4'-azoxyfurazan(DAAF)in the new insensitive booster and the safety and efficiency in the preparation process,a continuous preparation system of DAAF from synthesis to spherical coating was designed and established in this paper,which combined ultrasonic micromixing reaction with microdroplet globular template.In the rapid micro-mixing stage,the microfluidic mixing technology with ultrasonic was used to synergistically strengthen the uniform and rapid mass transfer mixing reaction between raw materials to ensure the uniformity of DAAF particle nucleation-growth,and to prepare high-quality DAAF crystals with uniform structure and morphology and concentrated particle size distribution.In the microdroplet globular template stage,the microfluidic droplet technology was used to form a droplet globular template with uniform size under the shear action of the continuous phase of the dispersed phase solution containing DAAF particles and binder.The size of the droplet template was controlled by adjusting the flow rate ratio between the continuous phase and the dispersed phase.In the droplet globular template,with the diffusion of the solvent in the dispersed phase droplets,the binder precipitates to coat the DAAF into a ball,forming a DAAF microsphere with high sphericity,narrow particle size distribution and good monodispersity.The problem of discontinuity and DAAF particle suspension in the process was solved,and the coating theory under this process was studied.DAAF was coated with different binder formulations of fluororubber(F2604),nitrocellulose(NC)and NC/glycidyl azide polymer(GAP),and the process verification and eval-uation of the system were carried out.The balling effects of large,medium and small droplet templates under different binder formulations were studied.The scanning electron microscope(SEM)results show that the three droplet templates under the three binder formulations exhibit good balling effect and narrow particle size distribution.The DAAF microspheres were characterized by powder X-ray diffraction(XRD),differential scanning calorimetry(DSC),thermo-gravimetric(TG)and sensitivity analyzer.The results showed that the crystal structure of DAAF did not change during the process,and the prepared DAAF microspheres had lower decomposition temperature and lower mechanical sensitivity than raw DAAF.The results of detonation parameters show that the coating of DAAF by using the above three binder formulations will not greatly reduce the energy output of DAAF,and has comparable detonation performance to raw DAAF.This study proves an efficient and safe continuous system from synthesis to spherical coating modification of explosives,which provides a new way for the continuous,safe and efficient preparation of spherical explosives.
基金项目
National Natural Science Foundation of China(22005275)
维普
万方数据