防务技术2024,Vol.32Issue(2) :675-690.DOI:10.1016/j.dt.2023.11.018

Mussel-inspired PTW@PDA composites for developing high-energy gun propellants with reduced erosion and enhanced mechanical strength

Xijin Wang Zhitao Liu Pengfei Sun Feiyun Chen Bin Xu Xin Liao
防务技术2024,Vol.32Issue(2) :675-690.DOI:10.1016/j.dt.2023.11.018

Mussel-inspired PTW@PDA composites for developing high-energy gun propellants with reduced erosion and enhanced mechanical strength

Xijin Wang 1Zhitao Liu 1Pengfei Sun 2Feiyun Chen 1Bin Xu 1Xin Liao1
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作者信息

  • 1. School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,Jiangsu,China
  • 2. China North Industries Group Corporation Limited,Beijing 100045,China
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Abstract

The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K2Ti6O13),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing fillers.The interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW materials.Compared to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-K-based protective coating being detected on the eroded steel.And 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of propellants.Despite the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic activity.This strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.

Key words

High energy gun propellant/Potassium titanate whiskers/Polydopamine modification/Erosion inhibitors/Mechanical reinforcing fillers

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基金项目

instrument and equipment fund of the Key Laboratory of Special Energy,Ministry of Education,Nanjing University of Science an()

出版年

2024
防务技术
中国兵工学会

防务技术

CSTPCD
影响因子:0.358
ISSN:2214-9147
参考文献量59
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