兵工学报2024,Vol.45Issue(5) :1547-1554.DOI:10.12382/bgxb.2022.1042

碳纳米管对酚醛树脂基复合材料性能的影响

Effect of Carbon Nanotubes on Properties of Phenolic Resin Matrix Composites

孔国强 安振河 赵寰 于秋兵 邵蒙 李莹 魏化震 王康 刘文博
兵工学报2024,Vol.45Issue(5) :1547-1554.DOI:10.12382/bgxb.2022.1042

碳纳米管对酚醛树脂基复合材料性能的影响

Effect of Carbon Nanotubes on Properties of Phenolic Resin Matrix Composites

孔国强 1安振河 1赵寰 2于秋兵 1邵蒙 1李莹 1魏化震 1王康 1刘文博1
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作者信息

  • 1. 山东非金属材料研究所,山东 济南250031
  • 2. 某军事代表局驻某地区军事代表室,山东 济南250031
  • 折叠

摘要

为制备具有隔热、耐烧蚀、电磁屏蔽等多功能集成的结构复合材料,满足武器装备对多功能复合材料的迫切需求,采用超声波分散的工艺将碳纳米管(Carbon Nanotubes,CNTs)在树脂基体中进行分散,并制备CNTs改性国产碳布/酚醛复合材料.经对CNTs改性国产碳布/酚醛复合材料的层间性能检测,当CNTs含量达到1.5%时,其层间剪切强度提高57.4%.对CNTs改性定向国产碳纤维/酚醛树脂复合材料的弯曲性能、层间性能和抗冲击性能都进行检测.检测结果表明,经CNTs改性后,定向国产碳纤维/酚醛复合材料的力学性能和模量均得到了大幅提高.对CNTs改性短切高强玻璃纤维/酚醛树脂基复合材料的导电性能和导热性能进行了研究.研究结果表明:随着CNTs含量的提高,短切高强玻璃纤维/酚醛树脂基复合材料的电阻率呈数量级速度降低,当CNTs含量达到14%时,复合材料的电阻率由1010Ω·m降低到了10-2Ω·m,复合材料由绝缘体转变为导体;当CNTs含量小于6%时,复合材料的导热系数虽有提高,但与复合材料电性能相比提高幅度不大.

Abstract

A multifunctional integrated structural composite material with heat insulation, erosion resistance, electromagnetic shielding, etc. , is prepared to meet the urgent demand for multifunctional composite materials in weapons and equipment. In this paper, the carbon nanotubes are dispersed in the resin matrix by ultrasonic dispersion process, and the domestic carbon cloth/phenolic composites modified by carbon nanotubes are prepared. The interlaminar shear strength of domestic carbon cloth/phenolic composites modified by carbon nanotubes is increased by 57. 4% when the content of carbon nanotubes reaches 1. 5%. The bending properties, interlaminar properties and impact resistance of the oriented domestic carbon fiber/phenolic resin composites modified by carbon nanotubes were tested. The test results show that the mechanical properties and modulus of the oriented domestic carbon fiber/phenolic resin composites are significantly improved after the modification of carbon nanotubes. The electrical conductivity and thermal conductivity of carbon nanotube-modified chopped high-strength glass fiber/phenolic resin matrix composites are also studied. The results show that the resistivity of chopped high-strength glass fiber/phenolic resin matrix composites is decreaseed by an order of magnitude with the increase of carbon nanotube content. When the content of carbon nanotubes reaches 14%, the resistivity of the composites decreases from 1010 Ω·m to 10 -2 Ω·m, and The composites change from insulator to conductor. When the content of carbon nanotubes is less than 6%, the thermal conductivity of the composites is improved, but it is improved modestly compared with the electrical properties of the composites.

关键词

碳纳米管/碳布/酚醛复合材料/碳纤维/酚醛复合材料/导电/隔热

Key words

carbon nanotubes/carbon cloth/phenolic composite/carbon fiber/phenolic composite/electric conduction/heat insulation

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出版年

2024
兵工学报
中国兵工学会

兵工学报

CSTPCD北大核心
影响因子:0.735
ISSN:1000-1093
参考文献量16
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