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石墨烯气凝胶的压缩力学性能研究

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为探究石墨烯气凝胶在防护领域的潜在应用,采用冷冻干燥法并控制冷冻温度变量制备不同的石墨烯气凝胶试样,进行单轴面内压缩力学实验;结合3D数字图像相关技术和扫描电子显微镜,分析变形模式与破坏机理.研究结果表明:冷冻干燥法制备的石墨烯气凝胶试样具有3D多孔网络结构、低密度(<33.93 mg/cm3)、高孔隙率(>98.5%)等特征,并具有受冷冻温度影响的特征微观结构;石墨烯气凝胶的压缩应力-应变曲线展现出多孔材料典型的三阶段特征,并且力学性能受冷冻温度的影响,-80 ℃所得石墨烯气凝胶的杨氏模量相较于-19℃提高160%,单位体积吸能提高67%;石墨烯气凝胶多次循环加载-卸载中随着内部致密区域的扩展,以塑性能为主的吸收总能趋于稳定不变,其状态变化可通过指数衰减模型描述;石墨烯气凝胶的横纵向片层不同的压缩变形形态发展为大规模的类弹簧型紧密折叠模式,使得石墨烯气凝胶表现出回弹性.所得研究成果为石墨烯气凝胶在防护领域的应用提供了理论与实践基础.
Study on Compressive Mechanical Properties of Graphene Aerogel
In order to explore the potential application of graphene aerogel in the field of protection,different graphene aerogel samples are prepared by a freeze-drying method and controlled freezing temperature variable,and the uniaxial in-plane compressive mechanics experiments are carried out.The deformation pattern and failure mechanism are analyzed by using 3D digital image correlation(DIC)technology and scanning electron microscope(SEM).The results show that the graphene aerogel samples prepared by freeze-drying method have the characteristics of three-dimensional porous network structure,low density(<33.93 mg/cm3)and high porosity(>98.5%),and have the characteristic microstructure affected by freezing temperature.The compressive stress-strain curves of graphene aerogel exhibit the typical three-stage characteristics of porous materials,and its mechanical properties are affected by the freezing temperature.The Young's modulus of graphene aerogel obtained at-80aCis increased by 160%compared with that at-19 ℃,and the energy absorption per unit volumeis increased by 67%.With the expansion of internal dense region during multiple cyclic loading-unloading of graphene aerogel samples,the absorption energy dominated by plastic energy tends to be stable and unchanged,and its states can be described by the exponential decay model.The different compression deformation forms of the transverse and longitudinal lamellas of graphene aerogels are developed into large-scale spring-like tight folding form,which made the graphene aerogels show resilience.This study provides a theoretical and practical basis for the application of graphene aerogels in the field of protection.

graphene aerogelcompressive mechanical propertyfreeze-drying methodenergy absorption characteristicsdeformation pattern

曹路晴、乔扬、谢晶、陈鹏万

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北京理工大学爆炸科学与技术重点实验室,北京 100081

爆炸防护与应急处置技术教育部工程研究中心,北京 100081

石墨烯气凝胶 压缩力学性能 冷冻干燥法 吸能特性 变形模式

国家自然科学基金项目国家自然科学基金项目

1200205212072038

2024

兵工学报
中国兵工学会

兵工学报

CSTPCD北大核心
影响因子:0.735
ISSN:1000-1093
年,卷(期):2024.45(7)
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