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湿法纺丝制备拉伸电阻不敏感液态金属导电纤维

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液态金属导电纤维在拉伸、折叠等状态下仍可保持导电性,在智能纺织品领域具有广阔的应用前景.然而,大多数液态金属导电纤维在拉伸状态下导电性能大幅下降.以液态金属(LM)/聚氨酯弹性体(TPU)为芯层材料,TPU为皮层材料,通过同轴湿法纺丝工艺制备拉伸电阻不敏感的液态金属导电纤维,探究液态金属含量及芯层内径对纤维结构和性能的影响.结果表明:液态金属导电纤维具有良好的力学性能,拉伸模量为17.7 MPa,断裂伸长率约为475%,断裂强度约为29.5 MPa.此外,所制备的导电纤维具有明显的皮芯结构,芯层直径越大,液态金属含量越高,拉伸电阻稳定性越好.当芯层直径为0.6 mm,液态金属质量分数为97%时,在0~300%的应变范围内纤维电阻几乎保持不变.
Preparation of Strain-insensitive Liquid Metal Conductive Fibers by Wet Spinning
Liquid metal ( LM) conductive fibers can maintain electrical conductivity in the state of stretching and folding,thus have wide applications in the field of smart textiles.However,the conductivity of LM fibers decreases significantly when stretched.In this paper,strain-insensitive LM conductive fibers were prepared by the coaxial wet spinning method.The conductive fibers were composed of LM/polyurethane elastomer ( TPU) as the core material and TPU as the sheath material.The effects of LM content and core diameter on the fiber structure and properties were investigated.The results show that the LM conductive fibers have good mechanical properties: the tensile modulus is 17.7 MPa,the elongation at break is about 475%,and the breaking strength is about 29.5 MPa.In ad-dition,the prepared conductive fibers have an obvious core-sheath structure.The larger the core layer diameter,the higher the liquid metal content,and the better the tensile resistance stability.With a core diameter of 0.6 mm and LM mass fraction of 97%,the conductive fiber exhibits an almost constant resistance in the strain range of 0-300%.

liquid metalstretchable conductive fiberstrain-insensitivewet spinningwater resistance

侯思彤、许倩、陈彦锟、张秀芹、邝旻翾

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北京服装学院材料设计与工程学院,北京100029

北京服装学院服装材料研究开发与评价北京市重点实验室,北京市纺织纳米纤维工程技术研究中心,北京100029

液态金属 可拉伸导电纤维 拉伸电阻不敏感 湿法纺丝 耐水性

国家重点研发计划苏州宝丽迪功能材料研究院开放课题北京学者项目

2022YFB3805802RCQJ20303

2024

北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
年,卷(期):2024.44(1)
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