北京服装学院学报(自然科学版)2024,Vol.44Issue(1) :28-35.DOI:10.16454/j.cnki.issn.1001-0564.2024.01.004

金属氧/硫化物修饰石墨烯复合纤维及其柔性超级电容器

Metal Oxide/Sulfide Modified Graphene Composite Fibers for Flexible Supercapacitors

李文娜 谢帆钰 杜苑 贾潇雨 李宏伟 张梅
北京服装学院学报(自然科学版)2024,Vol.44Issue(1) :28-35.DOI:10.16454/j.cnki.issn.1001-0564.2024.01.004

金属氧/硫化物修饰石墨烯复合纤维及其柔性超级电容器

Metal Oxide/Sulfide Modified Graphene Composite Fibers for Flexible Supercapacitors

李文娜 1谢帆钰 1杜苑 1贾潇雨 1李宏伟 1张梅1
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作者信息

  • 1. 北京服装学院材料设计与工程学院,服装材料研究开发与评价北京市重点实验室,北京市纺织纳米纤维工程技术研究中心,北京100029
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摘要

纤维型柔性超级电容器由于其高功率密度、长循环寿命、微型化、优异柔韧性等特点,在可穿戴电子产品、智能织物领域备受关注.以氧化石墨烯和片状二硫化钼为混合纺丝液,通过限域水热法组装制备二硫化钼/石墨烯复合纤维,并在纤维表面原位均匀沉积二氧化钌,制备二氧化钌@二硫化钼/石墨烯复合纤维(RuO2@MoS2/GF).采用SEM、TEM、XPS、XRD等测试方法对复合纤维进行结构形貌表征,并组装纤维型超级电容器,评价其在凝胶电解质体系的电化学性能.结果表明:在电流密度为0.2 mA/cm2时,RuO2@MoS2/GF的比电容为685 mF/cm2,同时具有良好的循环稳定性,充放电循环6000次后,比电容保持率80%;通过将纤维型超级电容器串联,实现为电子计时器实际供能,促进石墨烯纤维在智能可穿戴领域的应用.

Abstract

Fiber-based flexible supercapacitors have attracted much attention in the field of wearable electronics and smart fabrics due to their high power density,long cycle life,miniaturizatio,and excellent flexibility.This study prepared molybdenum disulfide/graphene composite fibers by confined hydrothermal method using graphene oxide and flake molybdenum disulfide as mixed spinning solution.And ruthenium dioxide@molybdenum disulfide / gra-phene composite fibers (RuO2@MoS2/GF) were prepared by in-situ uniform deposition of ruthenium dioxide on the surface of the fibers.SEM,TEM,XPS and XRD were used to characterize the structure and morphology of the composite fibers and to assemble fiber-based supercapacitors and evaluate their electrochemical performance in gel electrolyte systems.The results show that the specific capacitance of RuO2@MoS2/GF is 685 mF·cm-2 at a current density of 0.2 mA·cm-2 .At the same time,it has good cycle stability.After 6000 cycles of charge and discharge,the specific capacitance retention rate is 80%.By connecting the fiber-type supercapacitor in series,the electronic timer can promote the application of graphene fiber in the field of intelligent wearable.

关键词

石墨烯纤维/二硫化钼/二氧化钌/柔性超级电容器

Key words

graphene fiber/molybdenum disulfide/ruthenium dioxide/flexible supercapacitor

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基金项目

国家自然科学基金项目(52003010)

北京市自然科学基金面上项目(2232048)

北京服装学院高水平科研项目培育基金(NHFZ20230162)

出版年

2024
北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
参考文献量30
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