首页|丝网印刷制备同心圆型平面柔性电容器及其电化学储能性能研究

丝网印刷制备同心圆型平面柔性电容器及其电化学储能性能研究

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柔性微平面超级电容器(MPSCs)的研究已经取得很大的进展,但由于其能量密度较低,仍然无法满足可穿戴电子设备的应用要求.石墨烯(Graphene)作为电极材料时的高惰性限制了其作为超级电容器电极的活性.通过对Graphene进行60 Coγ射线辐照改性,再将改性后的Graphere与赝电容电极材料过渡金属碳化物(MXene)共混复合,借助丝网印刷方法,在柔性织物基底上制备复合改性电极的同心圆型平面电容器.结果表明:60 Coγ射线辐照Graphene后缺陷增加;比表面积增大,孔隙率增加.与MXene复合后所制备的平面电容器具有较高的面积比电容和能量密度(分别为119 mF/cm2和20µWh/cm2);当平面电容器进行5000次充放电循环时,电容保持率为102%,表现出优异的循环寿命和机械稳定性,在微型柔性电子器件储能设施领域具有潜在应用价值.
Preparation of Concentric Circular Planar Flexible Capacitor by Screen Printing Method and Its Electrochemical Energy Storage Performance
Great progress has been made in the research of flexible micro-plane supercapacitors ( MPSCs) .Howev-er,due to its lowenergy density,it still cannot meet the application requirements of wearable electronic devices.The inertia of Graphene limits its activity as a supercapacitor electrode.Therefore,this paper modified Graphene by 60 Coγ-ray irradiation,then compounded it with the pseudocapacitive electrode material transition metal carbide ( MXene) .With the help of screen printing method,a concentric circular planar capacitor with composite modified electrodes was prepared on a flexible fabric substrate.The results show that,according to Raman,the defects of Graphene modified with 60 Coγ-ray irradiation increase,resulting to the increase of specific surface area and porosi-ty.The planar capacitor prepared after recombination with MXene has a high area specific capacitance and energy density (119 mF/cm2 and 20 µWh/cm2 ) .When the planar capacitor is charged and discharged for 5000 cycles,the capacitance retention rate is 102%,which exhibits excellent cycle life and mechanical stability and has poten-tial applications in the field of micro-flexible electronic devices and energy storage facilities.

MXeneGrapheneplanar supercapacitor60Co γ-ray radiation

张通、关芳兰、张珺赫、李昕

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北京服装学院材料设计与工程学院,北京100029

服装材料研究开发与评价北京市重点实验室,北京100029

MXene 石墨烯 平面电容器 60Coγ辐照

国家级自然科学基金面上项目市属高校分类发展-北京服装学院"服装学"新兴交叉学科平台建设项目

5217300111000024T000003073871

2024

北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
年,卷(期):2024.44(1)
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