北京服装学院学报(自然科学版)2024,Vol.44Issue(1) :74-79,94.DOI:10.16454/j.cnki.issn.1001-0564.2024.01.009

PU@PEG相变材料的结构调控和性能研究

Structural Tuning and Performance Investigation of PU@PEG Phase Change Materials

赵志鹏 李安琪 关晓宇
北京服装学院学报(自然科学版)2024,Vol.44Issue(1) :74-79,94.DOI:10.16454/j.cnki.issn.1001-0564.2024.01.009

PU@PEG相变材料的结构调控和性能研究

Structural Tuning and Performance Investigation of PU@PEG Phase Change Materials

赵志鹏 1李安琪 2关晓宇2
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作者信息

  • 1. 中国纺织规划研究会,北京100020
  • 2. 北京服装学院材料设计与工程学院,北京100029
  • 折叠

摘要

相变材料与纺织材料结合能有效调节人体体温,提高人体穿着舒适性,降低人体对室内空调系统调温的依赖性,从而减少能源消耗.为改进固-固相变材料的性能,研究结合聚氨酯(PU)和聚乙二醇(PEG),利用同轴静电纺丝技术制备皮芯型PU@PEG固-固相变材料.通过控制静电纺丝工艺参数,调控纳米纤维定向排列程度与结晶程度,使相变材料的力学性能增强.定向排列的PU@PEG相变材料相较于随机排列的材料,其弹性模量提升幅度达到38.01%,断裂应力提升幅度达到15.92%,熔融焓提高8.51%,整体上提升了相变材料的储能性能和应用耐久性.

Abstract

Combining phase change materials with textile materials can effectively regulate body temperature,en-hance comfort,and reduce the reliance on air conditioning systems for temperature adjustment,thereby reducing energy consumption.This study prepared a core-shell PU@PEG solid-solid phase change material by using coaxial electrospinning,combining polyurethane ( PU) and polyethylene glycol ( PEG) .By controlling the electrospinning process parameters and adjusting the alignment and crystallinity of nanofibers,the mechanical properties of the phase change material were enhanced.Compared to randomly arranged materials,the oriented PU@PEG phase change material exhibits a significant improvement in elastic modulus ( increased by over 38.01%) ,fracture stress ( increased by over 15.92%) ,and melting enthalpy ( increased by 8.51%) .Overall,this enhancement contrib-utes to improved energy storage performance and application durability of the phase change material.

关键词

纳米纤维/相变材料/智能材料/取向结构

Key words

nanofiber/phase change material/smart material/oriented structure

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基金项目

北京服装学院新进青年教师启动计划(BIFTXJ202220)

北京学者项目(RCQJ20303)

纺织之光应用基础研究计划(J202309)

北京服装学院高水平教师队伍建设专项资金(BIFTGCC202302)

出版年

2024
北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
参考文献量20
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