北京服装学院学报(自然科学版)2024,Vol.44Issue(2) :1-10.DOI:10.16454/j.cnki.issn.1001-0564.2024.02.001

染料改性二氧化钛/石墨烯的制备及其在MB光催化降解中的应用

Preparation of Dye-modified Titanium Dioxide/graphene and Its Application in Photocatalytic Degradation of MB

李科宇 梁苗青 聂锦梅 关芳兰 鲍利红
北京服装学院学报(自然科学版)2024,Vol.44Issue(2) :1-10.DOI:10.16454/j.cnki.issn.1001-0564.2024.02.001

染料改性二氧化钛/石墨烯的制备及其在MB光催化降解中的应用

Preparation of Dye-modified Titanium Dioxide/graphene and Its Application in Photocatalytic Degradation of MB

李科宇 1梁苗青 1聂锦梅 1关芳兰 1鲍利红2
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作者信息

  • 1. 北京服装学院材料设计与工程学院,北京100029
  • 2. 北京服装学院材料设计与工程学院,北京100029;北京市服装材料研发与评价重点实验室,北京100029
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摘要

为了改进石墨烯基粉末光催化剂水分散性差的问题,采用水热法制备了二氧化钛/石墨烯(TG),再以含有多个亲水基团的染料对TG共价接枝,制备出三元复合光催化材料;考察了染料和TG比例及不同染料结构对光催化剂带隙、水分散性的影响以及不同光催化剂对亚甲基蓝(MB)模拟污水的降解性能.结果表明:复合材料DTG系列带隙相对TG均变窄,对光响应范围延伸至可见光区;复合材料D2.70 TG水分散性良好,静置7 d后无明显沉淀聚集;D2.70 TG在可见光照射下2 h,其对于模拟污水中MB的去除率达到99%以上,经过5次光照循环后,去除率仍可达95%以上.

Abstract

To improve the water dispersibility of graphene based powder photocatalyst,titanium dioxide/graphene (TG) was first prepared using a hydrothermal method in this paper,and then the ternary composite photocatalytic materials were prepared by covalently grafting TG with dyes containing hydrophilic groups.The bandgap,water dis-persibility,and photocatalytic degradation performance of methylene blue (MB) simulated wastewater of the photo-catalysts were mainly investigated.The results showed that the bandgaps of the DTG series of composites were nar-rowed compared to that of TG,extending the light response range to the visible light region.The composite D2.70 TG exhibited good water dispersibility,and no significant precipitation aggregation occurred after 7 days of testing.The removal rate of MB in the simulated wastewater by D2.70 TG under the irradiation of visible light for 2 h was over 99%,and the removal rate remained above 95% after 5 cycles of experimentation.

关键词

石墨烯/TiO2/光催化/染料/水分散/重氮化

Key words

graphene/TiO2/photocatalyst/dye/water dispersibility/diazonium

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基金项目

国家自然科学基金面上项目(52173001)

出版年

2024
北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
参考文献量3
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