北京服装学院学报(自然科学版)2024,Vol.44Issue(2) :18-22,39.DOI:10.16454/j.cnki.issn.1001-0564.2024.02.003

再生无色聚对苯二甲酸丁二醇酯-co-碳酸丁二醇酯流变性能研究

Study on Rheological Property of Colorless Regenerated Poly (Terephthalate-co-butylene Carbonate) Copolyster

裴婷婷 梁日辉 卜雯玥 杨中开 赵国樑
北京服装学院学报(自然科学版)2024,Vol.44Issue(2) :18-22,39.DOI:10.16454/j.cnki.issn.1001-0564.2024.02.003

再生无色聚对苯二甲酸丁二醇酯-co-碳酸丁二醇酯流变性能研究

Study on Rheological Property of Colorless Regenerated Poly (Terephthalate-co-butylene Carbonate) Copolyster

裴婷婷 1梁日辉 1卜雯玥 1杨中开 1赵国樑1
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作者信息

  • 1. 北京服装学院材料设计与工程学院,北京100029
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摘要

有色废旧聚酯纺织品经乙二醇(EG)醇解后,与甲醇(MeOH)酯交换并脱色提纯,得到无色对苯二甲酸二甲酯(DMT);DMT再与1,4-丁二醇(BDO)酯交换得到无色对苯二甲酸双羟基丁二醇酯(BHBT);BHBT与碳酸二甲酯(DMC)和BDO酯交换,得到双甲基碳酸丁二醇酯(BMBC),通过缩聚反应制备出再生无色聚对苯二甲酸丁二醇酯-co-碳酸丁二酯(clr-PBCT)共聚酯.采用毛细管流变仪分别对clr-PBCT60和clr-PBCT70的熔融流变性能进行了测试.结果表明:2种clr-PBCT共聚酯的熔体呈现剪切变稀现象,具有非牛顿流体的流动特征;当剪切速率小于1100 s-1时,clr-PBCT60的可纺性要优于clr-PBCT70;二者的非牛顿指数n均小于1,且随着测试温度的提高而增大;其粘流活化能(△Eη)则随剪切速率的增加而减小,且clr-PBCT60共聚酯的△Eη明显低于clr-PBCT70;当剪切速率小于1100 s-1时,clr-PBCT60样品熔体的结构黏度指数低于clr-PBCT70样品,剪切速率增大时则相反.

Abstract

Colored post-consumer polyester textiles were first alcoholized by ethylene glycol (EG),and the alcohol-ysis were then transesterified with methanol (MeOH ) .The transesterification products were decolorized and puri-fied to prepare colorless dimethyl terephthalate (DMT).It is then exchanged with 1,4-butanediol (BDO) to obtain colorless dihydroxybutanediol terephthalate (BHBT ) .And then,the regenerated colorless clr-PBCT copolyester was prepared by polycondensation of BHBT and dimethyl butylene carbonate (BMBC) which synthesized by trans-esterification of dimethyl carbonate (DMC) and 1,4-butanediol (BDO).The melting rheological properties of clr-PBCT60 and clr-PBCT 70 were tested by using capillary rheometer.The results show that,the melt of the two sam-ples exhibited shear thinning phenomenon,exhibiting non Newtonian fluid flow characteristics;When the shear rate-was less than 1100 s-1,the spinnability of clr-PBCT60 was better than that of clr-PBCT70 .The non-Newtonian ex-ponents (n) of both samples were less than 1 and increased with the increase of testing temperature.Its viscous flow activation energy (△Eη) decreased with the increase of shear rate,and the value of clr-PBCT60 were significantly lower than that of clr-PBCT70 sample.When the shear rate was less than 1100 s-1,the melt structural viscosity in-dex of clr-PBCT60 was lower than that of clr-PBCT70,and the opposite was true when the shear rate increased.

关键词

废旧有色聚酯纺织品/再生无色聚对苯二甲酸丁二醇酯-co-碳酸丁二醇酯/流变性能/粘流活化能Eη/结构黏度指数(△η)

Key words

waste colored polyester textiles/regenerated uncolor poly (terephthalate-co-butylene carbonate ) copolyster/rheological property/viscous flow activation energy(Eη)/structural viscosity index(△η)

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基金项目

&&(H2020-30)

出版年

2024
北京服装学院学报(自然科学版)
北京服装学院

北京服装学院学报(自然科学版)

影响因子:0.17
ISSN:1001-0564
参考文献量6
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