北京化工大学学报(自然科学版)2024,Vol.51Issue(1) :49-58.DOI:10.13543/j.bhxbzr.2024.01.006

连续法制备短切石英纤维/酚醛树脂预混料的固化反应动力学及其模压制品性能

Curing reaction kinetics and properties of the molded products for a chopped quartz fiber/phenolic resin premix prepared by a continuous method

王齐崧 宋金梅 杨帆 张薇 张翠妙
北京化工大学学报(自然科学版)2024,Vol.51Issue(1) :49-58.DOI:10.13543/j.bhxbzr.2024.01.006

连续法制备短切石英纤维/酚醛树脂预混料的固化反应动力学及其模压制品性能

Curing reaction kinetics and properties of the molded products for a chopped quartz fiber/phenolic resin premix prepared by a continuous method

王齐崧 1宋金梅 1杨帆 1张薇 1张翠妙1
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作者信息

  • 1. 北京玻钢院复合材料有限公司,北京 102101
  • 折叠

摘要

采用连续浸胶法,使用自制的压辊式浸胶槽制备了短切石英纤维/酚醛树脂预混料,通过红外光谱法(FT-IR)、热重分析法(TG)和差示扫描量热法(DSC)对预混料进行了表征,并研究了其固化反应动力学.结果表明,溶剂乙醇影响石英纤维的浸胶过程,连续法制备的石英纤维/酚醛树脂预混料能够降低乙醇的影响;预混料的固化工艺参数为:凝胶温度108.40℃,固化温度183.04℃,后处理温度264.47℃;固化反应级数为0.95,固化反应动力学模型为:dα/dt =Aexp(-△E/RT)(1-α)n=4.3×1012exp(-140.74/RT)(1-α)0.95.使用模压法对所制备的预混料进行压制,得到石英纤维/酚醛树脂复合材料的模压制品,该模压制品在 800℃下的质量残留率为 82.3%,拉伸强度为58 MPa,断裂伸长率为0.353%,剪切强度为105 MPa,线烧蚀率为0.088 mm/s,烧蚀表面形貌未见异常,结果表明采用连续法制备的石英纤维/酚醛树脂预混料的模压制品具有较好的耐热性、烧蚀性和力学性能.

Abstract

A chopped quartz fiber/phenolic resin premix was prepared by a continuous dipping method using a self-made pressure roller dipping tank.The premix was characterized by infrared spectroscopy(FT-IR),thermogravi-metric analysis(TG)and differential scanning calorimetry(DSC),and the curing reaction kinetics was studied.The results show that the ethanol solvent affects the impregnation of the quartz fiber,and the quartz fiber/phenolic resin premix prepared by the continuous method can reduce the influence of ethanol.The curing process parameters of the premix were as follows:gel temperature of 108.40℃,curing temperature of 183.04℃,and post-treatment temperature of 264.47℃.The curing reaction order is 0.95,and the curing reaction kinetic model is as follows:dα/dt =A·exp(-△E/RT)(1-α)n=4.3×1012·exp(-140.74/RT)(1-α)0.95.The quartz fiber/phenolic res-in composite molded products were obtained by pressing the prepared premix using the molding method.The mass residual rate of the molded product at 800℃was 82.3%,the tensile strength 58 MPa,the elongation at break 0.353%,the shear strength 105 MPa,and the linear ablation rate 0.088 mm/s,and no abnormalities were ob-served in ablation surface morphology.The results show that the molded products of the quartz fiber/phenolic resin premix prepared by the continuous method have good heat resistance,ablation resistance and mechanical proper-ties.

关键词

连续法/石英纤维/酚醛树脂/预混料/固化反应动力学/性能

Key words

continuous method/quartz fiber/phenolic resin/premix/curing kinetics/properties

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出版年

2024
北京化工大学学报(自然科学版)
北京化工大学

北京化工大学学报(自然科学版)

CSTPCDCSCD北大核心
影响因子:0.399
ISSN:1671-4628
参考文献量14
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