北京化工大学学报(自然科学版)2024,Vol.51Issue(2) :93-100.DOI:10.13543/j.bhxbzr.2024.02.010

硫系薄膜材料相变温度光功率测量法研究

An optical power method for measuring the phase change temperature of chalcogenide thin film materials

吴国栋 金森林 付俊杰 李硕 任玲玲 贺建芸
北京化工大学学报(自然科学版)2024,Vol.51Issue(2) :93-100.DOI:10.13543/j.bhxbzr.2024.02.010

硫系薄膜材料相变温度光功率测量法研究

An optical power method for measuring the phase change temperature of chalcogenide thin film materials

吴国栋 1金森林 2付俊杰 3李硕 2任玲玲 2贺建芸3
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作者信息

  • 1. 北京化工大学 机电工程学院, 北京 100029;中国计量科学研究院国家市场监管技术创新中心(石墨烯计量与标准技术), 北京 100029
  • 2. 中国计量科学研究院国家市场监管技术创新中心(石墨烯计量与标准技术), 北京 100029;深圳中国计量科学研究院技术创新研究院 国家石墨烯材料产业计量测试中心(深圳), 深圳 518107
  • 3. 北京化工大学 机电工程学院, 北京 100029
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摘要

相变温度是衡量相变薄膜材料性能的关键参数,对相变存储器的数据保持力、热稳定性和功耗有着巨大的影响,因此相变温度的准确测量非常重要.目前,国内外测量薄膜材料相变温度的主要方法有变温X射线衍射法和差示扫描量热法,前者测量精度有限,后者是破坏性测量.本文根据薄膜材料相变前后光学性质会发生较大改变的特性,首先设计了薄膜材料相变温度测量仪的硬件部分,主要包含高温加热炉、样品台、光路模块等;其次探究了高温加热炉腔的温场均匀性及温度模块的控制能力,结果表明均符合实验要求;最后,利用此装置测量了典型硫系材料GeTe和Ge2Sb2Te5薄膜的相变温度,10次测量平均值分别为212.7℃和145.4℃,标准偏差分别为1.70和2.32,测量结果稳定性良好,达到实验预期.

Abstract

Phase change temperature is a key parameter that determines the material properties of phase change films and has a huge impact on the data retention force, thermal stability and power consumption of phase change memory. Accurate measurements of phase change temperature are therefore very important. Currently, the main methods for measuring the phase transition temperature of thin film materials in China and elsewhere are variable temperature X-ray diffraction methods and differential scanning calorimetry. The former has limited measurement accuracy, while the latter is a destructive measurement method. Based on the fact that the optical properties of thin film materials will change greatly before and after a phase change, a new phase change temperature measuring in-strument for thin film materials has been designed. The hardware part includes a high-temperature heating furnace, a sample stage, and an optical path module. The temperature field uniformity of the high-temperature heating fur-nace cavity and the ability to control the temperature module were shown to meet the experimental requirements. Fi-nally, films of typical chalcogenide materials, GeTe and Ge2Sb2Te5 , were studied using the device. The average phase change temperatures of 10 measurements were 212. 7℃ and 145. 4℃, and the standard deviation was 1. 70 and 2. 32, respectively. The measurement results are stable and meet the expected requirements.

关键词

相变存储器/相变温度/高温加热炉/光功率/光功率测量法

Key words

phase change memory/phase change temperature/high temperature heating furnace/optical power/optical power measurement

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出版年

2024
北京化工大学学报(自然科学版)
北京化工大学

北京化工大学学报(自然科学版)

CSTPCDCSCD北大核心
影响因子:0.399
ISSN:1671-4628
参考文献量17
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