首页|聚氨酯乳液对碱-矿渣-粉煤灰基地聚物的体积稳定性影响研究

聚氨酯乳液对碱-矿渣-粉煤灰基地聚物的体积稳定性影响研究

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研究了不同掺量聚氨酯乳液下,碱-矿渣-粉煤灰基地聚物(AAFS)体积稳定性变化规律,并对其体积稳定性改善机理予以揭示.研究表明:聚氨酯掺量3% ~7%时,延长了AAFS的初终凝时间,降低了净浆流动度.聚氨酯的加入,减少了AAFS水化生成物的生成量,降低了砂浆的折压强度,28 d抗压强度为38~45 MPa,28d抗折强度为6.5~7.7 MPa,折压比提高14.8% ~22.3%,韧性改善明显.聚氨酯与AAFS的交互链接,改善了AAFS的体积变化,56 d收缩率为9.7% ~28.4%,下降明显.同条件下,PU改性AAFS试件的抗开裂性能明显改善.
Study on the Effect of Polyurethane Emulsion on the Volume Stability of Alkali-Slag-Fly Ash Based Geopolymer
The volumetric stability changes of different dosages of polyurethane emulsion alkali-slag-fly ash base polymers ( AAFS) are investigated and the improving mechanism of their volumetric stability is revealed. The research shows that when the PU dosage is between 3% and 7%, it prolongs the initial and final setting time of AAFS and reduces the flowability of the slurry. The addition of polyurethane reduces the generation of hydration products in AAFS, resulting in a decrease in the compressive strength of mortar. The 28-day compressive strength ranges from 38 to 45 MPa, and the 28-day flexural strength ranges from 6. 5 to 7. 7 MPa, with an increase in the flexural-to-compressive strength ratio by 14. 8% to 22. 3%, indicating a significant improvement in toughness. The interaction between polyurethane and AAFS improves the volumetric changes of AAFS, with a shrinkage rate of 9. 7% to 28. 4% at 56 days, showing a significant decrease. Under the same conditions, the cracking resistance of AAFS modified by PU is significantly improved.

polyurethanegeopolymershrinkage propertiestoughening modification

廖恒、卞立波、丁林娜、王昕轶、李珉宇

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北京建筑大学 土木与交通工程学院,北京 100044

聚氨酯 地聚物 收缩性能 增韧

"十四五"国家重点研发计划项目

2022YFV30803404-02

2024

北京建筑大学学报
北京建筑工程学院

北京建筑大学学报

影响因子:0.562
ISSN:1004-6011
年,卷(期):2024.40(3)
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