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细菌纤维素-壳聚糖-白藜芦醇复合膜的构建及其应用

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为开发具有良好保鲜效果的天然生物基复合膜材料,以结构和功能特性相近的细菌纤维素(BC)和壳聚糖(CS)为基础,将环状糊精-白藜芦醇包合物(RES)复合,得到了复合膜BC-CS/RESn.研究了不同质量分数的 RES(0、5%、10%、15%、20%)对 BC-CS/RESn理化及功能特性的影响.红外光谱和X射线衍射分析结果表明,RES与BC-CS之间存在氢键和范德华力等非共价相互作用,RES的添加可改善复合膜的机械性能和阻隔性能.RES质量分数为10%时,复合膜的拉伸强度为(81.64±0.14)MPa,断裂伸长率为(27.83±3.40)%;RES质量分数为15%时,BC-CS/RES3的氧气渗透率达(0.85±0.03)g/(m2·s);RES质量分数为20%时,BC-CS/RES4的水蒸气透过率最好,为(6.74±0.02)g/(m2·24 h).RES的添加使复合膜具有良好的抗氧化性和抑菌性,其中添加质量分数为20%的RES复合膜24 h后的DPPH自由基清除能力提高了13.31倍,铁离子还原能力提高了 49.99%,对大肠杆菌和金黄色葡萄球菌的抑菌能力分别提高了4.65倍和2.42倍.将复合膜应用于冷藏鱼片的保鲜,可以有效延缓鱼片在贮藏期间挥发性盐基氮的积累.BC-CS/RESn在水产保鲜方面具有潜在的应用价值.
Construction and Application of Bacterial Cellulose-Chitosan-Resveratrol Composite Film
In order to develop natural bio-based composite film materials with good preservation effects,bacterial cellulose(BC)and chitosan(CS),which have similar structural and functional properties,were used as the basis to composite cyclodextrin-resveratrol inclusion compound(RES),and finally bacterial cellulose-chitosan/cyclodextrin-resveratrol inclusion composite film(BC-CS/RESn)was obtained.The effects of RES addition(0,5%,10%,15%,20%)on the physicochemical and functional properties of BC-CS/RESn were investigated.The Fourier transform infrared spectroscopy and X-ray diffraction results showed that there were non-covalent interactions such as hydrogen bonding and van der Waals forces between RES and BC-CS,and the addition of RES improved the mechanical and barrier properties of the composite films.The tensile strength of the composite film was(81.64±0.14)MPa,and the elongation at break was(27.83±3.40)%when the addition of RES was 10%.The oxygen permeability of the BC-CS/RES3 could reach(0.85±0.03)g/(m2·s)when the addition of RES was 15%.The water vapor permeability of the BC-CS/RES4 was the best at 20%RES addition,which was(6.74±0.02)g/(m2·24 h).The addition of RES gave the composite film good antioxidant and bacteriostatic properties,in which the DPPH radical scavenging capacity of the composite film with 20%RES addition increased by 13.31 times after 24 h,and the ferric iron reduction capacity increased by 49.99%,and the antibacterial ability of the composite film against Escherichia coli and Staphylococcus aureus increased by 4.65 times and 2.42 times,respectively.When the composite film was applied to the preservation of refrigerated fish fillets,the accumulation of volatile basic nitrogen during storage was effectively delayed.Therefore,the BC-CS/RESnhad potential application value in aquatic preservation.

bacterial cellulosechitosanresveratrolcyclodextrincomposite filmfish fillet

窦荷影、王晓庆、孙欣、冯安琪、孙田雨、迪丽胡玛尔·迪力木拉提、刘晓丽

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江南大学食品学院/食品科学与资源挖掘国家重点实验室/江苏省食品安全与质量控制协同创新中心,江苏无锡 214122

细菌纤维素 壳聚糖 白藜芦醇 环状糊精 复合膜 鱼片

2025

食品科学技术学报
北京工商大学

食品科学技术学报

北大核心
影响因子:1.967
ISSN:2095-6002
年,卷(期):2025.43(1)