宝鸡文理学院学报(自然科学版)2024,Vol.44Issue(1) :12-18.DOI:10.13467/j.cnki.jbuns.2024.01.003

BaTiO3/Co3O4复合材料对PMS体系降解的效能优化

Optimization of BaTiO3/Co3O4 composites for degradation of PMS system

赵瑞 高紫璇 王芙蓉 李华 张沙沙 张洁 白晓龙 赵卫星 王艳
宝鸡文理学院学报(自然科学版)2024,Vol.44Issue(1) :12-18.DOI:10.13467/j.cnki.jbuns.2024.01.003

BaTiO3/Co3O4复合材料对PMS体系降解的效能优化

Optimization of BaTiO3/Co3O4 composites for degradation of PMS system

赵瑞 1高紫璇 1王芙蓉 1李华 1张沙沙 1张洁 1白晓龙 1赵卫星 1王艳1
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作者信息

  • 1. 宝鸡文理学院化学与化工学院,陕西宝鸡 721013
  • 折叠

摘要

目的 研究添加剂十六烷基三甲基溴化铵(CTAB)与乙二胺四乙酸二钠(EDTA-2Na)对所得BaTiO3/Co3O4(BT/Co)复合材料表面Co2+相对含量及催化活性的影响.方法 采用溶胶—凝胶法结合高温焙烧合成了铁电BT/Co复合材料,用于激活过一硫酸盐(Peroxy monosulfate,PMS)氧化降解水相中的亚甲基蓝(Methylene Blue,MB);通过有机污染物MB的氧化降解实验,探讨了CTAB与EDTA-2Na对获得BT/Co复合材料催化活性的影响.结果 CTAB与EDTA-2Na作为添加剂,对所得BT/Co复合材料的相组成与微观结构无明显影响,但催化剂表面Co2+相对含量呈现出明显变化.结论 当EDTA-2Na为添加剂时,所得BT/Co复合材料表面Co2+相对含量提高,活化PMS生成了较多的活性氧化物种,加速了MB的降解,10min内MB的降解率达到99%.

Abstract

Purposes—To study the effects of additives cetyltrimethyl ammonium bromide(CTAB)and EDT A-2Na on the relative Co2+content and catalytic activity of BaTiO3/Co3O4(BT/Co)compos-ite.Methods—Ferroelectric BT/Co composites were synthesized with sol-gel method in combination with high temperature and were used to activate peroxymonosulfate(PMS)to oxidize and degrade methylene blue(MB)in aqueous phase.The effect of CTAB and EDTA-2Na on obtaining the catalyt-ic activity of BT/Co composites were investigated via oxidative degradation experiments of organic pollutants MB.Results—As additives,CTAB and EDTA-2Na had no significant effect on the phase composition and microstructure of the BT/Co composites,but the relative content of Co2+ on the cata-lyst surface showed obvious changes.Conclusions—When EDTA-2Na was used as additive,the rela-tive content of Co2 on the surface of the BT/Co composite was increased,and more active oxidation species were generated by activating PMS,which accelerated the degradation of MB,and the degrada-tion rate of MB reached 99%within 10 min.

关键词

添加剂/BaTiO3/Co3O4复合材料/表面Co2+含量/催化性能

Key words

additives/BaTiO3/Co3O4 composites/surface Co2+content/catalytic performance

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基金项目

宝鸡文理学院大学生创新创业训练计划(2022)(202210721001)

陕西省科技计划面上项目(2023-JC-YB-093)

出版年

2024
宝鸡文理学院学报(自然科学版)
宝鸡文理学院

宝鸡文理学院学报(自然科学版)

影响因子:0.356
ISSN:1007-1261
参考文献量19
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