宝鸡文理学院学报(自然科学版)2024,Vol.44Issue(1) :19-27.DOI:10.13467/j.cnki.jbuns.2024.01.004

改性硅胶作为PAO-10润滑添加剂摩擦学性能研究

Tribological behavior of modified silica gels as lubricant additives in PAO-10

邱吉霞 白梓静 高鹏 王雨萌
宝鸡文理学院学报(自然科学版)2024,Vol.44Issue(1) :19-27.DOI:10.13467/j.cnki.jbuns.2024.01.004

改性硅胶作为PAO-10润滑添加剂摩擦学性能研究

Tribological behavior of modified silica gels as lubricant additives in PAO-10

邱吉霞 1白梓静 2高鹏 1王雨萌1
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作者信息

  • 1. 宝鸡文理学院化学化工学院,陕西省植物化学重点实验室,陕西宝鸡 721013
  • 2. 宝鸡文理学院化学化工学院,陕西省植物化学重点实验室,陕西宝鸡 721013;西安工业大学材料与化工学院,陕西西安 710021
  • 折叠

摘要

目的 合成4种改性硅胶,并将其作为PAO-10的润滑油添加剂,考察其摩擦学性能,并对润滑机理进行分析.方法 采用棕榈酰氯对不同目数的普通硅胶进行改性,形成长烃链酰胺官能团,并通过傅里叶红外光谱仪对其结构进行确认.进一步通过摩擦磨损试验机和三维轮廓仪对润滑体系的摩擦学性能进行表征,采用接触角、扫描电子显微镜(SEM)、能谱仪(EDS)和X射线光电子能谱(XPS)对润滑机理进行研究.结果 该系列改性硅胶添加剂极大改善了PAO-10的摩擦学性能.当向PAO-10中添加1.0%的改性硅胶S200~300PMAD后,PAO-10的摩擦系数降低了60%,磨损体积降低了74%.结论 摩擦副表面形成一定厚度的物理吸附膜层和含Fe2O3的化学反应膜层,二者共同提升了润滑体系的摩擦学性能,改性硅胶上附着的烷基链和活性杂原子是形成该保护膜的重要原因.

Abstract

Purposes—To improve the tribological properties of PAO-10 by synthesizing 4 exam-ples of silicone oil-based additives.Methods—Common silica gels with different meshes were modified by palmitoyl chloride with a simple method,by which the amide bond was formed.Then,the chemi-cal structures were confirmed by FTIR and the tribological performances were evaluated by SRV and 3D profiler.Furthermore,a possible lubricant mechanism was proposed after the tests including con-tact angle,SEM,EDS and XPS.Results—The results indicated that these additives could greatly im-prove the tribological performance of base oils.Specifically,when 1.0%modified silicone S200~300 PM AD was added to PAO-10,the friction coefficient of PAO-10 is reduced by 60%and the wear volume decreased by 74%.Conclusions—After the analysis including contact angle,SEM,EDS and XPS,it is shown that the alkyl chains and active heteroatoms on silica gels is crucial to its dispersion stability and the formation of protective films,which further improve the tribological performances of PAO-10.

关键词

硅胶/润滑剂添加剂/摩擦膜

Key words

silica gels/lubricant additives/tribo-film

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基金项目

陕西省科技计划面上项目(2024JC-YBMS-120)

出版年

2024
宝鸡文理学院学报(自然科学版)
宝鸡文理学院

宝鸡文理学院学报(自然科学版)

影响因子:0.356
ISSN:1007-1261
参考文献量38
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