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热膨胀法测定玻璃热性能的应用评估

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热膨胀法可以测定玻璃的热性能,包括:热膨胀系数α与应变点Tst、转变点Tg、退火点Ta、膨胀软化点兀等特征温度点.对热膨胀法测定玻璃热性能的应用进行评估,评估结果表明:(1)玻璃的热膨胀系数α会随着温度段变化而变化,同时在一定范围内,升温速率越大,热膨胀系数越小;(2)热膨胀法测定玻璃特征温度点的重复性偏差在±10℃以内,一定范围内,升温速率越大,特征温度点温度越高;(3)热膨胀法测定玻璃热性能的升温速率优选3℃/min;(4)玻璃中B2O3含量越高,同时CaO含量越低,那么玻璃的热膨胀系数α越小,玻璃的应变点Tst与转变温度gT越小,退火加工温度范围也就越大.
Application Evaluation of Thermal Expansion Method for Measuring Glass Thermal Properties
Thermal expansion method can measure glass thermal properties,including coefficient of thermal expansion α and Characteristic temperature points such as strain point Tst,transition point Tg,annealing point Ta,expansion softening point Td,etc.The evaluation of the application in measuring glass thermal properties using thermal expansion method shows that:(1)Thermal expansion coeficient α of glass will change with temperature changes,and within a certain range,the larger the heating rate,the smaller the coefficient of thermal expansion;(2)The repeatability deviation of thermal expansion method for measuring the characteristic temperature points of glass is within±10℃.Within a certain range,the higher the heating rate,the higher the characteristic temperature point temperature;(3)The optimal heating rate for measuring thermal properties of glass using thermal expansion method is 3 ℃/min;(4)The higher the B2O3 content and the lower the CaO content in glass,the higher the thermal expansion coefficient α of glass,the smaller the strain point Tst and transition point Tg of glass,the larger the annealing temperature range.

glasscoefficient of thermal expansionglass transition pointexpansion softening pointannealing

柏晓强、曹国荣、邢文忠、章林、洪秀成、赵刚

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巨石集团有限公司 桐乡 314500

玻璃 热膨胀系数 玻璃转变点 膨胀软化点 退火

2024

玻璃
秦皇岛玻璃工业研究设计院

玻璃

影响因子:0.274
ISSN:1003-1987
年,卷(期):2024.51(1)
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